Reference model for CH4 and N2O and trends

Abstract

Data from the Stratospheric and Mesospheric Sounder on Nimbus 7 were used as the basis for a model of the abundances of nitrous oxide and methane in the stratosphere. A version of this was produced two years ago (Taylor, Dudhia, and Rodgers - hereafter called the original paper) and in this new paper some of the possible error sources and long term trends are considered in more detail. The principle source of error in the SAMS retrievals is thought to be the use of climatological ozone profiles to invert the temperature profile data. However, it was found that the effect is too small, and of the opposite sign, to explain the discrepancies between satellite and in situ measurements, noted in the original paper. As expected, no systematic trends which exceed the estimated error in the data are found in either methane or nitrous oxide.