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Batteries & storage

Find NASA NTRS and DOE OSTI reports about batteries and energy storage. Search electrode materials, lithium-ion batteries and storage systems in indexed report metadata.

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NASA NTRS2023

Evaluation of Ultrasonic Battery Inspection Techniques

Lithium metal batteries are prone to subtle defects such as internal dendrites, which can cause internal short circuits and lead to catastrophic ignition. These defects are often undetectable by battery management systems, prompting the need to advance nondestructive evaluation (NDE) techniques for battery applications. In this work, two ultrasonic approaches were compared to establish their relative merits for this application: local ultrasonic resonance spectroscopy, and guided wave ultrasound. Benchtop experiments on batteries seeded with lithium chips emulating plating were used to demonstrate the two techniques. The results show the ability to identify and map local changes in cell structure.

Ultrasound↗

NASA NTRS2023

Evaluation of Ultrasonic Battery Inspection Techniques

Ultrasound↗

DOE OSTI2021

Multicriterion Benefit Evaluation of Deploying New Battery Technology with Increased Capacity at a Generic Nuclear Power

Nuclear power plant (NPP) safety improvements are routinely made by plant licensees and regulators. Examples of plant improvements include accident-tolerant fuel, diverse and flexible coping strategies, passive cooling systems, and increased battery capacity. A combined use of these plant improvements could lead to plant designs with enhanced resilience, allowing NPPs to better cope with both internal and external hazards and keep the plant operating safely, efficiently, and economically. This paper focuses on increased battery capacity and evaluates the potential costs and benefits of deploying batteries with increased capacities at a generic boiling water reactor (BWR) NPP. A multicriterion benefit evaluation methodology is used for the cost-benefit analysis. Ten alternatives for extending battery capacity are developed, including nine alternatives to provide additional direct-current power and one alternative to provide additional alternating-current power. Potential benefits of reducing plant risk are quantified through incorporating the alternatives into loss-of-offsite-power scenarios of the generic BWR probabilistic risk assessment model. Potential costs of implementing the alternatives are qualitatively discussed and ranked. The alternatives are then compared based on their impacts on plant risk and economics.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2021

Multicriterion Benefit Evaluation of Deploying New Battery Technology with Increased Capacity at a Generic Nuclear Power Plant

This presentation is prepared for the DOE LWRS RISA Pathway Stakeholder Engagement Meeting on October 13-14, 2021. Nuclear power plant (NPP) safety improvements are routinely made by plant licensees and regulators. Examples of plant improvements include accident-tolerant fuel, diverse and flexible coping strategies, passive cooling systems, and increased battery capacity. A combined use of these plant improvements could lead to plant designs with enhanced resilience, allowing NPPs to better cope with both internal and external hazards and keep the plant operating safely, efficiently, and economically. This presentation focuses on increased battery capacity and evaluates the potential costs and benefits of deploying batteries with increased capacities at a generic boiling water reactor (BWR) NPP. A multicriterion benefit evaluation methodology is used for the cost-benefit analysis. Ten alternatives for extending battery capacity are developed, including eight alternatives to provide additional direct-current power and one alternative to provide additional alternating-current power. Potential benefits of reducing plant risk are quantified through incorporating the alternatives into loss-of-offsite-power scenarios of the generic BWR probabilistic risk assessment model. Potential costs of implementing the alternatives are qualitatively discussed and ranked. The alternatives are then compared based on their impacts on plant risk and economics.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2025

Clean Energy for the Battery-to-EV Supply Chain: A Roadmap for Indonesia - Summary Brief

Indonesia has a unique opportunity to support the clean energy transition, enhance energy security, and spur economic growth with local battery manufacturing, bridging from the material supply all the way to pack designs and, ultimately, the manufacturing of electric cars. Following the elevation of United States and Indonesia relations to a Comprehensive Strategic Partnership, leaders of both countries highlighted the importance of Net Zero World support for Indonesia's energy transition, including collaboration on low-carbon battery supply chains. In support of this agreement, Net Zero World has partnered with Indonesia's Ministry of Energy and Mineral Resources and other Indonesian partners to chart actionable steps for establishing a clean, resilient battery supply chain and circular economy. This partnership aims to position Indonesia as a regional leader in clean energy and can help attract investment in the domestic battery and electric vehicle (EV) sectors.

batteries↗

NASA NTRS2019

Novel Electrolytes for Use in Li-Air Batteries for NASA Electric Aircraft

Li-Air batteries are a unique fit for electric aircraft due to their high theoretical energy densities and their potential to leverage on-board oxygen systems. The electrolyte and cathode are the limiting factors for advancing this technology. We are investigating novel "electrolyte and cathode engineering" concepts to enable Li-Air batteries with high practical energy densities, rechargeability and safety. New stable electrolytes and cathodes are being designed and fabricated for Li-Air batteries. An array of various electrolytes were screened and analyzed using NMR and DEMS analysis techniques to understand the fundamental decomposition mechanisms at the cathode surface and within the porous polymer separator. (NMR) spectroscopy has yielded mechanistic insight into decomposition pathway, which is vital to the development of future stable electrolyte candidates. Thus far, five new electrolytes have been screened with 2 showing promising results.

Li-Air↗

NASA NTRS2021

A Critical Look at Coulomb Counting Approach for State of Charge Estimation in Batteries

In this paper, we consider the problem of state-of-charge estimation for rechargeable batteries. Coulomb counting is a well-known method for estimating the state of charge, and it is regarded as accurate as long as the battery capacity and the beginning state of charge are known. The Coulomb counting approach, on the other hand, is prone to inaccuracies from a variety of sources, and the magnitude of these errors has not been explored in the literature. We formally construct and quantify the state-of-charge estimate error during Coulomb counting due to four types of error sources: (1) current measurement error; (2) current integration approximation error; (3) battery capacity uncertainty; and (4) timing oscillator error/drift. It is demonstrated that the state-of-charge error produced can be either time-cumulative or state-of-charge-proportional. Time-cumulative errors accumulate over time and have the potential to render the state-of-charge estimation utterly invalid in the long term. The proportional errors of the state of charge rise with the accumulated state of charge and reach their worst value within one charge/discharge cycle. The study presents methods for reducing time-cumulative and state-of-charge-proportional mistakes through simulation analysis.

Battery management system↗

DOE OSTI2022

Ion Transport in Batteries with Polymer Electrolytes

We discuss polymer electrolytes for use in rechargeable lithium batteries. Polymer electrolytes have the potential to enable batteries with lithium metal anodes. These batteries have significantly higher theoretical energy densities than current lithium-ion batteries. We consider binary mixtures of polymers and salts. We also cover more complex systems such as polymer electrolytes swollen with a solvent (gel polymer electrolytes) and microphase separated polymer electrolytes. By covalently attaching the anions to the chains in a polymer solid, one obtains a single-ion conductor. We mainly focus on experiments wherein the polymer electrolyte is placed between two lithium metal electrodes. These experiments enable the determination of three transport parameters, ionic conductivity, salt diffusion coefficient, and transference number, and the thermodynamic factor. The properties of dry polymer electrolytes are contrasted with those of gel polymer electrolytes. The gel systems exhibit higher conductivity while the dry systems exhibit superior mechanical properties. We discuss interfacial impedance when lithium metal is contacted with polymer electrolytes and the importance of coulombic efficiency.

Yu, Xiaopeng↗

DOE OSTI2021

Polypeptide-based batteries toward sustainable and cyclic manufacturing

Mass demand for lithium-ion batteries (LIBs) consumes enormous resources, thus having a great impact on the battery supply chain. Here, it is essential to create a sustainable manufacturing cycle for LIBs. Recently in Nature, Wooley and collaborators reported an all-polypeptide organic radical battery, demonstrating the potential of sustainable, recyclable metal-free batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Robust battery interphases from dilute fluorinated cations

Controlling solid electrolyte interphase (SEI) in batteries is crucial for their efficient cycling. Herein, we demonstrate an approach to enable robust battery performance that does not rely on high fractions of fluorinated species in electrolytes, thus substantially decreasing the environmental footprint and cost of high-energy batteries. In this approach, we use very low fractions of readily reducible fluorinated cations in electrolyte (~0.1 wt%) and employ electrostatic attraction to generate a substantial population of these cations at the anode surface. As a result, we can form a robust fluorine-rich SEI that allows for dendrite-free deposition of dense Li and stable cycling of Li-metal full cells with high-voltage cathodes. Our approach represents a general strategy for delivering desired chemical species to battery anodes through electrostatic attraction while using minute amounts of additive.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Designing interphases for practical aqueous zinc flow batteries with high power density and high areal capacity

Aqueous zinc flow batteries (AZFBs) with high power density and high areal capacity are attractive, both in terms of cost and safety. A number of fundamental challenges associated with out-of-plane growth and undesirable side reactions on the anode side, as well as sluggish reaction kinetics and active material loss on the cathode side, limit practical deployment of these batteries. We investigated artificial interphases created using a simple electrospray methodology as a strategy for addressing each of these challenges. The effectiveness of the electrospray interphases in full cell zinc-iodine flow batteries was evaluated and reported; it is possible to simultaneously achieve high power density [115 milliwatts per square centimeter (mW/cm 2 )] and high areal capacity [25 milliampere hour per square centimeter (mA·hour/cm 2 )]. Last, we extended it to aqueous zinc-bromine and zinc-vanadium flow batteries of contemporary interest. It is again found that high power density (255 and 260 mW/cm 2 , respectively) and high areal capacity (20 mA·hour/cm 2 ) can be simultaneously achieved in AZFBs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Elucidating the complex interplay between thermodynamics, kinetics, and electrochemistry in battery electrodes through phase-field modeling

Abstract This article highlights applications of phase-field modeling to electrochemical systems, with a focus on battery electrodes. We first provide an overview on the physical processes involved in electrochemical systems and applications of the phase-field approach to understand the thermodynamic and kinetic mechanisms underlying these processes. We employ two examples to highlight how realistic thermodynamics and kinetics can naturally be incorporated into phase-field modeling of electrochemical processes. One is a composite battery cathode with an intercalation compound (Li x FePO 4 ) as the electrochemically active material, and the other is a displacement reaction compound (Li–Cu–TiS 2 ). With the input parameters mostly from atomistic calculations and experimental measurements, phase-field simulations allowed us to untangle the interactions among transport, reaction, electricity, chemistry, and thermodynamics that lead to highly complex evolution of the materials within battery electrodes. The implications of these observations for battery performance and degradation are discussed. Graphical abstract

Andrews, W. Beck (ORCID:0000000287824621)↗

NASA NTRS1971

Miniature fuel cells relieve gas pressure in sealed batteries

Miniature fuel cells within sealed silver zinc batteries consume evolved hydrogen and oxygen rapidly, preventing pressure rupturing. They do not significantly increase battery weight and they operate in all battery life phases. Complete gas pressure control requires two fuel cells during all phases of operation of silver zinc batteries.

Frank, H. A.↗

NASA NTRS1972

Development and testing of a high cycle life 30 A-h sealed AgO-Zn battery

A two-phase program was initiated to investigate design parameters and technology to develop an improved AgO-Zn battery. The basic performance goal was 100 charge/discharge cycles (22 h/2 h) at 50 percent depth of discharge following a six-month period of charged stand at room temperature. Phase 1, cell evaluation, involved testing 70 cells in five-cell groups. The major design variables were active material ratios, electrolyte concentrations, separator systems, and negative plate shape. Phase 1 testing showed that cycle life could be improved 10 percent to 20 percent by using greater ratios of zinc to silver oxide and higher electrolyte concentrations. Wedge-shaped negatives increased cycle life by nearly 100 percent. Phase 2 battery evaluation, which was initiated before the Phase 1 results were known completely, involved evaluation of six designs as 19-cell batteries. Only one battery exceeded 100 cycles following nine months charged stand.

Bogner, R. S.↗

NASA NTRS1972

Nonleaking battery terminals.

Three different terminals were designed for usage in a 40 ampere/hour silver zinc battery which has a 45% KOH by weight electrolyte in a plastic battery case. Life tests, including thermal cycling, electrical charge and discharge for up to three years duration, were conducted on these three different terminal designs. Tests for creep rate and tensile strength were conducted on the polyphenylene oxide plastic battery cases. Some cases were unused and others containing KOH electrolyte were placed on life tests. The design and testing of nonleaking battery terminals for use with a KOH electrolyte in a plastic case are considered.

Snider, W. E.↗

NASA NTRS1976

The requirements for batteries for electric vehicles

Analysis of automobile use patterns shows that the battery requirements for an urban car can be met by mid-term battery technology. The far-term technology potentially offers greater range but does not proportionately increase the usefulness of the vehicle. This suggests that emphasis should be shifted toward more modest energy density goals, if such a shift would ease technical problems and allow the use of lower cost materials and construction methods. A technology diffusion model indicates that the impact of the mid-term batteries by the year 2000 would be greater than that of the far-term batteries because of their earlier introduction and nearly equal market potential. From the standpoint of maximizing both the cumulative impact and the benefits derived in the year 2000, however, a strategy of early introduction of near-term and mid-term cars followed by the far-term vehicle would produce the optimum results.

Schwartz, H. J.↗

NASA NTRS1977

SMS/GOES cell and battery data analysis report

The nickel-cadmium battery design developed for the Synchronous Meteorological Satellite (SMS) and Geostationary Operational Environmental Satellite (GOES) provided background and guidelines for future development, manufacture, and application of spacecraft batteries. SMS/GOES battery design, development, qualification testing, acceptance testing, and life testing/mission performance characteristics were evaluated for correlation with battery cell manufacturing process variables.

Armantrout, J. D.↗

NASA NTRS1977

Applications technology satellites battery and power system design

A summary of the ATS battery design which is onboard the Applications Technology Satellite (ATS) is provided. The 15 ampere hour nickel cadmium cells were manufactured by Gulton, 19 series connected cells per battery, and there are two batteries in each spacecraft. The operating design life was two years in a synchronous orbit, and a maximum depth of discharge of 50 percent. The design temperature for the batteries in the spacecraft was 0 to 25 C, and the charge control consisted of 1 volt versus temperature on a constant percentage voltage. Also, C/10 current limit, and a commandable trickle charge rate, using C/20 or C/60. The undervoltage was sent across a 9 cell and a 10 cell group, and it was set at one volt average per group on either group.

Ford, F. E.↗