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DOE OSTI · 1291709

Materials Data on Li2PdO2 by Materials Project

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Abstract

Li2PdO2 is Corundum-derived structured and crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. Li1+ is bonded to four equivalent O2- atoms to form a mixture of edge and corner-sharing LiO4 trigonal pyramids. There are two shorter (1.96 Å) and two longer (2.08 Å) Li–O bond lengths. Pd2+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Pd–O bond lengths are 2.06 Å. O2- is bonded to four equivalent Li1+ and two equivalent Pd2+ atoms to form a mixture of edge and corner-sharing OLi4Pd2 octahedra. The corner-sharing octahedra tilt angles range from 0–26°.

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36 MATERIALS SCIENCEcrystal structureLi-O-PdLi2PdO2

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2020-07-15. Materials Data on Li2PdO2 by Materials Project. https://doi.org/10.17188/1291709

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