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Yang, J. B.

Publications and source records attributed to Yang, J. B..

Tunable structural and magnetic properties of NiAs-type Mn x Sb (1.00≤x≤1.30) compounds

Mn-based alloys can exhibit a variety of magnetic properties related to their tunable exchange interactions. Here, structural and magnetic properties of hexagonal NiAs-type Mn x Sb (1.00≤x≤1.30) compounds are studied with a combination of X-ray diffraction, neutron diffraction, and magnetic measurements. It is found that the magnetization, Curie temperature, and magnetocrystalline anisotropy of Mn x Sb compounds can be tuned by controlling Mn concentration and doping at interstitial (2d) sites. With increasing Mn concentration, magnetic moments of Mn atoms decrease and deviate gradually from the ab-plane to the c-axis for 1.20≤x≤1.22 at room temperature, which leads to a decrease of the Curie temperature T c and the spin reorientation temperature T SR . By doping with nonmagnetic elements, a substantial room-temperature magnetocaloric effect without magnetic hysteresis was achieved for Mn 1.12 Zr 0.1 Sb compound, which is highly beneficial to the practical magnetic refrigeration application.

36 MATERIALS SCIENCE↗

Magnetic structure and phase transition of Ni 2 Mn 1.48 Sb 0.52 magnetic shape memory compound

Here, a comprehensive study of the structural and magnetic properties of the Ni 2 Mn 1.48 Sb 0.52 compound is presente using neutron diffraction and magnetic measurements. It is found that Mn atoms on 4a and 4 sites are ferrimagnetic coupled in the austenitic phase. At 300 K, the magnetic moments of Mn (4a) an Mn (4b) are determined to be 2.72(3) μ B and -2.67(5) μ B , respectively. From 260 K to 4 K, the compound is in martensite phase and the magnetic moments of Mn (2a), Mn (2f), Mn (2b), Mn (2e) at 4 K ar 2.2(5) μ B , 2.3(5) μ B , -2.1(5) μ B , and -2.6(5) μ B , respectively.

36 MATERIALS SCIENCE↗

Magnetic manipulation by resistance switching in CeO{sub 2}/PrBa{sub 2}Cu{sub 3}O{sub 7−δ}/Pt heterostructure: The role of oxygen vacancies

Pronounced bipolar resistance switching with a good retention property has been observed in CeO{sub 2}/PrBa{sub 2}Cu{sub 3}O{sub 7−δ}/Pt heterostructure. The low resistance state and high resistance state exhibited distinguished ferromagnetic signals, as compared to the nearly non-magnetic initial state. It is found that the migration of the oxygen vacancies under electric field is mainly responsible for the electric and the magnetic changes. The modified interfacial electronic structure by the oxygen vacancy migration and the trapping/detrapping of the carriers leads to the resistance switching. The exchange interaction of the hydrogen-like orbitals formed around the singly occupied oxygen vacancies in CeO{sub 2} is accounting for the emerged and modulated ferromagnetic signals. Temperature dependence of resistance in the low resistance state follows a variable range hopping law, further confirming that the amount of oxygen vacancies in the CeO{sub 2} layer directly affects the hydrogen-like orbital radius, which determines the strength of the ferromagnetic coupling.

36 MATERIALS SCIENCE↗

The evolution of the magnetic phases of Sb-doped Mn{sub 5}Sn{sub 3} compounds

The structural and magnetic properties of Mn{sub 5}(Sn{sub 1-x}Sb{sub x}){sub 3} compounds (x = 0-0.4) were investigated by means of X-ray diffraction and magnetization measurements. All samples crystallize in Ni{sub 2}In-type structure (P6{sub 3}/mmc) with the lattice parameters changing anisotropically with the increase of Sb concentration. Sb doping leads to the merging of the ferrimagnetic transition temperature T{sub c} and the re-entrant spin-glass transition temperature T{sub f}, indicating a direct transition from spin-glass state to paramagnetic state. The M(H) curve at 5 K evolves with x from a soft-magnet type to a linear-like shape. We proposed a basic explanation for the evolution of the magnetic properties in terms of crystal structure and magnetic interactions, which can be applied to other related compounds.

36 MATERIALS SCIENCE↗