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DOE OSTI · 1199130

Materials Data on Rb2TeCl6 by Materials Project

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Abstract

Rb2TeCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent Cl1- atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent RbCl12 cuboctahedra, faces with six equivalent RbCl12 cuboctahedra, and faces with four equivalent TeCl6 octahedra. All Rb–Cl bond lengths are 3.72 Å. Te4+ is bonded to six equivalent Cl1- atoms to form TeCl6 octahedra that share faces with eight equivalent RbCl12 cuboctahedra. All Te–Cl bond lengths are 2.57 Å. Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Te4+ atom.

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36 MATERIALS SCIENCECl-Rb-Tecrystal structureRb2TeCl6

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2020-07-16. Materials Data on Rb2TeCl6 by Materials Project. https://doi.org/10.17188/1199130

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36 MATERIALS SCIENCE↗