Materials Data on AgBrO4 by Materials Project

Abstract

AgO4Br crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Ag3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.37–2.86 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Ag3+ and one Br5+ atom. The O–Br bond length is 1.67 Å. In the second O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Ag3+ and one Br5+ atom. The O–Br bond length is 1.67 Å. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Ag3+ and one Br5+ atom. The O–Br bond length is 1.66 Å. In the fourth O2- site, O2- is bonded in a bent 150 degrees geometry to one Ag3+ and one Br5+ atom. The O–Br bond length is 1.66 Å. Br5+ is bonded in a tetrahedral geometry to four O2- atoms.