Engineering topics

Tucker, Dennis S.

Publications and source records attributed to Tucker, Dennis S..

At least 37 records · Page 2

NASA NTRS2003

Mechanisms for the Crystallization of ZBLAN

The objective of this ground based study is to test the hypothesis that shear thinning (the non-Newtonian response of viscosity to shear rate) is a viable mechanism to explain the observation of enhanced glass formation in numerous low-g experiments. In 1-g, fluid motion results from buoyancy forces and surface tension driven convection. This fluid flow will introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in fluids can be extremely low. It is believed that some fluids may have weak structure in the absence of flow. Very small shear rates could cause this structure to collapse in response to shear resulting in a lowering of the viscosity of the fluid. The hypothesis of this research is that: Shear thinning in undercooled liquids decreases the viscosity, increasing the rate of nucleation and crystallization of glass forming melts. Shear in the melt can be reduced in low-g, thus enhancing undercooling and glass formation. The viscosity of a model glass (lithium di-silicate, L2S) often used for crystallization studies has been measured at very low shear rates using a dynamic mechanical thermal analyzer. Our results are consistent with increasing viscosity with a lowering of shear rates. The viscosity of L2S may vary as much as an order of magnitude depending on the shear rate in the temperature region of maximum nucleation and crystal growth. Classical equations for nucleation and crystal growth rates, are inversely related to the viscosity and viscosity to the third power respectively. An order of magnitude variation in viscosity (with shear) at a given temperature would have dramatic effects on glass crystallization Crystallization studies with the heavy metal fluoride glass ZBLAN (ZrF2-BaF2-LaF3-AlF3-NaF) to examine the effect of shear on crystallization are being initiated. Samples are to be melted and quenched under quiescent conditions at different shear rates to determine the effect on crystallization. The results from this study are expected to advance the current scientific understanding of glass formation in low-g and glass crystallization under glass molding conditions and will improve the scientific understanding of technological processes such as fiber pulling, bulk amorphous alloys, and glass fabrication processes.

Ethridge, Edwin C.↗

NASA NTRS2003

Lifetime Predictions of a Titanium Silicate Glass with Machined Flaws

A dynamic fatigue study was performed on a Titanium Silicate glass to assess its susceptibility to delayed failure and to compare the results with those of a previous study. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions. The material strength and lifetime was seen to increase due to the removal of residual stress through grinding and polishing. Influence on time-to-failure is addressed for the case with and without residual stress present. Titanium silicate glass otherwise known as ultra-low expansion (ULE)* glass is a candidate for use in applications requiring low thermal expansion characteristics such as telescope mirrors. The Hubble Space Telescope s primary mirror was manufactured from ULE glass. ULE contains 7.5% titanium dioxide which in combination with silica results in a homogenous glass with a linear expansion coefficient near zero. delayed failure . This previous study was based on a 230/270 grit surface. The grinding and polishing process reduces the surface flaw size and subsurface damage, and relieves residual stress by removing the material with successively smaller grinding media. This results in an increase in strength of the optic during the grinding and polishing sequence. Thus, a second study was undertaken using samples with a surface finish typically achieved for mirror elements, to observe the effects of surface finishing on the time-to-failure predictions. An allowable stress can be calculated for this material based upon modulus of rupture data; however, this does not take into account the problem of delayed failure, most likely due to stress corrosion, which can significantly shorten lifetime. Fortunately, a theory based on fracture mechanics has been developed enabling lifetime predictions to be made for brittle materials susceptible to delayed failure. Knowledge of the factors governing the rate of subcritical flaw growth in a given environment enables the development of relations between lifetime, applied stress and failure probability for the material under study. Dynamic fatigue is one method of obtaining the necessary information to develop these relationships. In this study, the dynamic fatigue method was used to construct a time-to-failure diagram for polished ULE glass.

Tucker, Dennis S.↗

NASA NTRS2003

Proof Test Diagrams for a Lithia-Alumina-Silica Glass-Ceramic

The glass-ceramic (Zerodur, Schott Glaswerke, Mainz, Germany) contains 70% to 78% by weight crystalline phase of high-quartz structure with a mean crystal size of 50-55 nm. The vitreous phase has a positive thermal expansion coefficient which is practically balanced by the negative coefficient of the crystalline phase. This results in a material which can maintain longitudinal stability during thermal cycling. This was one of the reasons for its choice as the material for the grazing incidence mirrors for the Chandra X-Ray Facility. Brittle materials such as glass and glass-ceramics which exhibit slow crack growth and subsequent fast fracture to failure exhibit a time dependence in strength. The decrease in strength for a constant applied load is known as static fatigue. In many cases, environment plays a major role in the material lifetime. It has been shown for silicate glasses that crack velocity will increase as the amount of water vapor in the environment surface finish and rate of loading. A rough surface finish leads to a lower tensile strength than for an optically polished surface. The strength of glass is observed in general to increase with increasing load rate. This phenomena is known as dynamic fatigue. This was observed for Zerodur by Tucker and Gent and Tucker in previous dynamic fatigue studies, in which lifetimes were obtained. All of the above named factors need to be considered when glass is to be used in load bearing applications.

Tucker, Dennis S.↗

NASA NTRS2003

Effects of Gravity on ZBLAN Glass Crystallization

The effects of gravity on the crystallization of ZrF4-BaF2-LaF3-AlF3- NaF glasses have been studied utilizing NASA's KC135 and a sounding rocket, Fibers and cylinders of ZBLAN glass were heated to the crystallization temperature in unit and reduced gravity. When processed in unit gravity the glass crystallized, but when processed in reduced gravity, crystallization was suppressed. A possible explanation involving shear thinning is presented to explain these results.

Tucker, Dennis S.↗

NASA NTRS2002

Dynamic Fatigue of a Titanium Silicate Glass

A dynamic fatigue study was performed on a Titanium Silicate Glass in order to assess its susceptibility to delayed failure. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions for optical elements made from this material. The material has reasonably good resistance (N=23 to stress corrosion in ambient conditions).

Tucker, Dennis S.↗

NASA NTRS2002

An Automated Optical Fiber Puller for Use in Low-Earth Orbit

With the slowdown in space station construction, limiting astronaut time for scientific experiments, an effort is being made to automate certain experiments. One such experiment is production of heavy metal fluoride fibers in the microgravity environment. Previous work by this author and others have shown that microgravity inhibits crystallization of ZBLAN glass. Thus an automated experiment has been designed. This experiment will consist of several elements, one which includes the use of an autonomous robot to initiate fiber pulling. The first element will be to melt the preform to eliminate crystals. The preform tip will then be heated to the viscosity necessary for fiber drawing. The robot will initiate the draw and attach the fiber end to the take-up reel. Once fiber pulling has commenced, sensors will be used to detect a fiber break, whereupon the robot can re-initiate the pulling process. The fiber will be coated with a polymer and the polymer cured with ultraviolet light. A laser micrometer will be used to monitor fiber diameter. The experiment is designed so that up to 10 preforms can be pulled into fiber during one flight. The apparatus will be mounted on a free-flying carrier which will be placed into low-earth orbit from the cargo bay of the space shuttle by the shuttle robot arm. The experiment can be started by a signal from the shuttle or from the ground via telescience. The experiment will proceed automatically using specially designed algorithms and will be monitored from the ground. The carrier will be picked up by the shuttle before return to earth.

Tucker, Dennis S.↗

NASA NTRS2001

Mechanisms for the Crystallization of Zblan

The heavy metal fluoride glasses represent a class of reasonably good glass forming compositions with very unique infrared optical properties that have been of interest to researchers for 20 years. The most extensively studied glass with the most potential for practical applications is ZBLAN which contains the fluorides of zirconium, barium, lanthanum, aluminum, and sodium. It has a broad transmission range (0.3-6 um), low index of refraction (about 1.43), low dispersion, low Raleigh scattering, ultra-low thermal 2 dispersion, and potential ultra-low signal attenuation. Potential applications include fiber amplifiers, fiber optic gyroscopes, delivery systems for laser cutting, drilling and surgery, radiation resistant data links, nonlinear optical systems, and ultra-low-loss repeater-less transcontinental and transoceanic optical fiber. Potential markets for these materials are in the tens of billions of dollars per year. Optical fiber from this system possess excellent transmission characteristics in the IR, but the glass is somewhat susceptible to nucleation and crystallization. The theoretical intrinsic loss coefficient for ZBLAN at 2 microns is 0.00 1 dB/Km. Extrinsic losses, however, cause significant attenuation. The lowest loss coefficient measured is 0.7 dB/Km. This compares with the loss coefficient for fiber optic grade fused silica glass of 0.2 dB/Km. The extrinsic losses in ZBLAN have been attributed to 1) impurities which might be lowered by containerless processing and 2) to scattering from micro-crystallites that form during glass preform production or during fiber drawing.

Ethridge, Edwin C.↗

NASA NTRS2001

Production of Bulk and Fiber Glass in Space

The production of bulk glass and fiber glass in space and on the moon and Mars should lead to superior products. Specifically glass plates for windows and optical elements could be produced with theoretical strengths by production in vacuum. Water vapor is known to decrease glass strength by up to two orders of magnitude from theoretical. A low gravity glass plate apparatus prototype has been designed and built which uses centrifugal force to shape the glass and solar energy to melt the glass. Glass fiber could be produced on the moon or Mars from in-situ materials using standard technologies. This material could then be used as reinforcement in composite materials in construction of bases. Also, it has been shown that processing in reduced gravity suppresses crystallization in certain heavy metal fluoride glasses. It is proposed to reprocess optical fiber preforms on the space station and then pull these into optical fiber. It is estimated that the attenuation coefficient should be reduced by two orders of magnitude.

Tucker, Dennis S.↗

NASA NTRS2001

An Explanation of the Effects of Gravity on the Crystallization of ZBLAN Glass

The effects of gravity on crystallization of ZBLAN glasses have been studied utilizing NASA's KC-135 aircraft and a sounding rocket. Fibers were heated to the crystallization temperature in unit and reduced gravity. The fibers processed in unit gravity exhibited crystallization, while fibers processed in reduced gravity showed no signs of crystallization. An explanation based on shear thinning of liquids is presented to explain these results.

Tucker, Dennis S.↗

NASA NTRS2001

Dynamic Fatigue of ULE Glass

Ultra Low Expansion (ULE) glass is used in a number of applications which require a low thermal expansion coefficient. One such application is telescope mirror elements. An allowable stress can be calculated for this material based upon modulus of rupture data; however, this does not take into account the problem of delayed failure. Delayed failure, due to stress corrosion can significantly shorten the lifetime of a glass article. Knowledge of the factors governing the rate of subcritical flaw growth in a given environment enables the development of relations between lifetime, applied stress and failure probability for the material under study. Dynamic fatigue is one method of obtaining the necessary information to develop these relationships. In this study, the dynamic fatigue method was used to construct time-to-failure diagrams for both 230/270 ground and optically polished samples. The grinding and polishing process reduces the surface flaw size and subsurface damage, and relieves residual stress by removing materials with successively smaller grinding media. This resulted in an increase in the strength of the optic during the grinding and polishing sequence. There was also an increase in the lifetime due to grinding and polishing. It was found that using the fatigue parameters determined from the 230/270 grit surface are not significantly different from the optically polished values. Although the lower bound of the polished samples is more conservative, neither time-to-failure curves lie beyond the upper or lower bound of the confidence limits. Therefore, designers preferring conservative limits could use samples without residual stress present (polished samples) to determine the fatigue parameters and inert Weibull parameters from samples with the service condition surface, to determine time-to-failure of the optical element.

Tucker, Dennis S.↗

NASA NTRS2001

Utilization of Infrared Fiber Optic in the Automotive Industry

Fiber optics are finding a place in the automotive industry. Illumination is the primary application today. Soon, however, fiber optics will be used for data communications and sensing applications. Silica fiber optics and plastic fibers are sufficient for illumination and communication applications however, sensing applications involving high temperature measurement and remote gas analysis would benefit from the use of infrared fiber optics. Chalcogonide and heavy metal fluoride glass optical fibers are two good candidates for these applications. Heavy metal fluoride optical fibers are being investigated by NASA for applications requiring transmission in the infrared portion of the electromagnetic spectrum. Zirconium-Barium-Lanthanum-Aluminum-Sodium-Fluoride (ZBLAN) is one such material which has been investigated. This material has a theoretical attenuation coefficient 100 times lower than that of silica and transmits into the mid-IR. However, the measured attenuation coefficient is higher than silica due to impurities and crystallization. Impurities can be taken care of by utilizing cleaner experimental protocol. It has been found that crystallization can be suppressed by processing in reduced gravity. Fibers processed in reduced gravity on the KC135 reduced gravity aircraft were found to be free of crystals while those processed on the ground were found to have crystals. These results will be presented along with plans for producing continuous lengths of ZBLAN optical fiber on board the International Space Station.

Tucker, Dennis S.↗

NASA NTRS2001

Infrared Fibers for Use in Space-Based Smart Structures

Infrared optical fibers are finding a number of applications including laser surgery, remote sensing, and nuclear radiation resistant links. Utilizing these fibers in space-based structures is another application, which can be exploited. Acoustic and thermal sensing are two areas in which these fibers could be utilized. In particular, fibers could be embedded in IM7/8552 toughened epoxy and incorporated into space structures both external and internal. ZBLAN optical fibers are a candidate, which have been studied extensively over the past 20 years for terrestrial applications. For the past seven years the effects of gravity on the crystallization behavior of ZBLAN optical fiber has been studied. It has been found that ZBLAN crystallization is suppressed in microgravity. This lack of crystallization leads to a fiber with better transmission characteristics than its terrestrial counterpart.

Tucker, Dennis S.↗

NASA NTRS2000

Reduced Gravity Zblan Optical Fiber

Two optical fiber pullers have been designed for pulling ZBLAN optical fiber in reduced gravity. One fiber puller was designed, built and flown on board NASA's KC135 reduced gravity aircraft. A second fiber puller has been designed for use on board the International Space Station.

Tucker, Dennis S.↗

NASA NTRS2000

Mechanisms for the Crystallization of ZBLAN

A number of research teams have observed that glass forming melts that are solidified in low-g exhibit enhanced glass formation. This project will examine one of these glasses, the heavy metal fluoride glass ZBLAN. A four year ground based research program has been approved to examine the crystallization of ZBLAN glasses with the purpose of testing a theory for the crystallization of ZBLAN glass. The theory could explain the general observations of enhanced glass formation of other glasses melted and solidified in low-g. Fluid flow in 1-g results from buoyancy forces and surface tension driven convection. This fluid flow can introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in fluids in low-g are extremely low. It is believed that fluids may have some weak structure in the absence of flow. Even very small shear rates could cause this structure to collapse in response to the shear. A general result would be shear thinning of the fluid. The hypothesis of this research is that: Shear thinning in undercooled liquids increases the rate of nucleation and crystallization of glass forming melts. Shear of the melt can be reduced in low-g enhancing undercooling and glass formation. Samples will be melted and quenched in 1-g under quiescent conditions at a number of controlled cooling rates to determine times and temperatures of crystallization and heated at controlled heating rates to determine kinetic crystallization parameters. Experiments will also be performed on the materials while under controlled vibration conditions and compared with the quiescent experiments in order to evaluate the effect of shear in the liquid on crystallization kinetics. After the experimental parameters are well known, experiments will be repeated under low-g (and 2-g) conditions on the KC-135 aircraft during low-g parabolic maneuvers. The results will determine the effects of shear on crystallization. Our experimental setups will be designed with low-g experiments in mind and will be tested as breadboard low-g experiments. It is very likely that the thermal analysis instrumentation can be adapted to be run in the microgravity glovebox facilities. Critical space experiments may result to test the theory at longer low-g time experiments in space.

Ethridge, Edwin C.↗

NASA NTRS1999

The Effects of Gravity on ZBLAN Glass

Heavy metal fluoride glass fibers show promise in applications such as surgical lasers, spectroscopy and imaging fiber bundles. ZBLAN, which is within this class has been studied for a number of years. ZBLAN's theoretical attenuation coefficient is approximately 0.002 dB/km which is much better than that of fused silica at 0.2 dB/km. However, due to impurities and crystallites the attenuation coefficients achieved to date are considerably larger than those of fused silica. Impurities can be controlled with better processing techniques. Crystallization has been found to be a function of gravity. It is found that heating to the crystallization temperature in unit gravity results in crystallization while heating in reduced gravity does not. The exact mechanism for this phenomenon is not known but is speculated to be related to stress.

Tucker, Dennis S.↗

NASA NTRS1998

Commercial Production of Heavy Metal Fluoride Glass Fiber in Space

International Space Station Alpha (ISSA) will provide a platform not only for materials research but also a possible means to produce products in space which cannot be easily produced on the ground. Some products may even be superior to those now produced in unit gravity due to the lack of gravity induced convection effects. Our research with ZrF4-BaF2-LaF3-AlF3-NaF (ZBLAN glass) has shown that gravity does indeed play a major role in the crystallization behavior of this material. At the present time ZBLAN is being produced on earth in fiber optic form for use in surgical lasers and fiber optic lasers among other applications. High attenuation coefficients, however, have kept this material from being used in other applications such as long haul data transmission links. The high attenuation coefficients are due to impurities which can be removed through improved processing techniques and crystals which can only be removed or prevented from forming by processing in a reduced gravity environment.

Tucker, Dennis S.↗

NASA NTRS1998

Processing Glass Fiber from Moon/Mars Resources

Processing of Lunar/Mars raw materials into usable structural and thermal components for use on a Lunar/Mars base will be essential for human habitation. One such component will be glass fiber which can be used in a number of applications. Glass fiber has been produced from two lunar soil simulants. These two materials simulate lunar mare and lunar highlands soil compositions. Short fibers containing recrystallized areas were produced from the as-received simulants. Doping the highland simulant with 8 weight percent boria yielded a material which could be spun continuously. The effects of lunar gravity on glass fiber formation were studied utilizing NASA's KC 135 aircraft. Gravity was found to play a role in crystallization and final fiber diameter.

Tucker, Dennis S.↗

NASA NTRS1997

Effects of Gravity on Processing Heavy Metal Fluoride Fibers

The effects of gravity on the crystal nucleation of heavy metal fluoride fibers have been studied in preliminary experiments utilizing NASA's KC-135 reduced gravity aircraft and a microgravity sounding rocket flight. Commercially produced fibers were heated to the crystallization temperature in normal and reduced gravity. The fibers processed in normal gravity showed complete crystallization while the fibers processed in reduced gravity did not show signs of crystallization.

Tucker, Dennis S.↗