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Wasserburg, G. J.

Publications and source records attributed to Wasserburg, G. J..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

The Mn-53-Cr-53 System in CAIs: An Update

High precision techniques have been developed for the measurement of Cr isotopes on the Triton mass spectrometer, at JPL. It is clear that multiple Faraday cup, simultaneous ion collection may reduce the uncertainty of isotope ratios relative to single Faraday cup ion collection, by the elimination of uncertainties from ion beam instabilities (since ion beam intensities for single cup collection are interpolated in time to calculate isotope ratios), and due to a greatly increased data collection duty cycle, for simultaneous ion collection. Efforts to measure Cr by simultaneous ion collection have not been successful in the past. Determinations on Cr-50-54Cr, by simultaneous ion collection on the Finnigan/ MAT 262 instrument at Caltech, resulted in large variations in extrinsic precision, for normal Cr, of up to 1% in Cr-53/Cr-52 (data corrected for mass fractionation, using Cr-50/Cr-52).

Papanastassiou, D. A.↗
NASA NTRS2004

More on Ru Endemic Isotope Anomalies in Meteorites

We reported last year on endemic isotope anomalies for Ru in iron meteorites, pallasites, ordinary chondrites, and on a whole-rock sample of Allende. We have extended the Ru measurements to more meteorites, to refractory Ca-Al-rich inclusions (CAI) from Allende, and to a whole rock sample of Murchison (CM2). In a companion abstract we report on new measurements for the Mo isotopes, in some of the same samples. There has been a renewed interest in searching for isotope anomalies in this nuclide region, as Ru and Mo include many isotopes from r-, s-, and p-process nucleosynhesis. Furthermore, the Ru and Mo p-process isotopes show atypically high abundances, which have been hard to explain through the standard nucleosynthetic processes. Effects are possible in Ru-98 and Ru-99 from Tc-98 (with a poorly known t(sub 1/2)=4.2 to 10Ma) and from Tc-99 (t(sub 1/2)=0.21Ma). Natural Tc is now extinct on Earth due to the short half-lives, but may have been present in the early solar system. Both radiogenic and general isotope anomalies are important in understanding the processes for the formation of the early solar system. The current emphasis on Ru and Mo is also the result of the development of Negative-ion Thermal Ionization Mass Spectrometry and of Multiple-Collector, Inductively-Coupled-Mass-Spectrometry. We have also developed specific chemical siparation techniques for Ru, which eliminated mass interference effects.

Papanastassiou, D. A.↗
NASA NTRS2004

Endemic Mo Isotopic Anomalies in Iron and Carbonaceous Meteorites

Mo in refractory interstellar grains shows large isotope anomalies. Recent Mo studies showed isotope effects in Allende and Murchison, and in iron meteorites, mesosiderites, and pallasites. Excesses of p- and r-process isotopes (or depletion of sprocess isotopes) of up to 3.5 epsilon units (epsilon u=parts in 10(exp 4)) were reported. We have reported on endemic isotope anomalies in Ru. Other workers have resolved no isotope anomalies for Mo or Ru and have claimed that the work by others is incorrect. Because Ru isotopes can interfere at Mo-96, Mo-98, Mo-100, we improved the chemical separations and eliminated interferences. For Mo work, we used the same solutions from which we separated and analyzed Ru. Three of the iron meteorites (Coahuila, Cape York, and Cape of Good Hope) were chosen for their large Mo isotopic effects. Mo was loaded on outgassed Re filaments, and then reduced; we used Ba(OH)2-NaOH as emitter, and measured Mo in static mode, as MoO3(-). We used Mo-98/Mo-96 for the mass fractionation correction (exponential law). No interferences from Ru or Zr isotopes were detected using the electron multiplier and no corrections were needed. For results on Mo standards we show 2 sigma(not 2 sigma mean) external precision better than: 0.7 epsilon u for Mo-94/Mo-96 and Mo-95/Mo-96; 1.0 epsilon u for Mo-92/Mo-96 and Mo-97/Mo-96; 1.4 epsilon u for Mo-100/Mo-96. Reproducibility for Mo standards is shown as contours (blue lines).

Chen, J. H.↗
NASA NTRS2003

Endemic Ru Isotopic Anomalies in Iron Meteorites and in Allende

Small variations for Mo isotopes have been observed recently in the Allende meteorite and in iron meteorites, mesosiderites, and pallasites, using ICPMS. Large effects for Mo have been reported for leaches of Orgueil and in SiC and graphite from Murchison. Variations for Mo in bulk Allende and in Murchison have also been presented by NTIMS. Effects in Ru isotopes can define further the preserved exotic r, s, and p contributions in this mass region, and possible effects in Ru-98 and Ru-99 from Tc-98 (4.2 Ma half-life) and Tc-99 (0.21 Ma half-life). Previous attempts at determination of Ru isotopes yielded no resolved effects. The present work represents a substantial improvement in precision over the earlier work. Chemical and mass spectrometric analytical techniques are presented to determine the Ru isotope compositions in terrestrial standards and in meteorites.

Chen, J. H.↗
NASA NTRS2003

No Nd-142 Excess in the Early Archean Isua Gneiss IE 715-28

There is abundant evidence for the existence of 146Sm in the early solar system and for preservation of effects in the 146Sm-142Nd system in differentiated meteorites ([1]; see recent discussion in Stewart et al. 1994). Information from the 182Hf-182W system, as revised by new careful work [2-3] also indicates that the Earth s core formed relatively early. It is in principle possible for early-formed crust and mantle reservoirs on Earth to have preserved evidence for 146Sm if such reservoirs were produced with high Sm/Nd fractionation and if they have remained isolated and closed since ~4.3 Ga. The mean life of 146Sm of 149 Ma is sufficiently long to make this an intriguing possibility.

Papanastassiou, D. A.↗
NASA NTRS2003

Cautionary Notes on Cosmogenic W-182 and Other Nuclei in Lunar Samples

Leya et al. (2000) showed that neutron capture on Ta-181 results in a production rate of Ta-182 (decays with a half-life of 114 days to W-182) sufficiently high to cause significant shifts in W-182 abundances considering the neutron fluences due to the cosmic ray cascade that were known to occur near the lunar surface. Leya et al. concluded that this cosmogenic production of W-182 may explain the large positive epsilon(sub W-182) values that Lee et al. (1997) had reported in some lunar samples rather than being produced from decay of now extinct Hf-182 (bar tau = 13 x 10(exp 6) yr). If the large range in epsilon(sub W-182) of lunar samples (0 to +11 in whole rock samples) was due to decay of now extinct Hf-182, it would require a very early time of formation and differentiation of the lunar crust-mantle system (with high Hf/W ratios) during the earliest stages of Earth s accretion. This result was both surprising and difficult to understand. The ability to explain these results by a more plausible mechanism is therefore very attractive. In a recent report Lee et al. (2002) showed that there were excesses of W-182 and that epsilon(sub W-182) was correlated with the Ta/W ratios in the mineral phases of individual lunar rock samples. This is in accord with W-182 variations in lunar samples being produced by cosmic-ray induced neutron capture on Ta-182.

Yin, Qingzhu↗
NASA NTRS2002

Cool Bottom Processing on the AGB and Presolar Grain Compositions

We describe results from a model of cool bottom processing (CBP) in AGB (asymptotic giant branch) stars. We predict O, Al, C and N isotopic compositions of circumstellar grains. Measured compositions of mainstream SiC grains and many oxide grains are consistent with CBP. Additional information is contained in the original extended abstract.

Nollett, Kenneth M.↗
NASA NTRS2002

Circumstellar Oxide Grains in Ordinary Chondrites and Their Origin

Three new circumstellar hibonite and 14 circumstellar corundum grains have been found based on their highly anomalous oxygen. Al-Mg isotopes have been measured for these circumstellar oxides and for 14 oxides with a normal oxygen composition. Additional information is contained within the original extended abstract.

Krestina, Natalia↗
NASA NTRS2002

Cr Isotopes in Allende Ca-Al-rich Inclusions

We have determined Cr isotope compositions in minerals from Allende CAI in order to address the initial 53Mn (half-life 3.7 Ma) abundance in the solar system. Additional information is contained in the original extended abstract.

Bogdanovski, O.↗
NASA NTRS2002

Re-Os Isotope Systematics in Lunar Soils and Breccias

Lunar soil and breccia samples show a narrow range in 187Os/188Os, in the range for H-chondrites and unfractionated irons. All samples show enrichments in 187Re/188Os, possibly reflecting loss of Os, associated with the terminal lunar cataclysm. Additional information is contained in the original extended abstract.

Chen, J. H.↗
NASA NTRS2001

Development And Application Of The Ion Microprobe For Analysis Of Extraterrestrial Materials

This report covers the work carried out under NASA Grant NAG5-4083. The research was directed toward analyses of early solar system material, of presolar grains preserved in meteorites, and toward theoretical studies of nucleosynthesis in stars related to the chemical evolution of the galaxy and the formation of the solar system. The work was carried out over the time period 15 February 1998 - 31 May 2001 and involved the participation of the following individuals: M. Busso, Visiting Associate, Professor of Astrophysics, Perugia University, Italy; B.-G. Choi, research fellow, now Associate Professor at Seoul National University, Korea; H. C. Connolly, research fellow, now at Kingsborough Community College, CUNY; R. Gallino, Visiting Associate, Professor of Astrophysics, University of Torino; Y. Guan, Smithsonian Institution; C. Hohenberg, Professor of Physics, Washington University, St. Louis; M. Heinrich, electronics and systems engineer, Caltech; W. Hsu, research fellow, Caltech; T. LaTourrette, research fellow, now at Rand Corporation; G. R. Huss, Senior Research Scientist, now at Arizona State University; N. Krestina, research fellow in geochemistry, Caltech; G. J. MacPherson, Smithsonian Institution; K. Nollett, research fellow in astrophysics; Y.-Z. Qian, Professor of Physics, University of Minnesota; G. Srinivasan, research fellow, now Research Scientist, Physical Research Laboratory, Ahmedabad, India.

Wasserburg, G. J.↗
NASA NTRS2001

Sr and Nd Data for Upper Eocene Spherule Layers

Sr and Nd data for clinopyroxene-bearing (cpx) spherules from three sites support conclusions that there is only one cpx spherule layer and that the source crater may be Popigai. Additional information is contained in the original extended abstract.

Liu, Shaobin↗