Non-fullerene acceptors with direct and indirect hexa-fluorination afford >17% efficiency in polymer solar cells
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Engineering topics
Publications and source records attributed to Young, R..
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The NASA supported High-Altitude Calibration (HiCal)-2 instrument flew as a companion balloon to the ANITA-4 experiment in December 2016. Based on a high-voltage (HV) discharge pulser producing radio-frequency (RF) calibration pulses, HiCal-2 comprised two payloads, which flew for a combined 18 days, covering 1.5 revolutions of the Antarctic continent. ANITA-4 captured over 10,000 pulses from HiCal-2, both direct and reflected from the surface, at distances varying from 100–700 km, providing a large dataset for surface reflectivity measurements. In view of this, we present details on the design, construction and performance of HiCal-2.
We report that the balloon-borne HiCal radio-frequency (RF) transmitter, in concert with the ANITA radio-frequency receiver array, is designed to measure the Antarctic surface reflectivity in the RF wavelength regime. The amplitude of surface-reflected transmissions from HiCal, registered as triggered events by ANITA, can be compared with the direct transmissions preceding them by O(10) microseconds, to infer the surface power reflection coefficient R. The first HiCal mission (HiCal-1, Jan. 2015) yielded a sample of 100 such pairs, resulting in estimates of R at highly glancing angles (i.e., zenith angles approaching 90°), with measured reflectivity for those events which exceeded extant calculations [P. W. Gorham et al., Journal of Astronomical Instrumentation, 1740002 (2017)]. The HiCal-2 experiment, flying from December 2016–January 2017, provided an improvement by nearly 2 orders of magnitude in our event statistics, allowing a considerably more precise mapping of the reflectivity over a wider range of incidence angles. We find general agreement between the HiCal-2 reflectivity results and those obtained with the earlier HiCal-1 mission, as well as estimates from Solar reflections in the radio-frequency regime [D. Z. Besson et al., Radio Sci. 50, 1 (2015)]. In parallel, our calculations of expected reflectivity have matured; herein, we use a plane-wave expansion to estimate the reflectivity R from both a flat, smooth surface (and, in so doing, recover the Fresnel reflectivity equations) and also a curved surface. Lastly, multiplying our flat-smooth reflectivity by improved Earth curvature and surface roughness corrections now provides significantly better agreement between theory and the HiCal-2 measurements.
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Monoenergetic-proton radiographs of laser-generated, high-Mach-number plasma jets colliding at various angles shed light on the structures and dynamics of these collisions. The observations compare favorably with results from 2D hydrodynamic simulations of multistream plasma jets, and also with results from an analytic treatment of electron flow and magnetic field advection. In collisions of two noncollinear jets, the observed flow structure is similar to the analytic model’s prediction of a characteristic feature with a narrow structure pointing in one direction and a much thicker one pointing in the opposite direction. Spontaneous magnetic fields, largely azimuthal around the colliding jets and generated by the well-known ∇T e ×∇n e Biermann battery effect near the periphery of the laser spots, are demonstrated to be “frozen in” the plasma (due to high magnetic Reynolds number R M ~5×10⁴) and advected along the jet streamlines of the electron flow. These studies provide novel insight into the interactions and dynamics of colliding plasma jets.
Solar sails can play a critical role in enabling solar and heliophysics missions. Solar sail technology within NASA is currently at 80% of TRL-6, suitable for an in-flight technology demonstration. It is conceivable that an initial demonstration could carry scientific payloads that, depending on the type of mission, are commensurate with the goals of the three study panels of the 2010 Heliophysics Survey. Follow-on solar sail missions, leveraging advances in solar sail technology to support Heliophysics Survey goals, would then be feasible. This white paper reports on a sampling of missions enabled by solar sails, the current state of the technology, and what funding is required to advance the current state of technology such that solar sails can enable these missions
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Many major questions about the Venus stratosphere are still unanswered.
In spite of intensive ground-based and space observations, many major questions about the Venus stratosphere are still unanswered.
Hydrazine (HZ) and monomethylhydrazine (MMH) in air were monitored continuously using a hand-held ion mobility spectrometer equipped with membrane inlet, 63Ni ion source, acetone reagent gas, and ambient temperature drift tube. Response characteristics included detection limit, 6 ppb; linear range, 10-600 ppb; saturated response, >2 ppm; and stable response after 15-30 min. Ammonia interfered in hydrazines detection through a product ion with the same drift time as that for MMH and HZ. Acetone reagent gas was replaced with 5-nonanone to alter drift times of product ions and separate ammonia from MMH and HZ. Patterns in mobility spectra, ion identifications from mass spectra, and fragmentation cross-sections from collisional-induced dissociations suggest that drift times are governed by ion-cluster equilibria in the drift region of the mobility spectrometer. Practical aspects including calibration, stability, and reproducibility are reported from the use of a hand-held mobility spectrometer on the space shuttle Atlantis during mission STS-37.
The Galileo Mission, rather than a 'Jupiter mission' per se, is an integrated project encompassing multidisciplinary objectives regarding the whole of the Jovian system. This system is important in view of insights it affords into the conditions of the early solar nebula, as well as into the complex, interacting processes involved in planetary evolution. Jupiter itself is the focus of interest in virtue of representing a transitional object between the terrestrial planets and stars; its composition may be virtually unaltered from that of the original solar nebula. The Jovian system in its entirety presents basic questions regarding its satellite and ring system, which constitute a 'minisolar system'. The Galileo spacecraft consists of an Orbiter and an atmospheric entry Probe.
The recent Voyager flyby of Uranus and Neptune has provided refined values for the gravitational moments and rotation periods of those planets. Using these new parameters, models of the interiors of these planets show that their density distributions are very similar. This lends support to the conjecture that their compositions are similar as well. The models are indeed consistent with such a conjecture. The difference in the internal heat sources of these two planets may be due to the fact that heat transport from the interior of Uranus is inhibited by a statically stable interior.
During the Vega Venus balloon mission, data on the thermodynamic state of the atmosphere were obtained as well as wind and cloud information. Explanations are provided for the following: (1) the large amplitude atmospheric vertical winds encountered by the Vega balloons, (2) the observed 6.5 K temperature difference consistently measured between the two Vega balloons, and (3) the apparent influence of surface topography on atmospheric motions seen by the Vega-2 balloon as it flew over mountainous terrain (known as Aphrodite). It is believed that vertical winds of the magnitude encountered by the Vega-2 balloon over Aphrodite may be the result of surface-induced gravity waves.
Laminar flow offers the promise of significant fuel savings on future commercial transport aircraft, but laminar flow can be lost while encountering clouds or haze at cruise conditions. To quantify the effect of cloud particles on laminar flow during typical airline operating conditions, and evaluate candidate cloud particle detection instrument concepts for future laminar flow aircraft, two types of cloud particle detectors are being flown aboard a NASA JetStar aircraft in the Leading Edge Flight Test (LEFT) program. The instrumentation is described, and preliminary results and conclusions are presented.
An analysis of the difference between the interior structures of Uranus and Neptune is presented, based on models which fit the observed mass, radius, and gravitational moments for the assumed rotation periods of these planets. If Uranus and Neptune are assumed to be as similar in internal structure as they are in mass and radius, the rotation period for Neptune must be shorter than that for Uranus. It is suggested that the true rotation period is given by Neptune's oblateness, while the photometric period corresponds to the motion of Rossby waves in the upper atmosphere.