Carbon in oxides and silicates - Dissolution versus exsolution

Abstract

A theory of CO2 dissolution in the solid state is developed, using the idea proposed by Freund (1983) concerning dissolution of CO/CO2 in MgO on the basis of their experimental results obtained with an MgO-containing carbon impurity. It is shown that the dissolution mechanism may be linked to an internal redox reaction by which a certain number of lattice oxygens change their formal oxidation state from -2 to -1, while the carbon becomes reduced. The similarities between the mechanisms of CO and/or CO2 dissolution and that of H2O dissolution are pointed out. A hypothesis is proposed concerning the exsolution of reduced carbon from supersaturated solid solutions under conditions which permit C-C bond formation.