Solute rejection by porous glass membranes. II - Pore size distributions and membrane permeabilities.
Explore the source record for details and available documents.
Engineering topics
Publications and source records attributed to Wydeven, T..
Explore the source record for details and available documents.
In a closed ecological system it is necessary to reclaim most of the oxygen required for breathing from respired carbon dioxide and the remainder from waste water. One of the advanced physicochemical systems being developed for generating oxygen in manned spacecraft is the solid electrolyte-electrolysis system. The solid electrolyte system consists of two basic units, an electrolyzer and a carbon monoxide disproportionator. The electrolyzer can reclaim oxygen from both carbon dioxide and water. Electrolyzer preparation and assembly are discussed together with questions of reactor design and electrolyzer performance data.
Production of oxygen by rapid decomposition of cobalt oxide and sodium chlorate mixture is discussed. Cobalt oxide serves as catalyst to accelerate reaction. Temperature conditions and chemical processes involved are described.
Application of porous glass in form of capillary tubes for low capacity ion exchange in hyperfiltration experiments is discussed. Efficiency of desalination by process of reverse osmosis is described. Stabilization of porous glass membrane by presence of aluminum chloride is analyzed.
Method for purifying water that is contaminated with mineral salts and soluble organic compounds is described. Method consists of high pressure filtration of contaminated water through stabilized porous glass membranes. Procedure for conducting filtration is described. Types of materials by percentage amounts removed from the water are identified.
Simultaneous reverse-osmosis tests conducted with centrifuges having multiple compartment heads are discussed. Equipment for retaining reverse-osmosis membrane is illustrated. Method of conducting tests is described.
Production of alkali metal superoxides by interaction of molecular oxygen with alkali metals or their salts is discussed. Diagram of reactor to show components and operating principles is provided. Analysis of chemical reactions involved is developed.
The catalytic effect of cobalt powder on chlorate decomposition has been confirmed. Catalysis is enhanced by oxidation of the metal during burning. Catalysts other than cobalt compounds should also be effective; the complete elimination of fuel has shown that the oxidation of cobalt during decomposition is not a vital factor in the improved performance of catalyzed candles.
Hyperfiltration of sodium chloride and urea was studied with porous glass membranes in closed-end capillary form, to determine the effect of pressure, temperature, and concentration variations, and lifetime rejection and flux characteristics. Rejection data for sodium chloride were consistent with the functioning of the porous glass as a low-capacity ion-exchange membrane.
Solid electrolyte oxygen generator electrolysis test module with improved ceramic to ceramic and metal seals, electrode and grid design, discussing performance tests
Water vapor electrolysis for oxygen generation and humidity control in long term manned space flight
Porous glass hyperfiltration membranes stabilization by aluminum chloride solution, noting retreatment need
Catalytic decomposition of sodium chlorate using cobalt oxide catalysts
Prototype electrolyzer for generating oxygen from water vapor under various atmospheric conditions, noting spacecraft cabin application
Thermogravimetric analysis /TGA/ of gadolinium- doped silver carbonate decomposition, obtaining activation energy, preexponential factor and reaction order
Heats of adsorption of carbon dioxide on silver /I/ oxide and copper /II/ oxide by gas chromatography
Oxygen reclamation from carbon dioxide using solid oxide electrolyte, noting water vapor catalytic effect
Water electrolysis, discussing oxygen generators for spacecraft prototype cells and testing