A Novel Approach to Measuring Inelastic Differential Cross Sections for Electron-Molecule
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Engineering topics
Publications and source records attributed to Trajmar, Sandor.
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New experimental electron-energy-loss data have been used to extract differential and integral cross sections for excitation of the 2 1P level, and for the overlapping (3 1P, 3 1D, 3 3D) levels of helium, at 30-, 50-, and 100-eV incident electron energies. First-order many-body theory (FOMBT) has been used to calculate the differential and integral cross sections for excitation of the n 1P (n = 2,...,6) levels of helium by electron impact, for incident electron energies from threshold to 500 eV. Detailed comparisons between these two new sets of data are made as well as comparisons with appropriate published experimental and theoretical results. A simple scaling relationship is derived from the FOMBT results for n = 2,...,6 that provides differential and integral cross sections for all symmetry final levels of helium with n = 6 or greater.
First-order many-body theory has been used to calculate collision-frame magnetic-sublevel differential cross sections for electron-impact excitation of the n 1P (n = 2,3,4,5,6) levels of helium for electrons with incident energy in the 25-500-eV range. By combining results from electron-impact differential-cross-section measurements and electron-photon coincidence measurements, experimental magnetic-sublevel cross sections have also been derived for the excitation of the 2 1P and 3 1P levels. The theory predicts a pronounced minimum for the M = 0 magnetic-sublevel differential cross section for incident electron energies around 30 eV. The theoretical results are compared to the experimental data and some other theoretical results.
Differential cross sections for elastic electron scattering by SO2 were measured by utilizing a modulated, crossed-beam method and calibration against He. The energy and angular ranges were from 5 to 50 eV and from 12 to 156 deg, respectively. The present results are compared with earlier data of Orient et al. (1982), and it is suggested that their cross section values should be increased by about a factor of two.
Need for second laser eliminated. In scheme for separation of isotopes, electrons of suitable kinetic energy ionize specific isotope excited by laser beam in magnetic field. Ionization by electron beams cheap and efficient in comparison to ionization by laser beams, and requires no special technical developments. Feasibility of new scheme demonstrated in selective ionization of Ba138, making possible separation of isotope from Ba isotopes of atomic weight 130, 132, 134, 135, 136, and 137.
The apparatus comprises means for producing an atomic beam containing the isotope of interest and other isotopes. Means are provided for producing a magnetic field traversing the path of the atomic beam of an intensity sufficient to broaden the energy domain of the various individual magnetic sublevels of the isotope of interest and having the atomic beam passing therethrough. A laser beam is produced of a frequency and polarization selected to maximize the activation of only individual magnetic sublevels of the isotope of interest with the portion of its broadened energy domain most removed from other isotopes with the stream. The laser beam is directed so as to strike the atomic beam within the magnetic field and traverse the path of the atomic beam whereby only the isotope of interest is activated by the laser beam. The apparatus further includes means for producing a collimated and high intensity beam of electrons of narrow energy distribution within the magnetic field which is aimed so as to strike the atomic beam while the atomic beam is simultaneously struck by the laser beam and at an energy level selected to ionize the activated isotope of interest but not ground state species included therewith. Deflection means are disposed in the usual manner to collect the ions.