Materials Data on LiAgF4 by Materials Project

Abstract

LiAgF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Li1+ is bonded in a see-saw-like geometry to four equivalent F1- atoms. There is two shorter (1.96 Å) and two longer (1.98 Å) Li–F bond length. Ag3+ is bonded in a distorted square co-planar geometry to four F1- atoms. There is two shorter (1.95 Å) and two longer (1.99 Å) Ag–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to one Ag3+ atom. In the second F1- site, F1- is bonded in a distorted trigonal planar geometry to two equivalent Li1+ and one Ag3+ atom.