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DOE OSTI · 1201676

Materials Data on Al2PdCl8 by Materials Project

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Abstract

PdAl2Cl8 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PdAl2Cl8 clusters. Pd2+ is bonded in a square co-planar geometry to four Cl1- atoms. All Pd–Cl bond lengths are 2.34 Å. Al3+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Al–Cl bond distances ranging from 2.10–2.25 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Al3+ atom. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to one Pd2+ and one Al3+ atom. In the third Cl1- site, Cl1- is bonded in an L-shaped geometry to one Pd2+ and one Al3+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Al3+ atom.

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36 MATERIALS SCIENCEAl-Cl-PdAl2PdCl8crystal structure

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2020-07-23. Materials Data on Al2PdCl8 by Materials Project. https://doi.org/10.17188/1201676

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