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Waters, J.

Publications and source records attributed to Waters, J..

30 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

A 3D simulation of the early winter distribution of reactive chlorine in the north polar vortex

Early in December 1991, high values of ClO are seen by the Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite at latitudes south of areas of temperatures cold enough to form polar stratospheric clouds (PSCs). A 3D simulation shows that the heterogeneous conversion of chlorine reservoirs to reactive chlorine on the surfaces of PSCs (processing) takes place at high latitudes. Often the processed air must be transported to lower latitudes, where the reactive chlorine is photochemically converted to ClO, to be observed by MLS. In this simulation, one incidence of cold temperatures is associated with an anticyclone, and a second with a cyclone. The transport of processed air associated with the anticyclone is marked by shearing; a decrease in the maximum of the processed air is accompanied by growth of the area influenced by the processing. In contrast, the air processed in the cyclonic event spreads more slowly. This shows that transport and shearing is a crucial element to the evolution of reactive chlorine associated with a processing event. In particular, transport and shearing, as well as photochemical processes, can cause variations in observed ClO.

Douglass, A.↗
NASA NTRS1990

Ozone measurements from the Balloon Intercomparison Campaign

Measurements of the Balloon Intercomparison Campaign (BIC), conducted during fall, 1982 (BIC-1) and summer, 1983 (BIC-2), are reported. Results of five remote and two in situ techniques agree (with a few exceptions) within 95-percent confidence level uncertainties and generally within 15 percent above 20 km. Weighted mean profiles, which best represent conditions during the campaign, are used as a comparison standard. Accuracies of experiments indicated by BIC generally confirm estimated uncertainties for ECC sondes, UV photometry, and microwave emission experiments, are somewhat better for far-IR emission and IR absorption experiments, and are somewhat worse for IR emission and solar UV absorption experiments. The large collection of BIC measurements confirms a problem reported earlier with current theoretical modeling of ozone near 40 km.

Robbins, D.↗
NASA NTRS1990

Autoclavable addition polyimides for 371 C composite applications

Studies were conducted to improve the thermo-oxidative stability (TOS) of PMR type polyimides by the substitution of para-aminostyrene (PAS) for the nadic ester endcap in second generation PMR polyimides (PMR-2). The nadic endcap which provides the PMR polyimides with their relative ease of fabrication, both by limiting the molecular weight of the prepolymer and by undergoing the final addition cure without volatiles, is also the weak link with regard to TOS. A polyimide formulated with PAS endcaps, called V-CAP, utilizes a two step reaction sequence similar to that of the PMR polyimides and can be easily autoclave molded into low void composite materials. Resin studies included two formulations of both PMR-2 and V-CAP, corresponding to n = 9 and n = 14 prepolymer stoichiometry. Unidirectional reinforced T40R graphite fiber laminates were fabricated from each of the resins was post-cured in either air at 385 C or nitrogen at 400 C. Composite specimens were aged in air at 371 C and mechanical properties were measured at 371 C before and after exposure.

Vannucci, R. D.↗
NASA NTRS1985

Halogentated species

Stratospheric measurements of halogen containing species are reviewed and compared with model predictions. Halocarbons, HCl, HF, ClONO2, and ClO are discussed.

Molina, M. J.↗
NASA NTRS1985

Ozone intercomparisons from the Balloon Intercomparison Campaign

Intercomparisons of remote and in-situ techniques used to measure stratospheric ozone are made using results obtained on the Balloon Intercomparison Campaign of 1982 and 1983. Two in-situ and four remote instruments participated. These included ECC ozonesondes, a UV absorption photometer, and microwave emission, IR emission, and absorption spectrometers. Differences are generally less than 15 percent, and are within the quoted error bars. Flights which involved different sets of instruments were made on four separate days, and results are intercompared in plots of ozone density versus altitude. A careful assessment of errors was made for each instrument, and a plot of absolute errors versus altitude is given.

Robbins, D.↗