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Varanasi, P.

Publications and source records attributed to Varanasi, P..

51 records · Page 3
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NASA NTRS1975

Measurement of line widths of CO of planetary interest at low temperatures

Self-broadened, air-broadened and CO2-broadened half-widths of lines R(0) through R(16) in the CO fundamental have been measured at 100 K (self-broadening only), 200 K, 250 K and 300 K using the Ladenburg-Reiche curve-of-growth. The relation which we found previously for the nitrogen-broadened half-widths of R(0), R(8), and R(16), is shown to be valid for all of the line widths measured in the present study.

Varanasi, P.↗
NASA NTRS1974

Measurement of line intensities of linear molecules under low resolution

Spectral absorption measurements involving pure nitrous oxide were performed with the aid of a commercial grating spectrophotometer. A multiple reflection cell with a path length of 1.25 m was used in the investigation. The tests were conducted at pressures in the range from 5 to 8 atm. The obtained data were used to determine the apparent spectral absorption coefficients. Questions regarding the validity of a line approximation relation are discussed.

Varanasi, P.↗
NASA NTRS1974

The nu sub 9 fundamental of ethane - Integrated intensity and band absorption measurements with application to the atmospheres of the major planets

Measurements of the absolute intensity and integrated band absorption have been performed for the nu sub 9 fundamental band of ethane. The intensity is found to be about 34 per sq cm per atm at STP, and this is significantly higher than previous estimates. It is shown that a Gaussian profile provides an empirical representation of the apparent spectral absorption coefficient. Employing this empirical profile, a simple expression is derived for the integrated band absorption, which is in excellent agreement with experimental values. The band model is then employed to investigate the possible role of ethane as a source of thermal infrared opacity within the atmospheres of Jupiter and Saturn, and to interpret qualitatively observed brightness temperatures for Saturn.

Varanasi, P.↗
NASA NTRS1974

Measurement of multiplet intensities and noble gas-broadened line widths in the nu 3 fundamental of methane

Presented integrated intensity data at 300 K for J multiplets between P(11) and R(11) in the nu-3 fundamental of C-12 methane are shown to be in good agreement with most previously published pertinent values. Also, line widths measured at 100 K, 130 K, 190 K, 250 K, and 300 K for R(0), R(1), and R(2) broadened by He, Ne, and Ar are presented, and the line-width temperature dependence is discussed for the three cases of broadening.

Varanasi, P.↗
NASA NTRS1974

The role of higher-multipolar and repulsive forces in the calculation of collision-broadened line-widths of linear molecules

Collision-broadened line widths in CO-CO2 and CO-O2 collisions have been calculated by incorporating interactions due to octopoles and hexadecapoles and short-range repulsive interactions into Anderson's (1949) theory. It is shown how these higher-order interactions can be manipulated to yield good agreement with experimental data. A critical evaluation of this totally empirical manipulation suggests that a thorough revision of the theory is required for all but simple dipole-dipole interactions. In the process of the evaluation, the values of the multipole moments are discussed.

Varanasi, P.↗
NASA NTRS1972

Shapes and widths of ammonia lines collision-broadened by hydrogen.

Measurement of half-widths and shapes of several rotational lines in nu sub 2 bands of ammonia, collision-broadened by hydrogen. The measurements were made at room temperature with a spectral resolution of 0.15 per cm. Line intensities and self-broadened half-widths were also measured. From the line-intensity data, an estimate of S sub band = 600 plus or minus 30 per sq cm per atm has been derived for the absolute intensity of the pair of bands. Hydrogen-broadened half-widths of all the lines have been found to be equal to 0.075 plus or minus 0.004 per cm per atm. For all the lines measured, shapes of the lines in NH3-H2 collisions seem to conform to the super-Lorenz line shape proposed by Varanasi et al. (1972) for dipole quadrupole collisions.

Varanasi, P.↗
NASA NTRS1972

Experimental and theoretical studies on collision-broadened lines in the nu-4 fundamental of methane.

High-resolution experimental and theoretical studies performed earlier by us on the collision-broadened rotational lines in the nu-3 and 2nu-3 bands of methane have been repeated on the lines in the nu-4 fundamental of the molecule. Line-width measurements and computations, as well as line-shape measurements, indicate that the significant differences which exist between the rotational term values of the nu-3 and nu-4 vibrational levels have no observable effect on the collision-broadening mechanism. Using the predictions of line-widths, based on the Anderson-Tsao-Curnutte theory in the extended version of Tejwani for octopolar molecules, the theoretical dependence of line-widths on temperature has been calculated for CH4-CH4, CH4-H2 and CH4-He collisions.

Varanasi, P.↗
NASA NTRS1972

Line shape parameters for HCl and HF in a CO2 atmosphere.

Results of high-resolution (0.1 cm/cm) on several CO2-broadened lines in the fundamentals of HCl35 and HCl37. Line intensities, half-widths, and shapes were determined at room temperature. Half-widths in HCl-CO2 collisions were computed for several temperatures, employing Anderson's (1949) theory. The measured shapes of HCl lines broadened by CO2 are described by a semiempirical super-Lorentzian shape. The curve-of-growth for this line shape is derived in terms of a function similar to the Ladenburgh-Reiche function. Absorption between R(0) and P(1) is affected by the appearance of several pressure-induced Q-branch lines, at the pressures from 1 to 10 atm used in the present study.

Varanasi, P.↗