NASA NTRS · 20210001648
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Snyder, G. J.. 2003-08-17. Thermoelectric efficiency and compatibility. https://ntrs.nasa.gov/citations/20210001648
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A significant need exists to develop materials not only capable of providing desired electronic and mechanical properties but also survival at extreme temperatures during service and device fabrication, such as co-firing. Computational methods offers an efficient and systematic manner to design new materials and guide their development. As an example computational -based material approaches can be used to determine the suitability of a given materials as a practical thermoelectric for energy harvesting. In this presentation examples are given of applications to relevant technical ceramics such as thermoelectrics, dielectrics, and magnetic systems. The calculation were based on density functional theory and carried out with norm conserving and projector augmented wave (PAW) methods using commercial codes Materials Studio ( Biovia, Inc) with the Cambridge Serial Total Energy Package (CASTEP) and MedeA (Materials Design Inc.) utilizing the Vienna Ab-initio Simulation Package (VASP) as the respective computational engines. This study makes predictions of relevant technical properties of ceramic materials.
The MSL Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) was fueled on October 28, 2008 by the Department Of Energy (DOE) in preparation for a late 2009 launch. Shortly after, the MSL launch was delayed approximately 2 years until 2011. The fueled MMRTG was placed in storage to await the new date for liftoff. Occasional measurements of the MMRTG's power output were taken and compared with power predictions that pre-dated fueling. An error in the predictive models was quickly recognized and remedied. The resultant predictions, while improved, carried significant uncertainty. This uncertainty did not deter the launch of MSL, but did alter the planned mission on the surface of Mars. Once launched, the MSL spacecraft provided a hi-fidelity telemetry stream measuring the generator's electrical and thermal performance. These data were used to update the predictive models and a new prediction of the performance of the MMRTG on the surface of Mars was run just before Entry, Descent, and Landing (EDL) at Mars. The MSL MMRTG is working extremely well, providing power above predictions and operating within its flight allowable temperature limits. The generator was producing approximately 114 W at the beginning of the surface mission. This paper will elaborate on power modeling for the MSL MMRTG along with a review of some of the data recorded from the MSL cruise to Mars, EDL, and the early days of the surface mission.
Two types of promising phosphide skutterudite materials, Co(1-x)NixP3 (x= 0.025 to 0.70) and CoAs(3-x)Px (x=0.5 to 0.10), have been synthesized and their transport properties measured. These compounds were prepared using a direct synthesis technique. The samples were hot pressed and analyzed by electron microprobe microscopy. Hall Effect measurements were conducted to determine the electrical conductivity, mobility and carrier concentration. In addition, Seebeck voltage and thermal conductivity measurements were performed. The thermoelectric properties are presented anddiscussed as a function of temperature up to 1273 K. The thermal stability of the primary CoP3 was examined in a static vacuum under isothermal and in-gradient conditions. The effect of the presence of 1 atm of a cover gas on the material loss rate was analyzed.