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Zhang, Siyao

Publications and source records attributed to Zhang, Siyao.

Nucleon-Pair Shell Model within a Symmetry Broken Basis

The nucleon-pair shell model (NPSM) within the framework of a broken symmetry basis is studied. The results demonstrate the validity of such a scheme, which in turn leads to a significant reduction in the dimensionality of the multi-pair configuration space. Specifically, in the case of an axially-deformed basis, the results yield a satisfactory description of the low-lying spectrum, even without the need for applying the projection procedure. In the case of a triaxially-deformed basis, the result of variation after angular momentum projection suggest a potential for using the NPSM to find exact solutions in a semi-magic system.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate

Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.

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