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DOE OSTI · 1199543

Materials Data on CsIO4 by Materials Project

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Abstract

CsIO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Cs is bonded in a 8-coordinate geometry to eight O atoms. There are a spread of Cs–O bond distances ranging from 3.16–3.40 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to two equivalent Cs and one I atom. The O–I bond length is 1.80 Å. In the second O site, O is bonded in a distorted single-bond geometry to three equivalent Cs and one I atom. The O–I bond length is 1.80 Å. In the third O site, O is bonded in a distorted linear geometry to one Cs and one I atom. The O–I bond length is 1.80 Å. I is bonded in a tetrahedral geometry to four O atoms.

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36 MATERIALS SCIENCEcrystal structureCs-I-OCsIO4

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2020-07-20. Materials Data on CsIO4 by Materials Project. https://doi.org/10.17188/1199543

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