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Young, J. W.

Publications and source records attributed to Young, J. W..

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Infrared spectroscopy of the methanol cation and its methylene-oxonium isomer

The carbenium ion with nominal formula [C,H{sub 4},O]{sup +} is produced from methanol or ethylene glycol in a pulsed-discharge supersonic expansion source. The ion is mass selected, and its infrared spectrum is measured from 2000 to 4000 cm{sup −1} using laser photodissociation spectroscopy and the method of rare gas atom tagging. Computational chemistry predicts two isomers, the methanol and methylene-oxonium cations. Predicted vibrational spectra based on scaled harmonic and reduced dimensional treatments are compared to the experimental spectra. The methanol cation is the only isomer produced when methanol is used as a precursor. When ethylene glycol is used as the precursor, methylene-oxonium is produced in addition to the methanol cation. Theoretical results at the CCSD(T)/cc-pVTZ level show that methylene-oxonium is lower in energy than methanol cation by 6.4 kcal/mol, and is in fact the global minimum isomer on the [C,H{sub 4},O]{sup +} potential surface. Methanol cation is trapped behind an isomerization barrier in our source, providing a convenient method to produce and characterize this transient species. Analysis of the spectrum of the methanol cation provides evidence for strong CH stretch vibration/torsion coupling in this molecular ion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Infrared spectroscopy of the acetyl cation and its protonated ketene isomer

[C{sub 2},H{sub 3},O]{sup +} ions are generated with a pulsed discharge in a supersonic expansion containing methyl acetate or acetone. These ions are mass selected and their infrared spectra are recorded via laser photodissociation and the method of argon tagging. Computational chemistry is employed to investigate structural isomers and their spectra. The acetyl cation (CH{sub 3}CO{sup +}) is the global minimum and protonated ketene (CH{sub 2}COH{sup +}) is the next lowest energy isomer (+176.2 kJ/mol). When methyl acetate is employed as the precursor, the infrared spectrum reveals that only the acetyl cation is formed. Partially resolved rotational structure reveals rotation about the C{sub 3} axis. When acetone is used as the precursor, acetyl is still the most abundant cation, but there is also a minor component of protonated ketene. Computations reveal a significant barrier to interconversion between the two isomers (+221 kJ/mol), indicating that protonated ketene must be obtained via kinetic trapping. Both isomers may be present in interstellar environments, and their implications for astrochemistry are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Asteroid lightcurve observations from 1981

Photoelectric lightcurve observations in the V band, together with estimates of the mean and maximum reduced magnitudes, are presented for 59 different asteroids; 15 new or significantly revised periods are reported. While fits are generally good for objects with moderate phase-relation slope, poor quality fits remain among the highest and lowest albedo objects studied in virtue of their respectively shallow and steep sloping-phase curves.

Harris, A. W.↗
NASA NTRS1989

Asteroid lightcurve observations from 1979-1981

An account is given of the results of photometric light curve observations in the V band for asteroids, yielding estimates of the mean and maximum reduced magnitudes for each object. On the basis of fits of the H-G magnitude relation for 33 objects, the mean values of the slope parameter are examined for different taxonomic classes; these values are then applied to the analysis of less complete data sets. While in the case of the moderate albedo S and M class asteroids the H-G relation appears to fit the available data, the relation for dark asteroids appears to predict more of an opposition than is characteristically present.

Harris, A. W.↗
NASA NTRS1989

Phase relations of high albedo asteroids - The unusual opposition brightening of 44 Nysa and 64 Angelina

The present photoelectric lightcurve observations of 44 Nysa at one aspect, and 64 Angelina at both polar aspects, indicate the presence of an opposition spike or brightening of approximately 0.25 mag within several deg of zero-phase angle. Since the three curves are identical within the bounds of observational scatter, the opposition spike cannot be judged anomalous within the asteroid taxonomic class E. The general similarity of the observed phase curves to those of the Uranian satellites and the rings of Saturn supports the status of the spike as an ordinary property of moderate-to-high albedo atmosphereless surfaces.

Harris, A. W.↗
NASA NTRS1989

The diameter, shape, albedo, and rotation of 47 Aglaja

Observations of the September 16, 1984 occultation of SAO 146599 by the C-type asteroid 47 Aglaja from 13 sites in the continental U.S. have yielded a diameter of 136.4 + or - 1.2 km, leading to the calculation of a rotational period of 13.2 + or - 0.01 hr. At the time of the occultation, the zero-phase-angle visual geometric albedo of the asteroid's phase was 0.071 + or - 0.002. It is suggested that a substantial portion of the object's mean brightness variation with ecliptic longitude is ascribable to albedo differences over its surface.

Millis, R. L.↗
NASA NTRS1989

The puzzling case of asteroid 8 Flora solved

This paper reports the results obtained in an international campaign devoted to the observations of the asteroid 8 Flora, a possible target of the Vesta mission. Using the lightcurves obtained during three oppositions (1980, 1983, 1984), a synodic rotational period of 12.87 hours was determined. This period, applied to the lightcurves of 8 Flora already published, satisfactorily explains these observations. Applying the AM-method described by Zappala et al. (1983), the pole position was calculated. The slope parameter G, determined during the 1969 and 1983 apparitions, differs by about 0.10. Considering that in those years the ecliptic longitudes of the asteroid were about 115 degrees apart, this fact probably indicates the presence of variations in the structure and chemical compositions of the surface.

Di Martino, M.↗
NASA NTRS1989

Physical studies of Apollo-Amor asteroids - UBVRI photometry of 1036 Ganymed and 1627 Ivar

The 1036 Ganymed and 1627 Ivar photoelectric lightcurves presently discussed indicate in the former case a drastic lightcurve shape change, in conjunction with a significant increase of the synodic rotation period; a substantial change in viewing conditions during the apparition, and a complex interaction between these changes and the asteroid's irregular shape, are indicated by the change. In the latter asteroid's case, a prograde rotation rate is apparent in the observed decrease in synodic period. Both asteroids' phase curves exhibit deviations from the H-G magnitude system phase function at large phase angles.

Hahn, G.↗
NASA NTRS1989

Photoelectric observations of asteroids 3, 24, 60, 261, and 863

Observations of the five asteroids designated 3 Juno, 24 Themis, 60 Echo, 261 Prymo, and 863 Benkoela over the 1978-1984 period have been subjected to Fourier analysis to obtain composite lightcurves. The method yields a rotation-period value, mean absolute magnitudes for each night of observation, and Fourier coefficients that define composite-lightcurve shape, with formal error estimates for all quantities. The first three of the asteroids listed exhibit significant variation in surface albedo.

Harris, A. W.↗
NASA NTRS1987

Photoelectric lightcurves of the asteroid 1862 Apollo

A period of rotation of 3.0655 + or - 0.0008 hr is presently established for the 1862 Apollo asteroid on the basis of photoelectric light curves obtained during December 1980 and April-May 1982. The slope of the phase curve is typical for a moderate albedo asteroid. A pole position has been calculated using the observed deviation of the light curve from constant periodicity. While the formal uncertainty of the solution for the pole position is less than 10 deg, it may be several times that figure or even entirely wrong.

Harris, A. W.↗
NASA NTRS1986

Control/structures interaction study of two 300 KW dual-keel space station concepts

The results of an investigation of the influence of structural stiffness of the space station framework on the controllability of two 300 kw class, solar dynamic powered, dual-keel space station designs are presented. The two design concepts differed only in the truss bay dimensions of the structural framework of the stations. Two control studies were made: (1) A study of the interaction of the framework structural response with the reaction control system used for attitude control during an orbital reboost maneuver; and (2) A study of the stability of the space station attitude control system with sensors influenced by the elastic deformations of the station framework. Although both configurations had acceptable control characteristics, the configuration with the larger truss bay dimension and its increased structural stiffness had more attractive characteristics for pointing control of the solar dynamic system during reboost and for attitude control during normal in-orbit operations.

Young, J. W.↗
NASA NTRS1986

Multidisciplinary capability for analysis of the dynamics and control of flexible space structures

The paper describes a computerized data distribution capability, IMAT, in place at the NASA Langley Research Center for the multidisciplinary analysis of the dynamics and control of large flexible space structures. The paper includes results obtained in using IMAT to investigate the influence of the structural response of the space station framework on the control of a 300kw class, solar-dynamic-powered, dual-keel space station during an orbital reboost maneuver. The method of control, using an unfiltered proportional-plus-differential control law, led to a stable control system even with local flexible response measured at the control sensor location included as a part of the control error signal. The flexible response at the outboard solar dynamic system sun-line axis was close to the maximum rotation allowed for efficient operation; thus, active local control of each solar dynamic system may be necessary to limit sun-line axis rotations effectively during a reboost maneuver.

Cooper, P. A.↗
NASA NTRS1985

Decoupled and linear quadratic regulator control of a large, flexible space antenna with an observer in the control loop

An analysis is performed to compare decoupled and linear quadratic regulator (LQR) procedures for the control of a large, flexible space antenna. Control objectives involve: (1) commanding changes in the rigid-body modes, (2) nulling initial disturbances in the rigid-body modes, or (3) nulling initial disturbances in the first three flexible modes. Control is achieved with two three-axis control-moment gyros located on the antenna column. Results are presented to illustrate various effects on control requirements for the two procedures. These effects include errors in the initial estimates of state variables, variations in the type, number, and location of sensors, and deletions of state-variable estimates for certain flexible modes after control activation. The advantages of incorporating a time lag in the control feedback are also illustrated. In addition, the effects of inoperative-control situations are analyzed with regard to control requirements and resultant modal responses. Comparisons are included which show the effects of perfect state feedback with no residual modes (ideal case). Time-history responses are presented to illustrate the various effects on the control procedures.

Hamer, H. A.↗
NASA NTRS1985

Deriving Strain Modes From Vibrational Tests

Measurements and theoretical analysis complement each other. Experimental acceleration and strain data used to calculate coefficients of low-frequency vibrational modes of object under test. An iterative comparison of experimental and calculated strains give modal model of improved accuracy that predicts strains under operating conditions. Method useful in fatigue life and reliability analyses of buildings, pumps, engines, vehicles, and other systems subject to vibrations and loud noises during operation.

Young, J. W.↗
NASA NTRS1985

A Structural Dynamics Approach to the Simulation of Spacecraft Control/Structure Interaction

A relatively simple approach to the analysis of linear spacecraft control/structure interaction problems is presented. The approach uses a commercially available structural system dynamic analysis package for both controller and plant dynamics, thus obviating the need to transfer data between separate programs. The unilateral coupling between components in the control system block diagram is simulated using sparse matrix stiffness and damping elements available in the structural dynamic code. The approach is illustrated with a series of simple tutorial examples of a rigid spacecraft core with flexible appendages.

Young, J. W.↗
NASA NTRS1984

Radar and photoelectric observations of asteroid 2100 Ra-Shalom

Asteroid Ra-Shalom was subjected to 13-cm wavelength radar and V-filter photoelectric observations during its August-September 1981 apparition; the radar data yield echoes in the same sense of circular polarization as transmitted (SC) as well as in the opposite sense (OC). SC-to-OC echo power ratio estimates indicate that most of the backscattering is due to single reflections from surface elements that are relatively smooth at decimeter scales. The photoelectric data suggest a value of 19.79 hours for the synodic rotation period.

Ostro, S. J.↗
NASA NTRS1984

The lightcurve and phase relation of the asteroid 133 Cyrene

The asteroid 133 Cyrene was observed photometrically on 17 nights during oppositions in 1979 and 1980. The synodic period of rotation was found to be 12.708 + or - 0.001 h with an amplitude of 0.30 m during both oppositions. At large phase angles, the phase relation is quite ordinary (0.025 mag/degree); however, the low phase angle observations reveal a dramatic opposition brightening, about 0.2 mag/degree near zero phase angle. The absolute magnitude, V(1,0), extrapolated with the above linear phase coefficient, is 8.40. The following color indices were also measured: B-V = 0.90, U-B = 0.51.

Harris, A. W.↗