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Tyson, B. J.

Publications and source records attributed to Tyson, B. J..

Measurements of CF2Cl2, CFCl3, and N2O in the lower stratosphere between 2 deg S and 73 deg N latitude

Mixing ratios are presented for CF2Cl2, CFCl3, and N2O in the lower stratosphere. They are derived from measurements made on samples collected by a high-altitude aircraft during a survey in the northern hemisphere in the summer of 1977. The vertical distributions of the mixing ratios of these species show a decrease with increasing altitude and a marked decrease at a given altitude with increasing latitude from 2 deg S to 73 deg N latitude. These results agree with measurements at similar latitudes in the fall of 1976 and with results of other experiments. The experimental apparatus and procedures are described in greater detail than in previous papers.

Vedder, J. F.↗

Trace constituent mixing ratios in the lower stratosphere during the 1977 intertropical convergence zone experiment

Minor constituents in the atmosphere can play an important role as tracers in studies of atmospheric transport and mixing. Simultaneous measurements of the vertical distribution of trace constituents in the troposphere and lower stratosphere were conducted in the region of the Intertropical Convergence Zone (ITCZ). An effort was made to measure the mixing ratios of selected trace constituents. A cryogenic sampling system on board a U-2 aircraft was used to acquire whole-air samples and to cryogenically collect samples at 13.7 to 21.3 km. Simultaneous tropospheric measurements using whole-air sampling canisters on board a Learjet aircraft were also carried out.

Vedder, J. F.↗

COS in the stratosphere

Carbonyl sulfide (COS) has been detected in the stratosphere, and mixing ratio measurements are reported for altitudes of 15.2 to 31.2 km. A large volume, cryogenic sampling system mounted on board a U-2 aircraft has been used for lower stratosphere measurements and a balloon platform for measurement at 31.2 km. These observations and measurements strongly support the concept that stratospheric COS is an important precursor in the formation of sulfuric acid aerosols.

Inn, E. C. Y.↗

Interhemispheric gradients of CF2Cl2, CFCl3, CCl4, and N2O

Direct real-time gas-chromatographic measurements of CF2Cl2, CFCl3, CCl4, and N2O were made at latitudes from 74 deg N to 62 deg S aboard a NASA Convair 990 as part of the 1976 NASA CV-990 Latitude Survey Mission between Alaska and New Zealand. A difference was found in the average mixing ratios of CF2Cl2 and CFCl3 between the Northern and Southern Hemispheres, but no differences were noted for CCl4 and N2O. The results support some of the previous studies of interhemispheric tropospheric gradients and suggest the lack of any significant tropospheric sinks.

Tyson, B. J.↗

Stratospheric measurements of CF2Cl2 and N2O

Concentrated samples of stratospheric air were obtained at pressure altitudes of 18.3 km and 21.3 km aboard U-2 aircraft, and at 28.3 km and 35.9 km aboard a balloon platform. The mixing ratios of CF2Cl2 and N2O are reported for locations in California, Oregon, Texas, and Quebec, Canada. The observed mixing ratios compare within a factor of 2 to those reported by other investigators and show a more rapid decrease with altitude than predicted by a two-dimensional model.

Tyson, B. J.↗

Lower stratosphere measurements of variation with latitude of CF2Cl2, CFCl3, CCl4, and N2O profiles in the northern hemisphere

Measurements were made from a U-2 aircraft of profiles of CF2Cl2, CFCl3, CCl4 and N2O in the lower stratosphere in a meridional survey at a longitude of 159 deg W during the period October 1 to November 14, 1976. The latitude distributions obtained show a marked decrease in mixing ratio with increasing latitude from about 7 deg N in the Intertropical Convergence Zone to about 79 deg N. The results suggest the importance of meridional transport and mixing in the stratosphere in accounting, at least in part, for the observed profile variation with latitude. The contaminants C2F4Cl2, C2F3Cl3, CHCCl3 and SF6 were also detected but their mixing ratios were small and no accurate standards were prepared for them.

Vedder, J. F.↗

Chlorinated hydrocarbons in the atmosphere - Analysis at the parts-per-trillion level by GC-MS

The propellant gases (Freons) used in aerosol spray cans can diffuse into the earth's upper atmosphere where they can react with the unfiltered ultraviolet radiation from the sun to reduce the earth's protective ozone layer. These Freons have been identified commonly by gas chromatography. Mass spectrometer data confirm other reports on the widespread concentrations of the Freons in the troposphere and demonstrate the presence of Freon 113 which has not been previously identified.

Tyson, B. J.↗

Volatilisation of terpenes from Salvia mellifera

The study demonstrates significant terpene volatilisation from Salvia mellifera. Net photosynthesis and dark respiration were measured in an intact branch of a potted plant using a gas analysis system. Photosynthesis and respiration rates were determined for various temperatures. The rates were directly proportional to leaf temperature and were the same in both light and dark reactions. Using the temperature curve for the steady-state rate of terpene volatilisation and the gas exchange characteristics, the daily carbon gain and terpene loss were calculated.

Tyson, B. J.↗