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DOE OSTI · 1283630

Materials Data on CBr4 by Materials Project

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Abstract

CBr4 is Iron carbide-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two carbon tetrabromide molecules. C4+ is bonded in a tetrahedral geometry to four Br1- atoms. There is two shorter (1.95 Å) and two longer (1.97 Å) C–Br bond length. There are four inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one C4+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one C4+ atom. In the third Br1- site, Br1- is bonded in a single-bond geometry to one C4+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one C4+ atom.

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36 MATERIALS SCIENCEBr-CCBr4crystal structure

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2020-05-02. Materials Data on CBr4 by Materials Project. https://doi.org/10.17188/1283630

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