Engineering topics
Publications and source records attributed to Yung, Y. L..
The greenhouse effect due to nitrous oxide in the present atmosphere is about 0.8 K. Increase in atmospheric N2O due to perturbation of the nitrogen cycle by man may lead to an increase in surface temperature as large as 0.5 K by 2025, or 1.0 K by 2100. Other climatic effects of N2O are briefly discussed.
We describe a method for calculating directly the mean integrated intensity in an inhomogeneous Rayleigh scattering atmosphere using a combined variational and iterative technique. This method is particularly useful for computing dissociation rates in aeronomical problems. Simple semi-analytic expressions are derived.
The paper presents a quantitative theory of line formation in an atmosphere above a surface with backscattering properties. Sufficiently high spatial and spectral resolution spectra of resonance lines in Io region A can yield data on the surface scattering properties as well as the number density of scattering molecules. Macroscopically homogeneous models of scattering from the surface of Io are discussed, and it is concluded that multiple reflection from crystal facets is the most likely cause for the observed geometric albedo and phase variation.
Observations of the temporal and spatial distribution of N2O in solution are not yet sufficient to permit quantitative assessment of the role of the ocean in the budget of atmospheric N2O. Consideration of the global nitrogen cycle suggests that the land should be the primary source of N2O. The gas is removed in the atmosphere by photolysis and by reaction with O(1D), and there may be additional sinks in the ocean.
The paper outlines current understanding of phenomena associated with Io's atmosphere and optical emissions, along with a review of their relationships. The discussion covers the sodium D-line emission from Io, the ultraviolet emission observed from Pioneer 10, other optical emission lines, and future observational work on Io's line emission. Analysis of Io's ionosphere indicates that the atmosphere may be cooler than the observed sodium and that the exobase probably stands well above Io's surface. Also discussed is Io as a source of hydrogen and as a source of sodium. The observed electron profiles and the constraints provided by the emission cloud are consistent with two models of Io's neutral atmosphere. In the first model, hydrogen is supplied by dissociation of ammonia, whereas proton charge exchange is the primary source of hydrogen in the second model. Both models have the common feature that meteoritic impact or sputtering of the surface provides a source for sodium.
Bleaching of paper pulp represents a major industrial use of chlorine and could provide an environmentally significant source of atmospheric halocarbons. The related global production of chloroform is estimated at 300,000 ton per year and there could be additional production associated with atmospheric decomposition of perchloroethylene. Estimates are given for the production of methyl chloride, methyl bromide and methyl iodide, 5.2 million, 77 thousand, and 740 thousand ton per year respectively. The relative yields of CH3Cl, CH3Br and CH3I are consistent with the hypothesis of a marine biological source for these compounds. Concentrations of other halocarbons observed in the atmosphere appear to indicate industrial sources.
Bromine may act as a catalyst for recombination of ozone and could be more efficient than either nitric oxide or chlorine. The lower atmosphere contains small concentrations of gaseous bromine produced in part by marine activity and volatilization of particulate material released during the combustion of leaded gasoline, with an additional contribution due to the use of methyl bromide as an agricultural fumigant. Observations by Lazrus et al., (1975) indicate small concentrations of bromine, about 10 to the -11th power (v/v), in the contemporary stratosphere and appear to imply a reduction of approximately 0.3% in the global budget of O3. Estimates are given for future reductions in O3 which might occur if the use of CH3Br as an agricultural fumigant were to continue to grow at present rates.
Models for Jupiter's innermost Galilean satellite's atmosphere, ionosphere, and sodium airglow are developed on the basis of recent observational data. The sodium emission detected by Brown (1973) is seen to require a collisional excitation process in Io's atmosphere, while the extended sodium emission measured by Trafton et al. (1974) may require scattering of the planetary radiation by an extended sodium cloud. The sodium is presumably present in bound form on Io's surface, and may be released by a sputtering mechanism proposed by Matson et al. (1974). The ionosphere detected by a radio occultation experiment on Pioneer 10 could be attributed to photoionization of atmospheric sodium, provided Io's atmosphere could sustain significant upward motions during daytime and downward motions during nighttime. The incomplete hydrogen torus observed by Judge and Carlson (1974) in the vicinity of Io appears to require a large supply of hydrogen from the satellite's atmosphere. Implications of the hydrogen torus for the energy and mass balance of Jupiter's magnetosphere are discussed.
A quantitative theory is given for line formation in an atmosphere above a surface with backscattering properties. Sufficiently high spatial and spectral resolution spectra of resonance lines in Io region A can yield data on the surface scattering properties as well as the number density of scattering molecules. Macroscopically homogeneous models of scattering from the surface of Io are discussed and it was concluded that multiple reflection from crystal facets is the most likely cause for the observed phase variations of the geometric albedo.