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DOE OSTI · 1205209

Materials Data on Tl2Pt3 by Materials Project

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Abstract

Pt3Tl2 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pt+0.67- is bonded in a 5-coordinate geometry to six equivalent Pt+0.67- and five Tl1+ atoms. There are a spread of Pt–Pt bond distances ranging from 2.85–2.98 Å. There are a spread of Pt–Tl bond distances ranging from 2.84–3.02 Å. There are three inequivalent Tl1+ sites. In the first Tl1+ site, Tl1+ is bonded in a 6-coordinate geometry to six equivalent Pt+0.67- atoms. In the second Tl1+ site, Tl1+ is bonded in a 6-coordinate geometry to six equivalent Pt+0.67- atoms. In the third Tl1+ site, Tl1+ is bonded in a distorted q6 geometry to nine equivalent Pt+0.67- atoms.

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36 MATERIALS SCIENCEcrystal structurePt-TlTl2Pt3

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2020-07-17. Materials Data on Tl2Pt3 by Materials Project. https://doi.org/10.17188/1205209

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