Materials Data on HPbCSNO by Materials Project

Abstract

PbCNHSO crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two PbCNHSO ribbons oriented in the (1, 0, 0) direction. Pb2+ is bonded in a 4-coordinate geometry to one N3- and three equivalent O2- atoms. The Pb–N bond length is 2.56 Å. There are one shorter (2.42 Å) and two longer (2.48 Å) Pb–O bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.63 Å. N3- is bonded in a distorted single-bond geometry to one Pb2+ and one C4+ atom. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. S2- is bonded in a single-bond geometry to one C4+ atom. O2- is bonded in a single-bond geometry to three equivalent Pb2+ and one H1+ atom.