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Zahnle, Kevin J.

Publications and source records attributed to Zahnle, Kevin J..

Limits to Creation of Oxygen-Rich Atmospheres on Planets in the Outer Conventional Habitable Zone

Why Earth has an oxygen-rich atmosphere is not a solved problem, although the crucial importance of O2 to life on Earth, and its generation by life on Earth, are unquestioned. The factors that promote or frustrate the generation of free oxygen are central to what we mean by habitability, because it is O2 that makes a world fit for creatures like us attending conferences like these. The astronomical mission to identify and characterize an inhabited planet remains justifiably focused on the quest to detect O2 (or its byproduct O3) because free oxygen remains the bronze standard of habitation as we know it. We can expect that eventually, perhaps within 100 years, we will have accumulated a database of such exoplanets and we will begin to be able to evaluate basic hypotheses regarding the origin of oxygen (if not the origin of life).

Zahnle, Kevin J.↗

Methane, Carbon Monoxide, and Ammonia in Brown Dwarfs and Self-Luminous Giant Planets

We address disequilibrum abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based 1D atmospheric chemistry model. Our approach is to use the full kinetics model to survey the parameter space with effective temperatures between 500 K and 1100 K. In all of these worlds equilibrium chemistry favors CH4 over CO in the parts of the atmosphere that can be seen from Earth, but in most disequilibrium favors CO. The small surface gravity of a planet strongly discriminates against CH4 when compared to an otherwise comparable brown dwarf. If vertical mixing is like Jupiter's, the transition from methane to CO occurs at 500 K in a planet. Sluggish vertical mixing can raise this to 600 K; clouds or more vigorous vertical mixing could lower this to 400 K. The comparable thresholds in brown dwarfs are 1100±100 K. Ammonia is also sensitive to gravity, but unlike CH4/CO, the NH3/N2 ratio is insensitive to mixing, which makes NH3 a potential proxy for gravity. HCN may become interesting in high gravity brown dwarfs with very strong vertical mixing. Detailed analysis of the CO-CH4 reaction network reveals that the bottleneck to CO hydrogenation goes through methanol, in partial agreement with previous work. Simple, easy to use quenching relations are derived by fitting to the complete chemistry of the full ensemble of models. These relations are valid for determining CO, CH4, NH3, HCN, and CO2 abundances in the range of self-luminous worlds we have studied but may not apply if atmospheres are strongly heated at high altitudes by processes not considered here (e.g., wave breaking).

Planets and satellites↗

Characterizing Uranus with an Ice giant Planetary Origins Probe (Ice-POP)

We now know from studies of planetary transits and microlensing that Neptune-mass planets are ubitquitous and may be the most common class of planets in the Galaxy. As such it is crucial that we understand the formation and evolution of the ice giant planets in our own solar system so that we can better understand planet formation throughout the galaxy. An entry probe mission to Uranus would help accomplish this goal. In fact the Planetary Decadal Survey recommended a Uranus orbiter with entry probe but did not explore in detail the specifications for the entry probe. NASA Ames is currently studying thermal protection system requirements for such a mission and this has led to questions regarding the minimum interesting science payload of such an entry probe. The single most important in-situ measurement for an ice giant entry probe is a measurement of atmospheric composition. For Uranus this would specifically include the methane and noble gas abundances. An in situ measurement of the methane abundance, from below the methane cloud, would constrain the atmospheric carbon abundance, which is believed to be roughly 30 to 50 times solar. There are hints from the transiting planets that extrasolar ice giants show comparable or even greater enhancements of heavy elements compared to their primary stars. However the origin of this carbon enhancement is controversial. Is Uranus a "failed core" of a larger gas giant or was the atmosphere enhanced by accretion of icy planetesimals' Constraining atmospheric abundances of C and perhaps S or even N from below 5 bars would provide badly needed data to address such issues. A measurement of the N abundance would provide clues on the origin of the planetesimals that formed Uranus. Low N-abundance indicates planetesimals from 'warmer' regions where N was mainly in form of NH3, whereas a strong enrichment could indicate planetesimals / cometary material from the colder outer regions of the nebula. Furthermore CO and HCN have been detected in Neptune but not in Uranus. A measurement of the abundance of either would constrain the source mechanisms for these molecules (exogenic or internal). A major surprise from the Galileo Entry Probe was that the heavier noble gases Ar, Kr, and Xe are enhanced in Jupiter's atmosphere at a level comparable to what was seen for the chemically active volatiles N, C, and S. It had been generally expected that Ar, Kr, and Xe would be present in solar abundances, as all were expected to accrete with hydrogen during the gravitational capture of nebular gases. Enhanced abundances of Ar, Kr, and Xe is equivalent to saying that these noble gases have been separated from hydrogen. There are several mechanisms that could accomplish this but these hypotheses require further testing. Measurement of noble gas abundances in an ice giant would constrain the planetary formation and nebular mechanisms responsible for this enhancement. Standard three-layer models of Uranus find that the outer, predominantly H/He layer of Uranus does not reach pressures high enough (approximately 1 Mbar) for H2 to transition to liquid metallic hydrogen. However, valid models can also be constructed with a smaller intermediate water-rich layer, with hydrogen then reaching the metallic hydrogen phase. If this occurs, He should phase separate from the hydrogen and ``rain out," taking along a substantial abundance of Ne, as suggested for Jupiter (and likely also for Saturn). Hence He and Ne depletions could be probes of the planet's structure in the much deeper interior. A determination of Uranus' atmospheric abundances, particularly of the noble gasses, is thus critical to understanding the formation of Uranus, and giant planets in general. These measurements can only be performed with an entry probe. The second key measurement would be a temperature-pressure sounding to provide ground truth for remote measurements of atmospheric temperature and composition and to constrain the internal heat flow. This would also establish that the methane abundance measurements have indeed been made below any possible methane cloud. Finally an ultra stable oscillator would measure wind speeds and constrain atmospheric dynamics. In our presentation we will discuss the importance of all of these measurements and argue that an entry probe is a crucial component of any ice giant mission.

Marley, Mark S.↗

Transient Climate Effects of Large Impacts on Titan

Titan's thick atmosphere and volatile-rich surface cause it to respond to big impacts in a somewhat Earth-like manner. Here we construct a simple globally-averaged model that tracks the flow of energy through the environment in the weeks, years, and millenia after a big comet strikes Titan. The model Titan is endowed with 1.4 bars of N2 and 0.07 bars of CH4, methane lakes, a water ice crust, and enough methane underground to saturate the regolith to the surface. We find that a nominal Menrva impact is big enough to raise the surface temperature by approx. 80 K and to double the amount of methane in the atmosphere. The extra methane drizzles out of the atmosphere over hundreds of years. An upper-limit Menrva is just big enough to raise the surface to water's melting point. The putative Hotei impact (a possible 800-1200 km diameter basin, Soderblom et al., 2009) is big enough to raise the surface temperature to 350-400 K. Water rain must fall and global meltwaters might range between 50 m to more than a kilometer deep, depending on the details. Global meltwater oceans do not last more than a few decades or centuries at most, but are interesting to consider given Titan's organic wealth. Significant near-surface clathrate formation is possible as Titan cools but faces major kinetic barriers.

Titan↗

The Cosmic Shoreline

Volatile escape is the classic existential problem of planetary atmospheres. The problem has gained new currency now that we can study the cumulative effects of escape from extrasolar planets. Escape itself is likely to be a rapid process, relatively unlikely to be caught in the act, but the cumulative effects of escape in particular, the distinction between planets with and without atmospheres should show up in the statistics of the new planets. The new planets make a moving target. It can be difficult to keep up, and every day the paper boy brings more. Of course most of these will be giant planets loosely resembling Saturn or Neptune albeit hotter and nearer their stars, as big hot fast-orbiting exoplanets are the least exceedingly difficult to discover. But they are still planets, all in all, and although twenty years ago experts could prove on general principles that they did not exist, we have come round rather quickly, and they should be welcome now at LPSC. Here we will discuss the empirical division between planets with and without atmospheres. For most exoplanets the question of whether a planet has or has not an atmosphere is a fuzzy inference based on the planet's bulk density. A probably safe presumption is that a low density planet is one with abundant volatiles, in the general mold of Saturn or Neptune. On the other hand a high density low mass planet could be volatile-poor, in the general mold of Earth or Mercury. We will focus on planets, mostly seen in transit, for which both radius and mass are measured, as these are the planets with measured densities. More could be said: a lot of subtle recent work has been devoted to determining the composition of planets from equations of state or directly observing atmospheres in transit, but we will not go there. What interests us here is that, from the first, the transiting extrasolar planets appear to have fit into a pattern already seen in our own Solar System, as shown in Fig. 1. We first noticed this in 2004 when there were just two transiting exoplanets to consider. The trend was well-defined by late 2007. Figure 1 shows how matters stood in Dec 2012 with approx.240 exoplanets. The figure shows that the boundary between planets with and without active volatiles - the cosmic shoreline, as it were - is both well-defined and follows a power law.

Zahnle, Kevin J.↗

Xenological constraints on the impact erosion of the early Martian atmosphere

This paper considers impact erosion as the agent of the early Martian atmophere escape, by examining xenon-related constraints imposed on the impact erosion. It is found that, if impact erosion of a planetary atmosphere is important, the remnant atmosphere is likely to fall into one of two qualitatively distinct categories: (1) cometary xenon has an unexpected isotopic composition or (2) factors other than impacts, such as outgassing or recycling, are needed. Neither of these categories can readily account for the present Martian atmosphere.

Zahnle, Kevin J.↗

The 1908 Tunguska explosion - Atmospheric disruption of a stony asteroid

The explosion over Tunguska, Central Siberia, in 1908 released 10 to 20 megatons (high explosive equivalent) of energy at an altitude of about 10 km. This event represents a typical fate for stony asteroids tens of meters in radius entering the Earth's atmosphere at common hypersonic velocities. Comets and carbonaceous asteroids of the appropriate energy disrupt too high, whereas typical iron objects reach and crater the terrestrial surface.

Chyba, Christofer F.↗

Airburst origin of dark shadows on Venus

The Magellan images showed presence of radar-dark shadowlike disks surrounding small impact craters on the Venusian surface, which are also found without craters. This paper examines the hypothesis of Phillips et al. (1991) that the dark shadows formed where shock waves from airbursting impactors met the ground, pulverizing decimeter-scale surface features. A simple analytic model is used successfully to simulate the catastrophic disruption and the deceleration of impactors in a thick atmosphere to reproduce observed Venusian cratering statistics and generate radar-dark disks by the impact of atmospheric shock waves on the surface.

Zahnle, Kevin J.↗

Annihilation of ecosystems by large asteroid impacts on the early earth

Large asteroid impacts produced globally lethal conditions by evaporating large volumes of ocean water on the early earth. The earth may have been continuously habitable by ecosystems that did not depend on photosynthesis as early as 4.44 Gyr BP (before present). Only a brief interval after 3.8 Gyr exists between the time when obligate photosynthetic organisms could continuously evolve and the time when the palaeontological record indicates highly evolved photosynthetic ecosystems.

Sleep, Norman H.↗

Evolution of a steam atmosphere during earth's accretion

The evolution of an impact-generated steam atmosphere around an accreting earth is presently modeled under the assumption of Safronov (1978) accretion, in a scheme that encompasses the degassing of planetesimals on impact, thermal blanketing by the steam atmosphere, surface-to-interior water exchange, the shock heating and convective cooling of the earth's interior, and hydrogen escape due both to solar EUV-powered planetary wind and impact erosion. The model yields four distinct classes of impact-generated atmospheres: the first, on which emphasis is placed, has as its salient feature a molten surface that is maintained by the opacity of a massive water vapor atmosphere; the second occurs when the EUV-limited escape exceeds the impact degassing rate, while the third is dominated by impact erosion and the fourth is characterized by an atmosphere more massive than any thus far encountered.

Zahnle, Kevin J.↗

Mass fractionation during transonic escape and implications for loss of water from Mars and Venus

Hydrodynamic escape of hydrogen from a planetary atmosphere can remove heavier gases as well as hydrogen, provided that the escape rate is sufficiently large. Analytic approximations for the degree of mass fractionation of a trace species during hydrodynamic escape are compared with accurate numerical solutions for the case of transonic outflow. The analytic approximations are most accurate when the ratio of molecular weights of the heavier and lighter constituents is large so that nonlinear terms in the momentum equation for the heavy constituent become small. The simplest analytic formula is readily generalized to the case where a heavy constituent is also a major species. Application of the generalized formula to hypothetical episodes of hydrodynamic escape from Venus and Mars suggests that both hydrogen and oxygen could have escaped; thus, substantial quantities of water may have been lost without the need to oxidize large amounts of the crust.

Zahnle, Kevin J.↗