Engineering topics
Publications and source records attributed to Walker, J. C. G..
A method is presented for the analysis of twilight airglow spectra that may be contaminated by atmospheric continuum emission of unknown brightness. The necessity of correcting for this continuum emission when measuring weak airglow features in twilight is illustrated by application of the method to the neutral iron line at 3860 A.
An array of 5 autonomous spectrometers, the imaging spectrometric observatory covers a broad wavelength range (approximately 200 to 12,000 A), has a resolution selectable down to approximately 0.5 A, and a dynamic range of approximately 10 to the 7th power and is designed to select experiment measurement sequences by software control. Because current models of thermospheric ionic processes produce too much N2(+) ionization, the N2(+) reaction with O and the chemistry of metastable (N(+) ions and of O2(+) ions are objects of study on Spacelab 1.
The Atmosphere Explorer photochemistry is used to interpret simultaneous observations made at the Arecibo Observatory of the OI (6300 A) and NI (5200 A) airglow surface brightness and electron density and temperature profiles measured by incoherent scatter radar. It was found that the theory and the experiment agree for the 5200-A emission; however, it was not possible to obtain to a complete agreement for the 6300-A nightglow. It is suggested that the source of the discrepancy results from one of the parameters used to calculate the production rate of O(lD); the data show evidence of an asymmetrical behavior of the ionosphere between times when the F layer is descending and when it is ascending, with asymmetry probably reflecting the effects of transport on molecular ion densities in the bottom side of the F region.
The idealized 'servo' model of the ionospheric F2-layer of Rishbeth et al. (1978) is used to simulate the observed behavior of the daytime Fe-peak at Arecibo at sunspot minimum. The meridional pressure-gradient force associated with the meridional neutral-air wind is determined empirically. The local time variation during the day is found to be consistent with the semidiurnal variation given by the MSIS atmospheric model of Hedin et al. (1977). The values of the F2-layer loss and diffusion coefficients needed to match the data are broadly consistent with the MSIS model.
The rise of atmospheric O3 as a function of the evolution of O2 has been investigated using a one-dimensional steady-state photochemical model based on the chemistry and photochemistry of Ox(O3, O, O(1D)), N2O, NOx(NO, NO2, HNO3), H2O, and HOx(H, OH, HO2, H2O2) including the effect of vertical eddy transport on the species distribution. The total O3 column density was found to maximize for an O2 level of 0.1 present atmospheric level (PAL) and exceeded the present total O3 column by about 40%. For that level of O2, surface and tropospheric O3 densities exceeded those of the present atmosphere by about an order of magnitude. Surface and tropospheric OH densities of the paleoatmosphere exceeded those of the present atmosphere by orders of magnitude. It was also found that in the O2-deficient paleoatmosphere, N2O (even at present atmospheric levels) produces much less NOx than it does in the present atmosphere.
A theoretical model of the diurnal variations in the compositions of the ions O(+), NO(+), O2(+) and N2(+) in the midlatitude F1 layer is presented and compared with measurements made by AE-C. The theoretical model includes the rate coefficients and branching ratios for the dissociative recombination of NO(+), O2(+) and N2(+) with electrons and the ion-atom interchanges of O(+) with N2 and N2(+) with O. Input parameters to the model comprise measurements of ion and electron temperatures, neutral atmosphere composition, the solar EUV flux and the photoelectron spectrum. In general, model calculations are found to agree with satellite measurements, confirming the major ion sources and sinks of the photochemical model, which has an accuracy of + or - 60%.
Spectral analysis of the midnight temperature anomaly observed on Atmosphere Explorer-E indicates that the phenomenon can be adequately represented with wave numbers between 1 and 5. Results from a multiconstituent circulation model suggest that this feature and associated variations in composition are the result of a complex interaction between the semidiurnal tide generated in the lower atmosphere and ion-neutral momentum coupling associated with the diurnal variation of the ion density which, in turn, also generates higher order tidal models.
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The correlation between variations in the components of the ionospheric F2-layer parallel and perpendicular to the geomagnetic field is theoretically examined. The servo model of Rishbath (1967) is used as a basis for further calculations. The equations involved are presented in full and results are given for various assumed conditions. The response of the model to both steplike and periodic perturbations of the perpendicular component is considered along with the effects of winds and the Coriolis force. Arecibo and Malvern data are reviewed on the basis of theoretically predicted behavior.
The production and destruction of O(D-1) atoms in the thermosphere are studied on the basis of observations conducted by the Atmosphere Explorer-C spacecraft. In particular, measurements of the O I transition at 6300 A provide a means of calculating the strength of the O2(+) dissociative recombination source of O(D-1), which amounts to 1.33. A value of 3 times 10 to the minus 11th power cu cm/sec is established for the quenching rate of O(D-1) by molecular nitrogen, while the photodissociation rate for O2 is set at three millionths per sec. These determinations are in agreement with the conventional theory of the day 6300-A airglow.
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Using approximately 400 simultaneous measurements of ion and neutral densities and temperatures, and the spectrum of the solar flux measured by the Atmosphere Explorer C satellite, we have determined the rate constant k1 for the reaction between N2(+) and O in the ionosphere for ion temperatures between 600 and 700 K. We find that k1 = 1.1 x 10 to the minus 10th power cu cm per sec, with a standard deviation of + or - 15%. If we use the temperature dependence for this reaction determined in the laboratory then at 300 K we find excellent agreement with the recommended laboratory value.
Measurements of O(++) concentrations made by the Atmosphere Explorer C satellite are analyzed for altitudes where photochemical equilibrium conditions prevail in order to determine the photochemical sources and sinks of the doubly charged ion. The major loss process is found to be through partial charge exchange with neutral atomic oxygen with a rate coefficient of 1 x 10 to the -11th cu cm/s with an uncertainty of 40%. Above 220 km the major source is photo-ionization of O(+). However, X ray ionization of O (at not greater than 23.3 A) producing O(++) directly through the Auger process provides a better fit to the observed profile at lower altitudes.
The paper is concerned with a more detailed determination of the quenching rates of O(+)(2-P) ions by electrons, molecular nitrogen, and atomic oxygen using data from the Atmosphere Explorer C and D satellites. It is found that the orbit examined by Walker et al. (1975) was contaminated by zodiacal emissions. Production of the cited ions in the daytime is primarily due to photoionization excitation of neutral atomic oxygen. The quenching rate coefficients which best modified the 7319-A source functions to satisfy the data are determined by a least squares fitting technique. Molecular nitrogen is shown to dominate the quenching over most of the altitude ranges. Electrons become the most important quenching agent at high altitudes but are still a factor of 10 less important than radiation.
The visible airglow photometer on the Atmosphere Explorer C satellite has been used to compare the calibrations of a number of ground-based airglow observatories. Discrepancies between different ground stations as large as a factor of six have been revealed. Efforts to account for these discrepancies have resulted in the discovery of differences as large as a factor of two in the standard light sources in use at different observatories. The participation of additional observatories in the intercomparison of standard sources is solicited. The project has also led to the discovery of a source of error that can amount to another factor of two in the procedure used to calibrate many airglow instruments. In the course of the project, detailed maps based on satellite data have been made of the galactic and zodiacal-light background at a number of wavelengths, and a substantial source of contaminating emission has been discovered in the satellite data. The contamination appears to result from interaction of the spacecraft and the atmosphere at altitudes below 170 km.
The paper investigates the direct effect of soft electron precipitation on the nitrogen vibrational distribution and on the rate coefficient for the ion-atom interchange reaction between O(+) and N2, using a spectrum of the precipitating electrons characteristic of the dayside cusp region. Substantial increases in the nitrogen vibrational temperature and in the rate of the O(+) destruction reaction do not occur unless the flux of incident electrons is as large as 1 trillion per sq cm/sec. For such large fluxes, departures of the vibrational distribution from a Boltzmann distribution have a significant effect on the rate coefficient. Incident fluxes less than 100 billion per sq cm/sec, such as are usually observed, have little direct effect on nitrogen vibration, although the indirect effect resulting from enhanced electron temperatures might be important.
It is argued that the transition to an oxidizing atmosphere preceded the origin of eukaryotic cells, which in turn must have preceded the origin of metazoa. Moreover, the number of methods by which organisms can protect themselves from harmful UV radiation is sufficiently large to suggest that solar UV, even when the atmosphere was anaerobic, was not such as to control the distribution and diversification of life. An alternative explanation for the late and sudden appearance of metazoa in lower Cambrian sediments is proposed, which is related to the mechanisms by which fully mature eukaryotic cells probably originated. There was probably a protracted evolution of modern genetic systems based on mitosis in cells which acquired organelles (e.g., plastids and mitochondria) by hereditary endosymbiosis. The origin of hard parts underlies the Cambrian explosion of metazoans.