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DOE OSTI · 1202005

Materials Data on Tl2SnCl6 by Materials Project

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Abstract

Tl2SnCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tl1+ is bonded to twelve equivalent Cl1- atoms to form TlCl12 cuboctahedra that share corners with twelve equivalent TlCl12 cuboctahedra, faces with six equivalent TlCl12 cuboctahedra, and faces with four equivalent SnCl6 octahedra. All Tl–Cl bond lengths are 3.63 Å. Sn4+ is bonded to six equivalent Cl1- atoms to form SnCl6 octahedra that share faces with eight equivalent TlCl12 cuboctahedra. All Sn–Cl bond lengths are 2.47 Å. Cl1- is bonded in a distorted single-bond geometry to four equivalent Tl1+ and one Sn4+ atom.

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36 MATERIALS SCIENCECl-Sn-Tlcrystal structureTl2SnCl6

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2020-07-15. Materials Data on Tl2SnCl6 by Materials Project. https://doi.org/10.17188/1202005

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36 MATERIALS SCIENCE↗