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Williams, W.

Publications and source records attributed to Williams, W..

31 records · Page 2

Angular distributions in the electron impact excitation of Xe at 20 eV

Electron impact energy-loss spectra of Xe have been studied at 20 eV incident electron energy at scattering angles from 5 to 135 deg. Differential and integral cross sections for elastic scattering and for the excitation of electronic states up to 10.60 eV energy loss have been determined. The validity of the optical selection rules and the previously established angular behavior associated with direct and exchange processes were examined for this intermediate coupling case.

Williams, W.↗

Elastic and inelastic electron scattering at 20 and 60 eV from atomic Cu

Normalized differential and integral electron-impact cross sections are presented for elastic scattering and for specified excitation levels of atomic copper at 20 and 60 eV. For some excitation levels, an unexpectedly large cross section was found, which at certain angular and energy ranges surpasses the cross section for elastic scattering.

Williams, W.↗

Advanced high efficient liquid transport garments

The heat transfer characteristics, design, fabrication, and current and anticipated applications of a new liquid transport garment (LTG) are discussed. The new LTG is being constructed from highly efficient liquid transport modules which have been developed to replace the current tygon tubing networks for applications in Apollo and other liquid cooling garment designs.

Elkins, W.↗

Electron impact excitation of H2O.

The authors (1971) detected a new triplet state of water at 9.81 eV energy, and assigned the low energy-loss feature to the excitation of low-lying triplet state(s) of water on the basis of the angular distribution of the scattered electrons. The results are discussed here in more detail, as well as relative differential cross sections for elastic scattering, and for the excitation of these and several other electronic and pure vibrational states of water at impact energies of 15, 20, and 53 eV and at scattering angles ranging from 0 to 90 deg.

Trajmar, S.↗

Vibrational excitation in CO by electron impact in the energy range 10-90 eV.

The ratio of the scattering intensity for the v double prime = 1 excitation to the elastic scattering intensity at 40- and 80-deg scattering angles has been determined for 10- to 90-eV impact energies for electron scattering by CO. These ratio curves exhibit broad peaks near 20-eV impact energy which cannot be accounted for by plane-wave calculations based on potential scattering models. The peaks are indicative of a resonant excitation process (or processes) in the v double prime = 1 channel in the range from 15 to 25 eV.

Chutjian, A.↗

The excitation of O2 in auroras.

Newly measured electron impact cross sections for excitation of the a super 1 Delta sub g and b super 1 Sigma (plus) sub g electronic states of O2 have been employed to predict the absolute volume emission rates from these states under auroral conditions. A secondary electron flux typical of an IBC II nighttime aurora was used, and the most important quenching processes were included in the calculations. The new excitation cross sections for the a super 1 Delta sub g and b super 1 Sigma (plus) sub g states are more than an order of magnitude larger than previous estimates and lead to correspondingly greater intensities in the atmospheric and IR atmospheric band systems. The calculated intensity ratios of the volume emission rates of 7621 A and 1.27 micron to that for 3914 A are smaller than those obtained from aircraft observations and recent rocket experiments.

Cartwright, D. C.↗

The IR emission spectrum of N2 excited under auroral conditions.

Recently determined experimental and theoretical cross sections for electron impact excitation of six triplet states of N2 (A, B, W, C, E, D) have been utilized to predict the absolute IR volume emission rates from N2 under nighttime auroral conditions. Secondary electron fluxes appropriate to an IBC II normal aurora were used in the calculations. The cascade contributions coupling the various electronic states were included as well as the most important quenching processes. The results indicate that the B yields reversibly A and W yields reversibly B cascade processes, which are important in the population of the A, B, and W states, produce appreciable radiation in the 1- to 5-micron wavelength region.

Cartwright, D. C.↗

Angular dependence of electron impact excitation cross sections of O2.

Study of the electron-impact excitation spectrum of O2 at 20 and 45 eV impact energies and at scattering angles ranging from 10 to 90 deg. The angular behavior of the differential scattering cross sections for excitation of the a super 1 delta sub g, b super 1 sigma sub g (+), B super 3 sigma sub u (-) states for the 9.97-eV ('longest' band) and the 10.29-eV ('second' band) transitions, for the broad feature at 6.1 eV energy-loss, and for elastic scattering is determined. The experimentally measured relative differential and integral cross sections for these processes are approximately normalized to the absolute scale. The intensities of the different transitions in optical and electron-impact spectra are compared, and the importance of spin-orbit coupling and exchange processes is discussed. It is found that the energy-loss feature at 6.1 eV in the electron-impact spectrum is mostly due to the excitation of the c super 1 sigma sub u (-) state, and not the A super 3 sigma sub u (+) state, as had been previously thought.

Trajmar, S.↗

Vibrational population of the A super 3 sigma sub u/+/ and B super 3 pi sub g states of N2 in normal auroras.

Use of new electron impact excitation cross sections for the six lowest triplet states (A, B, W, C, E, D) of N2, and solution of the coupled equations of statistical equilibrium to obtain the vibrational population of each electronic state. The results show that cascade from high levels of the A super 3 sigma sub u(+) state and from the W super 3 delta sub u state is significant in populating the lower vibrational levels of the B state and hence the character of its ?apparent' excitation cross sections. For the B state excited under auroral conditions, the fraction of the total population due to cascade processes exceeds 25% for all levels lower than 7 and is greater than 80% for B(v' = 0). For the A state under similar conditions, cascade from the B state contributes 50% or more of the total vibrational population for levels lower than 7, and 80% or more for levels below 4. For levels of the A state greater than 7, the A yields B transitions depopulate the levels rapidly and indicate that the Vegard-Kaplan emissions from these higher levels will be weak or totally absent in normal auroras.

Cartwright, D. C.↗