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DOE OSTI · 1317090

Materials Data on AgBiO2 by Materials Project

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Abstract

AgBiO2 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Ag1+ is bonded in a linear geometry to two O2- atoms. There are one shorter (2.09 Å) and one longer (2.10 Å) Ag–O bond lengths. Bi3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Bi–O bond distances ranging from 2.20–2.80 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to one Ag1+ and three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded to one Ag1+ and three equivalent Bi3+ atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra.

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36 MATERIALS SCIENCEAg-Bi-OAgBiO2crystal structure

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2020-07-23. Materials Data on AgBiO2 by Materials Project. https://doi.org/10.17188/1317090

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36 MATERIALS SCIENCE↗