Engineering topics
Publications and source records attributed to Ulrich, D. R..
Technique of improved ceramic-oxide crystal growth utilizes high viscosity solutions (glass or fused solvent). Compositions are selected on basis of technical importance, gravity sensitive properties, and apparent compatibility. Seeded fused-solvent technique uses bismuth germanate, lithium niobate or lead germanate.
The successful nucleation of bismuth germanate, B12GeO20 on a high quality seed and the growth of regions of single crystals of the same orientation of the seed are reported. Lead germanate, Pb5Ge3O11 was also identified as a ferroelectric crystal with large electrooptic and nonlinear optic constants. Solvent criteria, solvent/development, and crystal growth are discussed, and recommendations for future studies are included.
The technique of differential thermal analysis (DTA) was applied to the study of the Apollo 17 orange soil (74220,63) and the Apollo 16 glass coated anorthite (64455,21). These glasses show accentuated exotherms of strain relief in the annealing range which is indicative of rapid cooling. These are amenable to interpretation by comparison to the known history of synthetic glasses. Synthetic glasses were prepared whose similarity in behavior between the lunar glasses and their synthetic analogs is striking. Approximate rates of cooling of the lunar glasses were determined from comparative DTA of lunar and synthetic glasses and from the determination of the relation of strain relief in the annealing range to quench rate. At higher temperatures the glasses show exotherms of crystallization. The crystallization products associated with the exothermic reactions have been identified by X-ray diffraction and the surface morphologies developed by strain relief and crystallization have been characterized with scanning electron microscopy.
The growth of single crystals in a space environment is discussed. Several crystals which could be beneficially grown in weightless conditions are identified. For surface wave acoustic applications, the surface perfection and internal crystal perfection which are obtainable in space, are favorably indicated.
Research is reported on the growth of electronic ceramic single crystals from solution for the future growth of crystals in a microgravity environment. Work included growth from fused or glass solvents and aqueous solutions. Topics discussed include: crystal identification and selection; aqueous solution growth of triglycine sulphate (TGS); and characterization of TGS.
Many advanced electronic technologies and devices for the 1980's are based on sophisticated compound single crystals, i.e. ceramic oxides and compound semiconductors. Space processing of these electronic crystals with maximum perfection, purity, and size is suggested. No ecomonic or technical justification was found for the growth of silicon single crystals for solid state electronic devices in space.
Techniques and materials have recently been developed to obtain high dielectric films /K of 300 to 800/. High dielectric barium titanate particles are mixed in a barium titanate glass.
Bismuth trioxide-tellurium dioxide glasses have improved infrared transmission characteristics.
Electrical and optical properties of glasses in bismuth trioxide-tellurium dioxide system
Wear life analysis of hot pressed molybdenum disulfide-silver electrical contact brushes in vacuum
Kinetics of hot pressed molybdenum disulfide and molybdenum disulfide-silver compositions with effect on electric conduction processes
Electrical and infrared properties of glass in bismuth oxide-tellurium oxide system