Materials Data on SN by Materials Project

Abstract

NS is red selenium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1,3,5,7,2,4,6,8-tetrathiatetrazocane molecules. there are four inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a bent 120 degrees geometry to two S1- atoms. Both N–S bond lengths are 1.63 Å. In the second N1+ site, N1+ is bonded in a bent 120 degrees geometry to two S1- atoms. Both N–S bond lengths are 1.63 Å. In the third N1+ site, N1+ is bonded in a bent 120 degrees geometry to two S1- atoms. Both N–S bond lengths are 1.63 Å. In the fourth N1+ site, N1+ is bonded in a bent 120 degrees geometry to two S1- atoms. Both N–S bond lengths are 1.63 Å. There are four inequivalent S1- sites. In the first S1- site, S1- is bonded in a water-like geometry to two N1+ atoms. In the second S1- site, S1- is bonded in a water-like geometry to two N1+ atoms. In the third S1- site, S1- is bonded in a water-like geometry to two N1+ atoms. In the fourth S1- site, S1- is bonded in a water-like geometry to two N1+ atoms.