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Wang, Yu

Publications and source records attributed to Wang, Yu.

At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Photovoltaic Array Differential Backside Exposure Conditions: Backsheet Degradation and Site Design

Backsheet exposure conditions and degradation are shown to vary significantly within an array. This is demonstrated by a survey of the NIST ground-mounted photovoltaic array, which is comprised of over 1000 modules of a single brand with a polyester-based backsheet. Site and array design factors are found to have significant effects on the exposure conditions, and thus degradation of the backsheets. Irradiance is found to be the most significant exposure factor which varies within the array.

14 SOLAR ENERGY↗
DOE OSTI2018

Selective CO 2 Reduction on 2D Mesoporous Bi Nanosheets

The conversion of CO 2 to value-added products using electrical or solar energy represents an attractive means for the capture and utilization of atmospheric CO 2 . Formate is a popular product from CO 2 reduction, but its reaction selectivity is usually unsatisfactory. Tin-based materials have attracted the most attention for formate production at present. Unfortunately, most of them only exhibit moderate selectivity in a narrow and highly cathodic potential window. In this study, it is demonstrated that traditionally under-explored bismuth has a much greater potential for formate production than tin or other materials. Mesoporous bismuth nanosheets are prepared here by the cathodic transformation of atomic-thick bismuth oxycarbonate nanosheets. They enable the selective CO 2 reduction to formate with large current density, excellent Faradaic efficiency (approximate to 100%) over a broad potential window and great operation stability. Moreover, Bi nanosheets are integrated with an oxygen evolution reaction electrocatalyst in full cells, and achieve efficient and robust solar conversion of CO 2 /H 2 O to formate/O 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2018

Formation Mechanism of Nanoscale Al{sub 3}Fe Phase in Al-Fe Alloy During Semisolid Forming Process

The formation mechanism of nanoscale Al{sub 3}Fe phase in Al-1Fe (wt pct) alloy during rheo-extrusion was investigated, and the mechanical property of the prepared alloy was also measured. The results show that the average length of Al{sub 3}Fe phase in Al-1Fe alloy prepared by rheo-extrusion is 300 nm, which is much more refined than the needlelike Al{sub 3}Fe phase in as-cast Al-1Fe alloy (50 μm). In rheo-extrusion, Al{sub 3}Fe phase formed by eutectic reaction is bonelike, but it could be continuously refined by the shear deformation in the wheel groove, in equal channel angular flow, and in expansion extrusion mold. The total equivalent strain of the shear deformation is higher than 4.82. The tensile strength and elongation of Al-1Fe alloy prepared by rheo-extrusion are 135 MPa and 30 pct, respectively. The tensile strength of Al-1Fe alloy prepared by rheo-extrusion is 58.8 pct higher than that of as-cast Al-1Fe alloy, and the elongation is 19 pct higher than that of as-cast Al-1Fe alloy. Compared with as-cast Al-1Fe alloy, the improvements of tensile strength and elongation caused by shear deformation in rheo-extrusion are higher than the reported improvements induced by rare earth modification.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Organosilane-assisted selective etching strategy for fabrication of hollow/rattle-type mesoporous organosilica nanospheres

Highlights: • Effective fabrication of organic hollow/rattle-type mesoporous organosilica. • The addition of CTES could increase the porosity of the materials. • Pore-making agent (CTES) could be removed by alkali treatment without additional step. - Abstract: A facile strategy to fabricate hollow or rattle-type mesoporous silica nanospheres (HMSNs or RMSNs) with organic functional groups and porous shell was developed. Herein, thiol-HMSNs were obtained via treating vinyl-SiO{sub 1.5} @cyano&thiol-SiO{sub 1.5} prepared by using 3-mercaptopropyltrimethoxysilane (MPTMS) as organosilane precursor, vinyltriethoxysilane (VTES) as sacrificial template precursor and cyanoethyltriethoxysilane (CTES) as pore-making agent. In this method, CTES was co-condensed with MPTMS to form hybrid shell and played an important role in the formation of pore structures. When the volume ratio of MPTMS to CTES was 1:1, well-defined thiol-HMSNs with a specific surface area of 295.6 m{sup 2} g{sup −1} and pore volume of 0.51 cm{sup 3} g{sup −1} could be obtained. Moreover, [email protected] could also be synthesized through this method from three-layered structures (thiocyanato-SiO{sub 1.5} @vinyl-SiO{sub 1.5} @cyano&thiol-SiO{sub 1.5}). The as-prepared RMSNs presented good performance for the adsorption of 2, 4-dichloropheno in water. And this selective etching strategy was versatile and might be extended to fabricate more valuable organic hollow/rattle-type composites for different applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Transcriptional regulation of bHLH during plant response to stress

Highlights: • bHLH can regulate gene expression through interaction with specific motif in target genes. • In this review, we discuss the role of bHLH in plants in response to stresses such as drought, salt and cold stress. • This review will provide new ideas and targets for the prevention and treatment of plant stress resistance. Basic helix-loop-helix protein (bHLH) is the most extensive class of transcription factors in eukaryotes, which can regulate gene expression through interaction with specific motif in target genes. bHLH transcription factor is not only universally involved in plant growth and metabolism, including photomorphogenesis, light signal transduction and secondary metabolism, but also plays an important role in plant response to stress. In this review, we discuss the role of bHLH in plants in response to stresses such as drought, salt and cold stress. To provide a strong evidence for the important role of bHLH in plant stress response, in order to provide new ideas and targets for the prevention and treatment of plant stress resistance.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

A facile pathway to prepare VO{sub 2} and V{sub 2}O{sub 3} powders via a carbothermal reduction process

The development of a highly efficient and low cost production process is instrumental for the wide application of VO{sub 2} and V{sub 2}O{sub 3}. In this paper, VO{sub 2} and V{sub 2}O{sub 3} powders are successfully prepared via carbothermal reduction of V{sub 2}O{sub 5} in a flowing Ar atmosphere at 973 K and 1423 K, respectively. Compared with the traditional methods, graphite is used as a reductant, which resulted in a low cost. The experimental results show that a high temperature assists in improving the kinetic rate. The phase transformation during the low-temperature reduction process between 948 K and 973 K occurs in the following sequential order: V{sub 2}O{sub 5}→V{sub 6}O{sub 13}→VO{sub 2}. When the temperature is 1423 K or 1473 K, the phase transformation can be described as follows: V{sub 2}O{sub 5}→V{sub 3}O{sub 5}→V{sub 2}O{sub 3}. Owing to the shrink of the volume, the as-prepared VO{sub 2} and V{sub 2}O{sub 3} particles could not maintain the original micro-morphology of V{sub 2}O{sub 5}. Relative to VO{sub 2}, the as-prepared V{sub 2}O{sub 3} particles are porous. It is also concluded that the V{sub 2}O{sub 3} can be easily oxidized to VO{sub 2}, when the partial pressure of O{sub 2} is in the range of 10{sup −8} atm to 10{sup −1} atm. Therefore, a reasonable reaction temperature and reaction time are important to prepare high purity V{sub 2}O{sub 3}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

ADAM17 promotes cell migration and invasion through the integrin β1 pathway in hepatocellular carcinoma

ADAM17 is believed to promote tumor development by facilitating both cell proliferation and migration. In this study, we investigated the involvement of ADAM17 and the activation of the integrin pathway in the regulation of the malignant properties of hepatocellular carcinoma cells and tissues. ADAM17 was positively correlated with active integrin β1, which was determined using a human tissue microarray and an N-nitrosodiethylamine-induced HCC mouse model. We found elevated ADAM17 and active integrin β1 levels in HCC tissues compared with adjacent liver tissues, and the active integrin β1 levels were associated with tumor size and TNM grade. High ADAM17 and active integrin β1 levels in tumor tissues were significantly associated with poor survival of HCC patients. RNAi-mediated ADAM17 knockdown and integrin β1 blockade significantly attenuated the migration and invasion of HCC cells, and overexpression of ADAM17 showed the reverse effects. ADAM17 interference attenuated the intrahepatic growth and metastasis of HCC cells in an orthotopic xenograft model. ADAM17-knockdown cells showed diminished levels of active integrin β1, p-FAK, p-AKT, MMP-2 and MMP-9. ADAM17 knockdown significantly attenuated the translocation of the Notch1 intracellular domain into the nucleus, whereas overexpression of the Notch1 intracellular domain rescued the translocation and enhanced the activation of integrin β1. Our data provide evidence for ADAM17 as an important determinant of malignant properties via regulation of integrin β1 activation and Notch1 signaling. Inhibition of ADAM17 may provide viable therapeutic potential for preventing HCC metastasis.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Indium Tin Oxide Broadband Metasurface Absorber

Metamaterials have been designed to achieve a wide range of functionalities. Metamaterial absorbers are of particular interest for various applications such as infrared detectors, emissivity coatings, and photovoltaic cells. Various metamaterial platforms have been demonstrated to achieve perfect absorption and several attempts have been made to extend the absorption bandwidth of such devices. We demonstrate a broadband infrared absorber using an asymmetric Fabry–Perot cavity consisting of a monolithically fabricated two-layer metasurface. Superoctave optical absorption is achieved by tailoring the structure of the metasurface layers and the thickness of the cavity. Furthermore, the device yields absorptance of over 80% from λ = 4–16 μm, while maintaining the performance over a wide range of incident angles. In contrast to most metamaterial absorbers, our metasurface layers are made of customized indium tin oxide (ITO), conferring the advantage of CMOS compatibility compared to previous approaches using noble metals.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Electron mass enhancement and magnetic phase separation near the Mott transition in double-layer ruthenates

Here, we present a detailed investigation of the specific heat of Ca 3 (Ru 1-x M x ) 2 O 7 (M = Ti, Fe, Mn) single crystals. Depending on the dopant and doping level, three distinct regions are present: a quasitwo-dimensional metallic state with antiferromagnetic (AFM) order formed by ferromagnetic bilayers (AFM-b), a Mott insulating state with G-type AFM order (G-AFM), and a localized state with a mixed AFM-b and G-AFM phase. Our specific heat data provide deep insights into the Mott transitions induced by Ti and Mn doping. We observed not only an anomalous large mass enhancement, but also an additional term in the specific heat, i.e., C ∝ T 2 , in the localized region. The C ∝ T 2 term is most likely due to long-wavelength excitations with both FM and AFM components. A decrease in the Debye temperature is observed in the G-type AFM region, indicating lattice softening associated with the Mott transition.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Flexible magnetic composites for light-controlled actuation and interfaces

The interaction between light and matter has been long explored, leading to insights based on the modulation and control of electrons and/or photons within a material. An opportunity exists in optomechanics, where the conversion of radiation into material strain and actuation is currently induced at the molecular level in liquid crystal systems, or at the microelectromechanical systems (MEMS) device scale, producing limited potential strain energy (or force) in light-driven systems. We present flexible material composites that, when illuminated, are capable of macroscale motion, through the interplay of optically absorptive elements and low Curie temperature magnetic materials. These composites can be formed into films, sponges, monoliths, and hydrogels, and can be actuated with light at desired locations. Finally, light-actuated elastomeric composites for gripping and releasing, heliotactic motion, light-driven propulsion, and rotation are demonstrated as examples of the versatility of this approach.

42 ENGINEERING↗
DOE OSTI2018

Voltage-Controlled Sensitivity of the Spin Seebeck Effect in Pt/Y 3 Fe 5 O 12 /MgO/(PbMg 1/3 Nb 2/3 O 3 ) 0.7 (PbTiO 3 ) 0.3 Multiferroic Heterostructures

The characteristics of pure spin current from the longitudinal spin Seebeck effect are investigated at room temperature in Pt / Y 3 Fe 5 O 12 deposited on the ( Pb Mg 1 / 3 Nb 2 / 3 O 3 ) 0.7 ( Pb Ti O 3 ) 0.3 substrate, through which electrostrain can be controllably applied. The applied voltage enables the modification of magnetic anisotropy in the magnetic insulating Y 3 Fe 5 O 12 layer, and thus the sensitivity of the spin Seebeck effect at small magnetic fields, without suppressing the spin Seebeck effect and the inverse spin Hall effect. This is due to the robust intrinsic physical parameters in Pt / Y 3 Fe 5 O 12 . In conclusion, our results pave the way for the application of voltage-controlled pure spin-current devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Circular RNA hsa{sub c}irc{sub 0}000673 promotes hepatocellular carcinoma malignance by decreasing miR-767-3p targeting SET

Highlights: • Hsa{sub c}irc{sub 0}000673 was highly expressed in HCC tissues. • Hsa{sub c}irc{sub 0}000673 knockdown suppressed HCC cell proliferation and invasion. • Hsa{sub c}irc{sub 0}000673 promoted HCC proliferation and invasion by sponging miR-767-3p. • Hsa{sub c}irc{sub 0}000673 facilitated HCC cell proliferation and invasion via regulating miR-767-3p/SET pathway. The importance of circular RNAs (circRNAs) in human cancers has gradually been acknowledged. In hepatocellular carcinoma (HCC), several circRNAs have been reported to regulate tumor growth and metastasis. However, the role of hsa{sub c}irc{sub 0}000673 in HCC remains largely unknown. In this study, we found that hsa{sub c}irc{sub 0}000673 was significantly upregulated in HCC tissues compared to adjacent non-tumor tissues. Moreover, we found that hsa{sub c}irc{sub 0}000673 knockdown markedly inhibited the proliferation and invasion of HCC cells in vitro. Besides, hsa{sub c}irc{sub 0}000673 silence led to delayed tumor growth in vivo. In terms of mechanism, we showed that hsa{sub c}irc{sub 0}000673 directly associated with miR-767-3p in HCC cells. Via inhibiting miR-767-3p, hsa{sub c}irc{sub 0}000673 promoted HCC cell proliferation and invasion. Furthermore, we demonstrated that SET was a downstream effector of hsa{sub c}irc{sub 0}000673/miR-767-3p signaling. We showed that miR-767-3p could significantly promote SET expression by sponging miR-767-3p in HCC cells. Finally, rescue assays indicated that SET expression was essential for the effects of hsa{sub c}irc{sub 0}000673/miR-767-3p signaling on HCC cell proliferation and invasion. Taken together, our findings demonstrated that hsa{sub c}irc{sub 0}000673 promoted HCC malignant behaviors via regulating miR-767-3p/SET pathway.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Developing a landscape of urban building energy use with improved spatiotemporal representations in a cool-humid climate

Urban buildings account for up to 75% of total energy use in the United States (U.S.). Understanding urban building energy use is important for developing feasible options to mitigate energy use and greenhouse gas emissions. In this study, an improved bottom-up building energy use model, named City Building Energy Use Model (City-BEUM), was developed to estimate building energy use for all buildings in Polk County, Iowa. First, 28 commercial and 6 residential building prototypes were designed by combing Assessor's parcel data and building footprint data. Then, the EnergyPlus in the CityBEUM was calibrated for all building prototypes using the U.S. Energy Information Administration's survey data, monthly utility meter data, and actual weather data. Finally, spatial and temporal variations of building energy use in the study area were estimated using the CityBEUM. Results indicate that the spatial variation of building energy use in the study area can be captured using the CityBEUM. With the monthly-calibrated model, the temporal pattern of urban building energy use can be well represented. The comparison of building energy use using the Typical Meteorological Year and actual weather data demonstrates the importance of using actual weather data in building energy modeling for an improved temporal representation.

CityBEUM, Urban building energy use, High spatiote↗