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Vedder, James F.

Publications and source records attributed to Vedder, James F..

Hypervelocity impact survivability experiments for carbonaceous impactors, part 2

Hypervelocity impact experiments were performed to further test the survivability of carbonaceous impactors and to determine potential products that may have been synthesized during impact. Diamonds were launched by the Ames two-stage light gas gun into Al plate at velocities of 2.75 and 3.1 km sec(exp -1). FESEM imagery confirms that diamond fragments survived in both experiments. Earlier experiments found that diamonds were destroyed on impact above 4.3 km sec(exp -1). Thus, the upper stability limit for diamond on impact into Al, as determined from our experimental conditions, is between 3.1 and 4.3 km sec(exp -1). Particles of the carbonaceous chondrite Nogoya were also launched into Al at a velocity of 6.2 km sec (exp -1). Laser desorption (L (exp 2) MS) analyses of the impactor residues indicate that the lowest and highest mass polycyclic aromatic hydrocarbons (PAH's) were largely destroyed on impact; those of intermediate mass (202-220 amu) remained at the same level or increased in abundance. In addition, alkyl-substituted homologs of the most abundant pre-impacted PAH's were synthesized during impact. These results suggest that an unknown fraction of some organic compounds can survive low to moderate impact velocities and that synthesized products can be expected to form up to velocities of, at least, 6.5 km sec(exp -1). We also present examples of craters formed by a unique microparticle accelerator that could launch micron-sized particles of almost any coherent material at velocities up to approximately 15 km sec(exp -1). Many of the experiments have a direct bearing on the interpretation of LDEF craters.

Bunch, T. E.↗

Irreversible transport in the stratosphere by internal waves of short vertical wavelength

Measurements performed during stratospheric flights of the U-2 aircraft confirm that cross-jet transport is dominated by waves, not by large-scale circulations. Monotonic gradients of trace constituents normal to the jet axis, with upper stratospheric tracers increasing poleward and tropospheric tracers increasing equatorward, are augmented by large-scale confluence as the jet intensifies during cyclogenesis. These gradients are rotated, intensified, and significantly increased in areas as their mixing ratio surfaces are folded by the differential transport of a very low frequency transverse wave. The quasi-horizontal transport produces a laminar structure with stable layers rich in upper stratospheric tracers alternating vertically with less stable layers rich in tropospheric tracers. The transport proceeds toward irreversibility at higher frequency, shear-gravity waves extend the folding to smaller horizontal scales.

Danielsen, Edwin F.↗

Ames ER-2 ozone measurements

The objective of this research is to study ozone (O3) in the stratosphere. Measurements of the ozone mixing ratio at 1 s intervals are obtained with an ultraviolet photometer which flies on the ER-2 aircraft. The photometer determines the amount of ozone in air by measuring the transmission of ultraviolet light through a fixed path with and without ambient O3 present.

Pearson, R., Jr.↗

Whole air sampler

Minor constituents play an important role in upper atmospheric photochemistry and serve as tracers in transport and mixing studies in tropospheric stratospheric exchange processes. Measurements of trace gases are essential to an understanding of the mechanisms by which minor constituents originating in the troposphere, both naturally occurring and anthropogenic, reach the stratosphere; data on tracer distributions thus acquired are important in the development of models for predicting photochemical effects in the stratosphere.

Vedder, James F.↗

Measurements of ozone in the Antarctic atmosphere during August and September 1987

Mixing ratios changed dramatically for ozone in the austral polar stratosphere during August and September 1987. Data were obtained with an ultraviolet photometer mounted in the equipment bay of an ER-2 aircraft. Measurements were made between the latitudes of 53 and 72 deg S at pressure altitudes (U.S. Standard Atmosphere, 1976) up to 21 km in a series of flights from Punta Arenas, Chile, over the Palmer Peninsula. Additional data were obtained between 37 N and 53 deg S on the ferry flights leaving from and returning to Moffett Field, California. The sampling-collecting system and the analytical techniques are described. In September the mixing ratios for ozone at pressure altitudes above 15 km in the southernmost part of the flights over the Palmer Peninsula were significantly lower than values for midlatitudes. The various latitudes of the ER-2 aircraft's encounters with the boundary of the region of depleted ozone lie between 59 and 71 deg S. Near the 425 K potential temperature surface and well within the vortex, the measured mixing ratio of ozone declined from about 2 parts per million by volume (ppmv) to about 0.6 ppmv during the period of the ER-2 flights. The distributions of ozone as a function of altitude indicate the presence of layering of ozone.

Starr, Walter L.↗

Measurements of ozone in the Antarctic region during August and September of 1987

Mixing ratios are presented for ozone in the austral polar atmosphere during Aug. and Sept. of 1987. Since the mid-1970's, there has been a continuing decrease in the total column abundance of ozone over Antarctica during the late winter and early spring. This reduction now amounts to about one-half of the historical October mean. The results presented are derived from an ultraviolet ozone photometer. The ER-2 aircraft carrying 14 instruments participated in a major effort to penetrate the region of depletion. Data were gathered between altitudes of 53 deg and 72 deg S at pressure altitudes up to 21 km in a series of 12 flights. Additional data were obtained between latitudes of 37 deg N and 53 deg S on the 3 flight legs required to reach Punta Arenas from Moffett Field, CA, and on the same return legs to Moffett Field. The observed ozone mixing ratios indicate the effects of chemistry as well as the effects of the stratospheric polar vortex. Examples of the distributions of ozone mixing ratios as a function of altitude, latitude, or a time and the relationships to temperature and other trace gases are presented.

Starr, Walter L.↗

Mixing ratios of trace gases in the austral polar atmosphere during August and September of 1987

Mixing ratios are presented for a number of long-lived trace gases in the austral polar atmosphere during August and September of 1987. The recent discovery of a 12-year trend of increasing depletion of ozone over the Antarctic Continent in the spring of each year led to numerous theoretical interpretations and several scientific expeditions to the region. The results herein were obtained as part of a major effort involving penetration of the region of ozone depletion by NASA's multi-instrumented aircraft. One of the 14 instruments on the high-altitude ER-2 aircraft collected pressurized air samples between latitudes of 53 degrees and 72 degrees south at pressure altitudes up to 21 km in a series of 12 flights from Punta Arenas, Chile, over the Palmer Peninsula. The sampling system, located in the nose section of ER-2, has an inlet tube in the free airstream, a metal-bellows air pump, and 14 specially treated 1.6 l stainless-steel canisters for containing the pressurized air at 350 kPa. A typical flight profile consisted of a southbound path on the 428 K potential temperature surface, a descent to a pressure altitude of 13.7 km, a climb to the 460 K surface, and return on this surface. Mixing ratios for the trace gases were obtained from gas chromatographic analyses of the pressurized air samples. Of the species measured, the mixing ratios for CH4, CO, N2O, CF2 Cl2, CFCl3, CH3, CCl3, CCl4, and C2F3Cl3 are reported here.

Vedder, James F.↗

Transport into the south polar vortex in early spring

Estimates of the mean circulation and diffusive transport of ozone and other species into the Antarctic polar vortex during the spring of 1987 are made using data from the Airborne Antarctic Ozone Experiment. Measurements of long-lived tracers of tropospheric origin remained relatively constant at the levels of the maximum rate of decline of ozone during September. At lower levels in the stratosphere some evidence exists to support intrusions of tropospheric or low latitude air. Given the distribution in latitude and height of these tracers measured from the ER-2 aircraft, it can be inferred that the Lagrangian or diabatic mean circulation was zero or downward over Antarctica during the period of the ozone decline. The observation of a decline in ozone therefore requires a photochemical sink for ozone. The magnitude of the required photochemical sink must be sufficient to offset the transport of ozone into the polar region and produce the observed decline. Quasi-isentropic mixing and downward motion are coupled and are difficult to estimate from a single tracer. The full suite of measured tracers and auxiliary information are brought together to provide an estimate of the rate at which air is cycled through the polar vortex during spring. Estimates of large scale transport of potential vorticity and ozone from previous years are generally consistent with the data from the airborne experiment in suggesting a relatively slow rate of mass flow through the polar vortex in the lower stratosphere during September.

Hartmann, D.↗

Concentrating Trace Gases at Low Pressures

Open adsorption tube enables measurement of gases at parts-per-trillion-by-volume concentrations. Traps trace materials in flowing gas. Variety of configurations possible; tube consists of single long coil instead of several short ones, and tube is made of materials other than stainless steel. Partial immersion of coil in cryogen results in 100 percent trapping rather than typical 85 percent for total immersion.

Vedder, James F.↗