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Witzke, W. R.

Publications and source records attributed to Witzke, W. R..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Alloy softening in binary iron solid solutions

An investigation was conducted to determine softening and hardening behavior in 19 binary iron-alloy systems. Microhardness tests were conducted at four temperatures in the range 77 to 411 K. Alloy softening was exhibited by 17 of the 19 alloy systems. Alloy softening observed in 15 of the alloy systems was attributed to an intrinsic mechanism, believed to be lowering of the Peierls (lattice friction) stress. Softening and hardening rates could be correlated with the atomic radius ratio of solute to iron. Softening observed in two other systems was attributed to an extrinsic mechanism, believed to be associated with scavenging of interstitial impurities.

Stephens, J. R.↗
NASA NTRS1975

The role of electron concentration in softening and hardening of ternary molybdenum alloys

An investigation was conducted to determine softening and hardening behavior in ternary Mo alloys and to correlate these effects with electron concentration. Results showed that the hardness behavior of ternary Mo alloys could be correlated with results anticipated from binary data based upon expressions involving the number of s + d electrons contributed by the solute elements. It was further shown that combining alloying elements at concentrations that produce the maximum amount of softening in Mo does not result in additive softening in ternary Mo alloys. Once a critical electron concentration is exceeded, only alloy hardening is observed. A comparison of hardness behavior with literature data on Hall coefficient and magnetic susceptibility for W-Re alloys showed that hardness minima occur at Re concentrations where minima are observed for the physical property measurements. These observations, and the correlation of hardness with electron concentration, support the hypothesis that alloy softening in Group VI metals is an intrinsic characteristic of these metals and that electron concentration plays the dominant role in controlling hardness.

Stephens, J. R.↗
NASA NTRS1975

Compositional effects on mechanical properties of hafnium-carbide-strengthened molybdenum alloys

The mechanical properties of swaged rod thermomechanically processed from arc melted Mo-2Re-Hf-C alloys containing as much as 0.9-mol% HfC were evaluated. The low-temperature ductilities of these alloys were not influenced by the amount of HfC present but by the amount of Hf in excess of stoichiometry. Maximum ductility occurred at 0.2- to 0.3-at.% excess Hf. At 0.3- to 0.5-mol% HfC, alloy strength varied directly with the Mo content of extracted carbide particles, both decreasing as the amount of excess Hf increased. Additions of 2-at.% Re had little effect on strength or ductility. Tensile and creep strengths of Mo-2Re-0.7Hf-0.5C alloy equaled or exceeded those of other high strength Mo alloys.

Witzke, W. R.↗
NASA NTRS1975

Hardness behavior of binary and ternary niobium alloys at 77 and 300 K

An investigation was conducted to determine the effects of alloy additions of zirconium, hafnium, molybdenum, tungsten, rhenium, ruthenium, osmium, rhodium, and iridium on the hardness of niobium. Both binary and ternary alloys were investigated by means of hardness tests at 77 and 300 K. Results showed that atomic size misfit plays a dominant role in controlling the hardness of binary niobium alloys. Alloy softening, which occurred at dilute solute additions, is most likely due to an extrinsic mechanism involving interaction between solute elements and interstitial impurities.

Stephens, J. R.↗
NASA NTRS1975

Role of electron concentration in softening and hardening of ternary molybdenum alloys

Effects of various combinations of hafnium, tantalum, rhenium, osmium, iridium, and platinum in ternary molybdenum alloys on alloy softening and hardening were determined. Hardness tests were conducted at four test temperatures over the temperature range 77 to 411 K. Results showed that hardness data for ternary molybdenum alloys could be correlated with anticipated results from binary data based upon expressions involving the number of s and d electrons contributed by the solute elements. The correlation indicated that electron concentration plays a dominant role in controlling the hardness of ternary molybdenum alloys.

Stephens, J. R.↗
NASA NTRS1974

Hardness behavior of binary and ternary niobium alloys at 77 and 300 K

The effects of alloy additions of zirconium, hafnium, molybdenum, tungsten, rhenium, ruthenium, osmium, rhodium, and iridium on the hardness of niobium was determined. Both binary and ternary alloys were investigated by means of hardness tests at 77 K and 300 K. Results showed that atomic size misfit plays a dominant role in controlling hardness of binary niobium alloys. Alloy softening, which occurred at dilute solute additions, is most likely due to an extrinsic mechanism involving interaction between solute elements and interstitial impurities.

Stephens, J. R.↗
NASA NTRS1974

The effects of composition on mechanical properties of W-4Re-Hf-C alloys

Studies were made of the effects of alloy composition on the mechanical behavior of as-worked W-4Re-Hf-C alloys containing up to about 0.8 mol % Hfc. Extracted second-phase particles were analyzed and related to alloy composition and creep strength. While strengthening is attributed to HfC particles, the presence of excess hafnium or carbon (above the calculated amounts for stoichiometric HfC) in swaged W-4Re-Hf-C alloys generally causes a reduction of the high-temperature (1930 C) tensile strength; maximum creep strength is, however, indicated for alloys with a slight (about 0.05 to 0.1 at. %) excess of hafnium. Particle strengthening is reduced by WC in solid solution with HfC for allow compositions with an excess of carbon. The low-temperature ductility of worked W-4Re-Hf-C alloys appears to be far more dependent on the amount of excess C or Hf present than on the HfC particle content in the range studies.

Witzke, W. R.↗
NASA NTRS1973

Mechanical properties of electron-beam-melted molybdenum and dilute Mo-Re alloys.

Study of Mo-Re alloys aimed at examining the effects of small rhenium additions on the low-temperature ductility of molybdenum and determining the mechanical properties of dilute Mo-Re alloys. The results obtained indicate that high-purity Mo-Re alloys have ductile-brittle transition temperatures considerably lower than those for unalloyed molybdenum and that rhenium promotes normal solid-solution strengthening in molybdenum at elevated temperatures.

Klopp, W. D.↗
NASA NTRS1973

Composition effects on mechanical properties of tungsten-rhenium-hafnium-carbon alloys

The mechanical properties of rod and sheet fabricated from arc melted W-4Re-Hf-C alloys containing up to about 0.8 mol percent hafnium carbide (HfC) were evaluated in the as-worked condition. The DBTT's of electropolished bend and tensile specimens were independent of HfC content in this range but dependent on excess Hf or C above that required for stoichiometric HfC. Low temperature ductility was a maximum at Hf contents slightly in excess of stoichiometric. Variations in high temperature strength were also dependent on excess Hf and C. Maximum creep strengthening also occurred at Hf contents in excess of stoichiometric. Analysis of extracted second phase particles indicated that creep strength was reduced by increasing WC content in the HfC particles.

Witzke, W. R.↗
NASA NTRS1972

Alloy hardening and softening in binary molybdenum alloys as related to electron concentration.

Determination of the effects of alloy additions of Hf, Ta, W, Re, Os, Ir, and Pt on the hardness of Mo. Special emphasis was placed on alloy softening in these binary Mo alloys. A modified microhardness test unit permitted hardness determinations at homologous temperatures ranging from 0.02 to 0.15, where alloy softening normally occurs in bcc alloys. Results showed that alloy softening was produced by those elements having an excess of s + d electrons compared to Mo while those elements having an equal number or fewer s + d electrons than Mo failed to produce alloy softening. The magnitude of the softening and the amount of solute element at the hardness minimum diminished rapidly with increasing test temperature. At solute concentrations where alloy softening was observed, the temperature sensitivity of hardness was lowered. For solute elements having an excess of s + d electrons or fewer s + d electrons than Mo, alloy softening and alloy hardening can be correlated with the difference in number of s + d electrons of the solute element and Mo.

Stephens, J. R.↗
NASA NTRS1972

Mechanical properties of electron-beam-melted molybdenum and dilute molybdenum-rhenium alloys

A study of molybdenum and three dilute molybdenum-rhenium alloys was undertaken to determine the effects of rhenium on the low temperature ductility and other mechanical properties of molybdenum. Alloys containing 3.9, 5.9, and 7.7 atomic percent rhenium exhibited lower ductile-brittle transition temperatures than did the unalloyed molybdenum. The maximum improvement in the annealed condition was observed for molybdenum - 7.7 rhenium, which had a ductile-brittle transition temperature approximately 200 C (360 F) lower than that for unalloyed molybdenum. Rhenium additions also increased the low and high temperature tensile strengths and the high temperature creep strength of molybdenum. The mechanical behavior of dilute molybdenum-rhenium alloys is similar to that observed for dilute tungsten-rhenium alloys.

Klopp, W. D.↗
NASA NTRS1972

Alloy hardening and softening in binary molybdenum alloys as related to electron concentration

An investigation was conducted to determine the effects of alloy additions of hafnium, tantalum, tungsten, rhenium, osmium, iridium, and platinum on hardness of molybdenum. Special emphasis was placed on alloy softening in these binary molybdenum alloys. Results showed that alloy softening was produced by those elements having an excess of s+d electrons compared to molybdenum, while those elements having an equal number or fewer s+d electrons that molybdenum failed to produce alloy softening. Alloy softening and alloy hardening can be correlated with the difference in number of s+d electrons of the solute element and molybdenum.

Stephens, J. R.↗
NASA NTRS1972

Alloy softening in binary molybdenum alloys.

An investigation was conducted to determine the effects of alloy additions of Hf, Ta, W, Re, Os, Ir, and Pt on the hardness of Mo. Special emphasis was placed on alloy softening in these binary Mo alloys. Results showed that alloys softening was produced by those elements having an excess of s+d electrons compared to Mo, while those elements having an equal number or fewer s+d electrons than Mo failed to produce alloy softening. Alloy softening and alloy hardening can be correlated with the difference in number of s+d electrons of the solute element and Mo.

Stephens, J. R.↗
NASA NTRS1972

Alloy softening in binary molybdenum alloys

An investigation was conducted to determine the effects of alloy additions of Hf, Ta, W, Re, Os, Ir, and Pt on the hardness of Mo. Special emphasis was placed on alloy softening in these binary Mo alloys. Results showed that alloy softening was produced by those elements having an excess of s+d electrons compared to Mo, while those elements having an equal number or fewer s+d electrons than Mo failed to produce alloy softening. Alloy softening and hardening can be correlated with the difference in number of s+d electrons of the solute element and Mo.

Stephens, J. R.↗