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Yu, Tony

Publications and source records attributed to Yu, Tony.

Sound Velocities of Stishovite at Simultaneous High Pressure and High Temperature Suggest an Eclogite‐Rich Layer Beneath the Hawaii Hotspot

Compressional and shear wave velocities of polycrystalline stishovite (SiO 2 ) have been measured at simultaneous high pressures and temperatures up to 14.5 GPa and 800°C. By fitting velocities to the finite strain equations, the elastic moduli and density were determined to be K S0 = 306.6(46) GPa, $K$$^{′}_{S}$ = 4.92(10), ∂K S /∂T = −0.024(1) GPa/K, G 0 = 229.0(34) GPa, G′ = 1.07(10), ∂G/∂T = −0.017(1) GPa/K, ρ 0 = 4.287(2) g/cm 3 . Our modeling suggested that, in the eclogite, coesite-stishovite transition can increase P and S wave velocities by 2.4% and 3.5%, respectively. A comparison between geophysical observations and our model shows that the coesite-stishovite phase transition in the eclogite can potentially be responsible for the occurrence of the X discontinuity beneath Hawaii. In addition, our current results suggest an eclogite-rich layer between 340 and 450 km depth beneath Hawaii. The eclogite concentration at the top and bottom of the layer is 41–55 vol% and >77 vol%, respectively.

36 MATERIALS SCIENCE↗

Transformational faulting in Mn 2 GeO 4 from olivine to wadsleyite structure: Implications for physical mechanism of deep-focus earthquakes

High-pressure and temperature deformation experiments interfaced with acoustic emission (AE) monitoring have been conducted to study transformational faulting in Mn 2 GeO 4 olivine, which transforms to the β phase, isostructural to wadsleyite. Metastable Mn 2 GeO 4 olivine exhibits a marked embrittlement behavior at temperatures between 800 and 1100 K, emitting numerous AEs. At each temperature, brittle deformation is characterized by a two-stage process: (1) a “preparation” stage with numerous diffusedly located low-magnitude AEs and large b values (>2), and (2) a failure stage where larger-magnitude AEs form a planar distribution with b values about 1. Microstructure analysis reveals extensive kink band development in olivine grains in the recovered samples. Kink band boundaries (KBBs), with a typical thickness of ∼100 nm, are filled with a nanometric β-Mn 2 GeO 4 “gouge”. A dense array of secondary shear localizations is often present within the kink bands, suggesting significant shear deformation therein. The combined observations suggest that faulting in metastable Mn 2 GeO 4 olivine is a self-similar process, from grain-scale to the sample-scale. Both observed embrittlement behavior and the microstructure of metastable Mn 2 GeO 4 olivine are essentially identical to those in Mg 2 GeO 4 olivine we have reported previously, indicating that the physical mechanism of faulting in metastable olivine is insensitive to the specific crystallographic structure of the high-pressure phase. The low b values (about 1) observed in the faulting process in our experiments are similar to those of deep focus earthquakes in cold subduction zones. Our observed mechanism explains deep focus seismicity in cold metastable mantle wedges, provided that the self-similarity assumption holds to geological scales.

58 GEOSCIENCES↗

Reassessment of Birch's Law on hcp‐Fe From Ultrasonic Sound Velocity Measurement and Implications on the Velocity Profiles of Earth's Inner Core

Here, we performed in situ X-ray diffraction and ultrasonic sound velocity measurements on hcp-Fe up to 15 GPa, 873 K in a multi-anvil apparatus. The elastic moduli and their pressure and temperature derivatives were determined by fitting the velocity and density data to the third-order finite strain equations, yielding K S0 = 169.0(57) GPa, K$^{′}_{S0}$ = 5.4(6), (∂K S /∂T) P = −0.031(3) GPa/K, G 0 = 104.5(27) GPa, G$^{′}_{0}$ = 1.7(2), (∂G/∂T) P = −0.060(2) GPa/K. Within the experimental P-T range, we find significant temperature effect on the density-velocity (ρ − V P or S ) relations and caution the use of the temperature-independent Birch's law for extrapolation to core conditions. Furthermore, temperature-induced velocity decrease is more significant in V S than in V P , offering a possible explanation for the high Poisson's ratio in the core. Extrapolations based on our results together with previous experimental data suggest that V P of hcp-Fe aligns with PREM at Earth's core conditions, while Vs and density are approximately 10% and 2.7% higher than PREM, respectively.

36 MATERIALS SCIENCE↗

Viscosity Measurements at High Pressures: A Critical Appraisal of Corrections to Stokes' Law

Abstract Fluids and melts in planetary interiors significantly influence geodynamic processes from volcanism to global‐scale differentiation. The roles of these geofluids depend on their viscosities ( η ). Constraining geofluid η at relevant pressures and temperatures relies on laboratory‐based measurements and is most widely done using Stokes' Law viscometry with falling spheres. Yet small sample chambers required by high‐pressure experiments introduce significant drag on the spheres. Several correction schemes are available for Stokes' Law but there is no consensus on the best scheme(s) for high‐pressure experiments. We completed high‐pressure experiments to test the effects of (a) the relative size of the sphere diameter to the chamber diameter and (b) the top and bottom of the chamber, that is, the ends, on the sphere velocities. We examined the influence of current correction schemes on the estimated viscosity using Monte Carlo simulations. We also compared previous viscometry work on various geofluids in different experimental setups/geometries. We find the common schemes for Stokes' Law produce statistically distinct values of η . When inertia of the sphere is negligible, the most appropriate scheme may be the Faxén correction for the chamber walls. Correction for drag due to the chamber ends depends on the precision in the sinking distance and may be ineffective with decreasing sphere size. Combining the wall and end corrections may overcorrect η . We also suggest the uncertainty in η is best captured by the correction rather than propagated errors from experimental parameters. We develop an overlying view of Stokes' Law viscometry at high pressures.

Geochemistry & Geophysics↗

Compact Coherent Laser Ranging (CCLR)

Presents a design to develop a Compact Coherent Laser Ranging with the following goals: Match the performance as GRACE-FO, with much reduced SWaP to fit on mini-Sat or CubeSat; Enables low cost and more frequent LL-SST gravitational missions; Immunes from ionosphere propagation delay with optical ranging; Increases the body pointing capability due to small satellite.

photon counting detector↗