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DOE OSTI · 1289529

Materials Data on NClO3 by Materials Project

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Abstract

ClONO2 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four chlorine nitrate molecules. N is bonded in a trigonal planar geometry to three O atoms. There are a spread of N–O bond distances ranging from 1.20–1.54 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one N atom. In the second O site, O is bonded in a bent 120 degrees geometry to one N and one Cl atom. The O–Cl bond length is 1.68 Å. In the third O site, O is bonded in a single-bond geometry to one N atom. Cl is bonded in a single-bond geometry to one O atom.

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36 MATERIALS SCIENCECl-N-Ocrystal structureNClO3

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2020-04-29. Materials Data on NClO3 by Materials Project. https://doi.org/10.17188/1289529

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