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DOE OSTI · 1276450

Materials Data on WSCl4 by Materials Project

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Abstract

WSCl4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WSCl4 clusters. W6+ is bonded in a distorted trigonal bipyramidal geometry to one S2- and four Cl1- atoms. The W–S bond length is 2.10 Å. There are two shorter (2.30 Å) and two longer (2.31 Å) W–Cl bond lengths. S2- is bonded in a single-bond geometry to one W6+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one W6+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one W6+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one W6+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one W6+ atom.

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36 MATERIALS SCIENCECl-S-Wcrystal structureWSCl4

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2020-07-15. Materials Data on WSCl4 by Materials Project. https://doi.org/10.17188/1276450

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