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DOE OSTI · 1190967

Materials Data on Sc2MnSe4 by Materials Project

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Abstract

Sc2MnSe4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Sc3+ is bonded to six equivalent Se2- atoms to form ScSe6 octahedra that share corners with six equivalent MnSe4 tetrahedra and edges with six equivalent ScSe6 octahedra. All Sc–Se bond lengths are 2.72 Å. Mn2+ is bonded to four equivalent Se2- atoms to form MnSe4 tetrahedra that share corners with twelve equivalent ScSe6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Mn–Se bond lengths are 2.53 Å. Se2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Sc3+ and one Mn2+ atom.

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36 MATERIALS SCIENCEcrystal structureMn-Sc-SeSc2MnSe4

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2020-07-15. Materials Data on Sc2MnSe4 by Materials Project. https://doi.org/10.17188/1190967

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