Engineering Papers⌕ Search

Engineering topics

Xu, X.

Publications and source records attributed to Xu, X..

At least 73 records · Page 4

Hybrid strategies and technologies for full spectrum solar conversion

Harvesting the full spectrum of sunlight using a hybrid approach offers the potential for higher efficiencies, lower power production costs, and increased power grid compatibility than any single technology by itself. In this article, the base technologies for converting sunlight into electricity, including photovoltaics and solar thermal approaches are discussed. Then feasible strategies for combining them to utilize the various portions of the solar spectrum most effectively are discussed. In this study, we particularly focus on the advantages of a spectral splitting approach. This helps to convert higher energy photons (UV and visible) directly into electrons using optimized single or tandem photovoltaic (PV) cells, while capturing lower energy photons as heat using a selective solar absorber, which absorbs photons within a range of energies, down to a cutoff in the mid-infrared. The solar heat is then thermally concentrated and driven through a high temperature thermoelectric generator on top of a high efficiency mechanical engine (e.g., a steam-driven Rankine cycle) through a heat exchanger, which connects to both thermal storage and the mechanical engine at 550 °C. The thermal storage allows for significant flexibility in the time of power generation (also known as dispatchability) at a modest cost. Furthermore, the system can produce power for hours after sunset. Ideally, the system can achieve efficiencies over 50% using a combination of an InAlAs/InGaP tandem photovoltaics, ErAs:(InGaAs) 1– x (InAlAs) x thermoelectrics, and mechanical Rankine cycles. The configuration and operating conditions can be optimized to minimize the levelized cost of energy (LCOE).

14 SOLAR ENERGY↗

Nano-optical imaging of WS e 2 waveguide modes revealing light-exciton interactions

We report on a nano-optical imaging study of WSe 2 thin flakes with scanning near-field optical microscopy (NSOM). The NSOM technique allows us to visualize in real space various waveguide photon modes inside WSe 2 . By tuning the excitation laser energy, we are able to map the entire dispersion of these waveguide modes both above and below the A exciton energy of WSe 2 . We found that all the modes interact strongly with WSe 2 excitons. The outcome of the interaction is that the observed waveguide modes shift to higher momenta right below the A exciton energy. At higher energies, on the other hand, these modes are strongly damped due to adjacent B excitons or band-edge absorptions. Lastly, the mode-shifting phenomena are consistent with polariton formation in WSe 2 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Design of structurally distinct proteins using strategies inspired by evolution

Natural recombination combines pieces of preexisting proteins to create new tertiary structures and functions. In this paper, we describe a computational protocol, called SEWING, which is inspired by this process and builds new proteins from connected or disconnected pieces of existing structures. Helical proteins designed with SEWING contain structural features absent from other de novo designed proteins and, in some cases, remain folded at more than 100°C. High-resolution structures of the designed proteins CA01 and DA05R1 were solved by x-ray crystallography (2.2 angstrom resolution) and nuclear magnetic resonance, respectively, and there was excellent agreement with the design models. Finally, this method provides a new strategy to rapidly create large numbers of diverse and designable protein scaffolds.

59 BASIC BIOLOGICAL SCIENCES↗

Isospin mixing reveals 30 P(p, γ) 31 S resonance influencing nova nucleosynthesis

Here, the thermonuclear 30 P(p, γ) 31 S reaction rate is critical for modeling the final elemental and isotopic abundances of ONe nova nucleosynthesis, which affect the calibration of proposed nova thermometers and the identification of presolar nova grains, respectively. Unfortunately, the rate of this reaction is essentially unconstrained experimentally, because the strengths of key 31 S proton capture resonance states are not known, largely due to uncertainties in their spins and parities. Using the β decay of 31 Cl, we have observed the β-delayed γ decay of a 31 S state at E x = 6390.2(7) keV, with a 30 P(p, γ) 31 S resonance energy of E r = 259.3(8) keV, in the middle of the 30 P(p, γ) 31 S Gamow window for peak nova temperatures. This state exhibits isospin mixing with the nearby isobaric analog state at E x = 6279.0(6) keV, giving it an unambiguous spin and parity of 3/2 + and making it an important l = 0 resonance for proton capture on 30 P.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Responses of two nonlinear microbial models to warming and increased carbon input

A number of nonlinear microbial models of soil carbon decomposition have been developed. Some of them have been applied globally but have yet to be shown to realistically represent soil carbon dynamics in the field. A thorough analysis of their key differences is needed to inform future model developments. In this paper, we compare two nonlinear microbial models of soil carbon decomposition: one based on reverse Michaelis–Menten kinetics (model A) and the other on regular Michaelis–Menten kinetics (model B). Using analytic approximations and numerical solutions, we find that the oscillatory responses of carbon pools to a small perturbation in their initial pool sizes dampen faster in model A than in model B. Soil warming always decreases carbon storage in model A, but in model B it predominantly decreases carbon storage in cool regions and increases carbon storage in warm regions. For both models, the CO 2 efflux from soil carbon decomposition reaches a maximum value some time after increased carbon input (as in priming experiments). This maximum CO 2 efflux (F max ) decreases with an increase in soil temperature in both models. However, the sensitivity of F max to the increased amount of carbon input increases with soil temperature in model A but decreases monotonically with an increase in soil temperature in model B. These differences in the responses to soil warming and carbon input between the two nonlinear models can be used to discern which model is more realistic when compared to results from field or laboratory experiments. Lastly, these insights will contribute to an improved understanding of the significance of soil microbial processes in soil carbon responses to future climate change.

58 GEOSCIENCES↗

Brightness measurement of an electron impact gas ion source for proton beam writing applications

We are developing a high brightness nano-aperture electron impact gas ion source, which can create ion beams from a miniature ionization chamber with relatively small virtual source sizes, typically around 100 nm. A prototype source of this kind was designed and successively micro-fabricated using integrated circuit technology. Experiments to measure source brightness were performed inside a field emission scanning electron microscope. The total output current was measured to be between 200 and 300 pA. The highest estimated reduced brightness was found to be comparable to the injecting focused electron beam reduced brightness. This translates into an ion reduced brightness that is significantly better than that of conventional radio frequency ion sources, currently used in single-ended MeV accelerators.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Widely tunable alloy composition and crystal structure in catalyst-free InGaAs nanowire arrays grown by selective area molecular beam epitaxy

We delineate the optimized growth parameter space for high-uniformity catalyst-free InGaAs nanowire (NW) arrays on Si over nearly the entire alloy compositional range using selective area molecular beam epitaxy. Under the required high group-V fluxes and V/III ratios, the respective growth windows shift to higher growth temperatures as the Ga-content x(Ga) is tuned from In-rich to Ga-rich InGaAs NWs. Using correlated x-ray diffraction, transmission electron microscopy, and micro-photoluminescence spectroscopy, we identify structural defects to govern luminescence linewidths in In-rich (x(Ga) < 0.4) and Ga-rich (x(Ga) > 0.6) NWs, whereas limitations at intermediate Ga-content (0.4 < x(Ga) < 0.6) are mainly due to compositional inhomogeneities. Most remarkably, the catalyst-free InGaAs NWs exhibit a characteristic transition in crystal structure from wurtzite to zincblende (ZB) dominated phase near x(Ga) ∼ 0.4 that is further reflected in a cross-over from blue-shifted to red-shifted photoluminescence emission relative to the band edge emission of the bulk ZB InGaAs phase.

36 MATERIALS SCIENCE↗

A model for the compositions of non-stoichiometric intermediate phases formed by diffusion reactions, and its application to Nb 3 Sn superconductors

In this work we explore the compositions of non-stoichiometric intermediate phases formed by diffusion reactions: a mathematical framework is developed and tested against the specific case of Nb 3 Sn superconductors. In the first part, the governing equations for the bulk diffusion and interphase interface reactions during the growth of a compound are derived, numerical solutions to which give both the composition profile and growth rate of the compound layer. The analytic solutions are obtained with certain approximations made. In the second part, we explain an effect that the composition characteristics of compounds can be quite different depending on whether it is the bulk diffusion or grain boundary diffusion that dominates in the compounds, and that “frozen” bulk diffusion leads to unique composition characteristics that the bulk composition of a compound layer remains unchanged after its initial formation instead of varying with the diffusion reaction system; here the model is modified for the case of grain boundary diffusion. Lastly, we apply this model to the Nb 3 Sn superconductors and propose approaches to control their compositions.

36 MATERIALS SCIENCE↗

Pauli-limited effect in the magnetic phase diagram of FeSe{sub x}Te{sub 1−x} thin films

We present a detailed investigation on the doping dependence of the upper critical field H{sub c2}(T) of FeSe{sub x}Te{sub 1−x} thin films (0.18 ≤ x ≤ 0.90) by measuring the electrical resistivity as a function of magnetic field. The H{sub c2}(T) curves exhibit a downturn behavior with decreasing temperature in all the samples, owing to the Pauli-limited effect (spin paramagnetic effect). The Pauli-limited effect on the upper critical field can be monotonically modulated by variation of the Se/Te composition. Our results show that Te-doping induced disorder and excess Fe atoms give rise to enhancement of the Pauli-limited effect.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A high-resolution analytical scanning transmission electron microscopy study of the early stages of spinodal decomposition in binary Fe–Cr

Spinodal decomposition (SD) is an important phenomenon in materials science and engineering. For example, it is considered to be responsible for the 475 °C embrittlement of stainless steels comprising the bcc (ferrite) or bct (martensite) phases. Structural characterization of the evolving minute nano-scale concentration fluctuations during SD in the Fe–Cr system is, however, a notable challenge, and has mainly been considered accessible via atom probe tomography (APT) and small-angle neutron scattering. The standard tool for nanostructure characterization, viz. transmission electron microscopy (TEM), has only been successfully applied to late stages of SD when embrittlement is already severe. However, we here demonstrate that the structural evolution in the early stages of SD in binary Fe–Cr, and alloys based on the binary, are accessible via analytical scanning TEM. An Fe–36 wt% Cr alloy aged at 500 °C for 1, 10 and 100 h is investigated using an aberration-corrected microscope and it is found that highly coherent and interconnected Cr-rich regions develop. The wavelength of decomposition is rather insensitive to the sample thickness and it is quantified to 2, 3 and 6 nm after ageing for 1, 10 and 100 h, which is in reasonable agreement with prior APT analysis. The concentration amplitude is more sensitive to the sample thickness and acquisition parameters but the TEM analysis is in good agreement with APT analysis for the longest ageing time. These findings open up for combinatorial TEM studies where both local crystallography and chemistry is required. - Highlights: • STEM-EELS analysis was successfully applied to resolve early stage SD in Fe–Cr. • Compositional wavelength measured with STEM-EELS compares well to previous ATP studies. • Compositional amplitude measured with STEM-EELS is a function of experimental parameters. • STEM-EELS allows for combinatorial studies of SD using complementary techniques.

36 MATERIALS SCIENCE↗

Tokamak power exhaust with the snowflake divertor: Present results and outstanding issues

Here, a snowflake divertor magnetic configuration (Ryutov in Phys Plasmas 14(6):064502, 2007) with the second-order poloidal field null offers a number of possible advantages for tokamak plasma heat and particle exhaust in comparison with the standard poloidal divertor with the first-order null. Results from snowflake divertor experiments are briefly reviewed and future directions for research in this area are outlined.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Gas Sensing Properties of Epitaxial LaBaCo 2 O 5.5+δ Thin Films

Chemical reactivity and stability of highly epitaxial mixed-conductive LaBaCo 2 O 5.5+δ (LBCO) thin films on (001) LaAlO 3 (LAO) single-crystalline substrates, fabricated by using pulsed laser deposition system, were systematically investigated. Microstructure studies from x-ray diffraction indicate that the films are c-axis oriented with the interface relationship of [100] LBCO //[100] LAO and (001) LBCO //(001) LAO . LBCO thin films can detect the ethanol vapor concentration as low as 10ppm and the response of LBCO thin film to various ethanol vapor concentrations is very reliable and reproducible with the switch between air and ethanol vapor. Moreover, the fast response of the LBCO thin film, as the p-type gas sensor, is better than some n-type oxide semiconductor thin films and comparable with some nanorods and nanowires. These findings indicate that the LBCO thin films have great potential for the development of gas sensors in reducing/oxidizing environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magnetic control of valley pseudospin in monolayer WSe 2

Local energy extrema of the bands in momentum space, or valleys, can endow electrons in solids with pseudo-spin in addition to real spin 1-5 . In transition metal dichalcogenides this valley pseudo-spin, like real spin, is associated with a magnetic moment1,6 which underlies the valley-dependent circular dichroism 6 that allows optical generation of valley polarization 7-9 , intervalley quantum coherence 10 , and the valley Hall effect 11 . However, magnetic manipulation of valley pseudospin via this magnetic moment 12-13 , analogous to what is possible with real spin, has not been shown before. Here we report observation of the valley Zeeman splitting and magnetic tuning of polarization and coherence of the excitonic valley pseudospin, by performing polarization-resolved magneto-photoluminescence on monolayer WSe 2 . Our measurements reveal both the atomic orbital and lattice contributions to the valley orbital magnetic moment; demonstrate the deviation of the band edges in the valleys from an exact massive Dirac fermion model; and reveal a striking difference between the magnetic responses of neutral and charged valley excitons which is explained by renormalization of the excitonic spectrum due to strong exchange interactions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Validation of Finite-Element Models of Persistent-Current Effects in Nb 3 Sn Accelerator Magnets

Persistent magnetization currents are induced in superconducting filaments during the current ramping in magnets. The resulting perturbation to the design magnetic field leads to field quality degradation, in particular at low field where the effect is stronger relative to the main field. The effects observed in NbTi accelerator magnets were reproduced well with the critical-state model. However, this approach becomes less accurate for the calculation of the persistent-current effects observed in Nb 3 Sn accelerator magnets. Here a finite-element method based on the measured strand magnetization is validated against three state-of-art Nb3Sn accelerator magnets featuring different subelement diameters, critical currents, magnet designs and measurement temperatures. The temperature dependence of the persistent-current effects is reproduced. Based on the validated model, the impact of conductor design on the persistent current effects is discussed. The performance, limitations and possible improvements of the approach are also discussed.

36 MATERIALS SCIENCE↗

Self-assembled ZnGa{sub 2}O{sub 4}–RGO nanocomposites and their enhanced adsorption and photocatalytic performance in water treatment

Highlights: • ZnGa{sub 2}O{sub 4}–RGO nanocomposites by a self-assembly approach under facile solvothermal condition. • ZnGa{sub 2}O{sub 4} NPs have a well-controlled size and uniform distribution. • The water treatment process is formed by two successive parts: adsorption and photocatalytic degradation. • The content of RGO sheets is crucial for optimizing the photocatalytic activity with a key value of 5%. - Abstract: ZnGa{sub 2}O{sub 4} nanoparticles (NPs) have been successfully anchored onto reduced graphene oxide (RGO) nanosheets by a self-assembly approach under facile solvothermal condition. The as-synthesized ZnGa{sub 2}O{sub 4}–RGO nanocomposites were investigated by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM). The results reveal that ZnGa{sub 2}O{sub 4} NPs with a well-controlled size and uniform distribution were successfully assembled onto RGO sheets. Moreover, both methylene blue (MB) and rhodamine B (RhB) were employed as model pollutants to evaluate the ability of as-prepared ZnGa{sub 2}O{sub 4}–RGO nanocomposites for wastewater treatment. The content of RGO sheets was found to be crucial for optimizing the photocatalytic activity of various nanocomposites with a key value of 5% beyond which the adsorption ability of ZnGa{sub 2}O{sub 4}–RGO nanocomposites for dyes dominates the process of water treatment.

36 MATERIALS SCIENCE↗