Materials Data on Xe2NO2F13 by Materials Project

Abstract

Xe2F13NO2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydroxylamine, n-hydroxy- molecules and four Xe2F13 clusters. In each Xe2F13 cluster, there are two inequivalent Xe sites. In the first Xe site, Xe is bonded in a 6-coordinate geometry to eight F atoms. There are a spread of Xe–F bond distances ranging from 2.00–2.59 Å. In the second Xe site, Xe is bonded in a distorted pentagonal bipyramidal geometry to seven F atoms. There are a spread of Xe–F bond distances ranging from 2.00–2.24 Å. There are nine inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Xe atom. In the second F site, F is bonded in a single-bond geometry to one Xe atom. In the third F site, F is bonded in a single-bond geometry to one Xe atom. In the fourth F site, F is bonded in a distorted bent 120 degrees geometry to two Xe atoms. In the fifth F site, F is bonded in a single-bond geometry to one Xe atom. In the sixth F site, F is bonded in a single-bond geometry to one Xe atom. In the seventh F site, F is bonded in a single-bond geometry to one Xe atom. In the eighth F site, F is bonded in a single-bond geometry to one Xe atom. In the ninth F site, F is bonded in a single-bond geometry to one Xe atom.