Structural phase transitions of SrF{sub 2} at high pressure
The high-pressure behavior of SrF{sub 2} has been investigated by angle-dispersive synchrotron X-ray powder diffraction measurement up to 50.3 GPa at room temperature. Two phase transformations were observed at 6.8 and 29.5 GPa, and the two high pressure phases were identified as orthorhombic (Pnma) phase and hexagonal (P6{sub 3}/mmc) phase by Rietveld refinement. Upon decompression, retransformation was observed and the sample recovered under ambient conditions consisted of a mixture of cubic phase and orthorhombic phase. The compressing characteristics of SrF{sub 2} as the pressure increases were discussed, indicating higher incompressibility of SrF{sub 2} under high pressure. - Graphical abstract: The high-pressure behavior of SrF{sub 2} has been investigated by angle-dispersive synchrotron X-ray powder diffraction measurement up to 50.3 GPa at room temperature. Highlights: Black-Right-Pointing-Pointer The high-pressure study on SrF{sub 2} up to 50.3 GPa at room temperature. Black-Right-Pointing-Pointer Two first-order phase transformations were observed at 6.8 and 29.5 GPa. Black-Right-Pointing-Pointer The three stable structures are confirmed by Rietveld refinements. Black-Right-Pointing-Pointer The cubic and orthorhombic phase co-exist at pressures down to ambient pressure. Black-Right-Pointing-Pointer The bulk modulus indicates higher incompressibility of SrF{sub 2} under high pressure.