Materials Data on AgC4OF9 by Materials Project

Abstract

AgCO(CF3)3 is Ammonia-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve fluoroform molecules and one AgCO cluster. In the AgCO cluster, there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 2-coordinate geometry to two O2- atoms. There are one shorter (2.25 Å) and one longer (2.34 Å) Ag–O bond lengths. In the second Ag1+ site, Ag1+ is bonded in a distorted linear geometry to two O2- atoms. There are one shorter (2.17 Å) and one longer (2.20 Å) Ag–O bond lengths. There are two inequivalent C+2.50+ sites. In the first C+2.50+ site, C+2.50+ is bonded in a single-bond geometry to one O2- atom. The C–O bond length is 1.38 Å. In the second C+2.50+ site, C+2.50+ is bonded in a single-bond geometry to one O2- atom. The C–O bond length is 1.39 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to two Ag1+ and one C+2.50+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Ag1+ and one C+2.50+ atom.