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Toon, Owen B.

Publications and source records attributed to Toon, Owen B..

At least 91 records · Page 5

Denitrification mechanisms in the polar stratospheres

Microphysical simulations suggest that the time required for nitric acid particles to sediment from the stratosphere is comparable to the time required for falling ice particles to incorporate nitric acid vapor from the vapor phase. Since nitric acid particles form earlier in the winter than ice particles, these simulations favor denitrification being a separate process from dehydration, with denitrification being due to nitric acid particles and dehydration due to ice particles. In the simulations, the column abundance of nitric acid is only depleted if temperatures low enough for nitric acid particles to exist extend to the altitude above which the column is measured. Such low temperatures are infrequent in the Arctic lower stratosphere, which may be the main reason that the Arctic stratospheric column shows little loss of nitric acid during winter, while the colder Antarctic stratospheric column shows a substantial loss of nitric acid.

Toon, Owen B.↗

DC-8 mission planning

A number of tasks needed to be performed to operate the DC-8 aircraft in the Arctic Ozone Expedition during 1989. These included development of improved navigational computer programs and performing advanced planning for flight tracks. The missions required further work in the field to plan flight tracks and to establish a data archive. The DC-8 aircraft was operated during the deployment phase of the Arctic Ozone Expedition. Data were collected revealing the presence of extensive systems of polar stratospheric clouds. The data also showed the evolution of the chlorine and nitrogen chemistry within the Arctic vortex. A navigational computer code was improved so that the DC-8 navigators could perform their function more efficiently.

Toon, Owen B.↗

Stratospheric dynamics

A global circulation model is being used to study the dynamical behavior of stratospheric planetary waves (waves having horizontal wavelengths of tens of thousands of kilometers) forced by growing cyclonic disturbances of intermediate scale, typically with wavelengths of a few thousand kilometers, which occur in the troposphere. Planetary scale waves are the dominant waves in the stratosphere, and are important for understanding the distribution of atmospheric trace constituents. Planetary wave forcing by intermediate scale tropospheric cyclonic disturbances is important for producing eastward travelling planetary waves of the sort which are prominent in the Southern Hemisphere during winter. The same global circulation model is also being used to simulate and understand the rate of dispersion and possible stratospheric climatic feedbacks of the El Chichon volcanic aerosol cloud. By comparing the results of the model calculation with an established data set now in existence for the volcanic cloud spatial and temporal distribution, stratospheric transport processes will be better understood, and the extent to which the cloud modified stratospheric wind and temperature fields can be assessed.

Young, Richard E.↗

Studies of stratospheric particulates

A sophisticated computer model of polar stratospheric clouds was developed and used to study the properties of ice clouds. The model has recently been extended to investigate nitric acid clouds and ice clouds as well as their interactions with stratospheric gases. The model is now being applied to interpret data collected during recent expeditions to the Antarctic and the Arctic. Some work has also been done to understand the properties of noctilucent clouds and their implications for the chemistry and dynamics of the upper stratosphere.

Toon, Owen B.↗

Simulations of the large-scale environment during the FIRE Cirrus IFO

A numerical model that can facilitate the study of cirrus cloud systems is described in an effort to understand the dynamics during the first FIRE IFO. The model has a developed horizontal and vertical structure in the moisture fields with scales of order 200 km that were not found in the NMC analyses, suggesting that the model simulations can be used to describe the large-scale environment in which aircraft, surface, and satellite observations were made. The results of this preliminary simulation warrant application of the model to other case studies, particularly that of October 27-28, 1986.

Westphal, Douglas L.↗

Heterogeneous physicochemistry of the polar ozone hole

Processes occurring in the polar winter stratosphere, which involve polar stratospheric clouds (PSCs), are investigated using observations from the Airborne Antarctic Ozone Experiment. In particular, data on the properties of PSCs and their physical chemistry, the microphysical processes and time constants for cloud processes, the heterogeneous chemical processes and their time constants, and nonlinearities in the long-term ozone trend associated with physical and chemical processes are examined. The chemical reactions leading to the depletion of the inert chlorine reservoir in a presence of type I PSCs are established, and it is shown that type II PSCs contribute to chemical processing that sustains the chemical imbalance of the polar stratosphere. It is shown that, using a simple model, the decadal evolution of the Antarctic ozone hole may be understood through nonlinearities in the heterogeneous chemistry, with possible contributing effects of variations in stratospheric temperatures and water vapor concentrations.

Turco, Richard P.↗

Rapid calculation of radiative heating rates and photodissociation rates in inhomogeneous multiple scattering atmospheres

The solution of the generalized two-stream approximation for radiative transfer in homogeneous multiple scattering atmospheres is extended to vertically inhomogeneous atmospheres in a manner which is numerically stable and computationally efficient. It is shown that solar energy deposition rates, photolysis rates, and infrared cooling rates all may be calculated with the simple modifications of a single algorithm. The accuracy of the algorithm is generally better than 10 percent, so that other uncertainties, such as in absorption coefficients, may often dominate the error in calculation of the quantities of interest to atmospheric studies.

Toon, Owen B.↗

On the diurnal variation of noctilucent clouds

The relationship between nuctilucent clouds (NLC), which are observed from the ground usually within 2 or 3 hrs of local midnight, and the polar mesospheric clouds (PMC), which are observed by satellites in full daylight, as well as the reason for the differences in their optical properties and their observed heights are investigated. Based on a suggestion that these differences can be attributed to a diurnal variation in the properties of a single type of cloud, two published models of the diurnal and semidiurnal variations of temperature, vertical wind speed, and eddy diffusion coefficient at high latitude to simulate the evolution of ice clouds over a 24-hr period. The results show that the minimum in temperature at about 2000 hours LT causes a sharp maximum in scattered brightness to occur about 1 hour before local midnight, with up to a factor of 7 variation in cloud brightness between noon and midnight. It is noted, however, that considerable uncertainties exist in these tidal models.

Jensen, Eric↗

Physical processes in polar stratospheric ice clouds

The formulation and evolution of polar stratospheric ice clouds are simulated using a one-dimensional model of cloud microphysics. It is found that the optical thickness and particle size of ice clouds depend on the cooling rate of the air in which the cloud formed. It is necessary that there be an energy barrier to ice nucleation upon the preexisting aerosols in order to account for the cooling rate dependence of the cloud properties.

Toon, Owen B.↗

Self-limiting physical and chemical effects in volcanic eruption clouds

One-dimensional aerosol microphysical and photochemical models are used to study the chemistry of stratospheric volcanic clouds. The results indicate that the aerosol microphysical processes of condensation and coagulation produce larger particles as the SO2 injection rate is increased. Larger particles have a smaller optical depth per unit mass and settle out of the stratosphere at a faster rate than smaller ones, restricting the total number of particles in the stratosphere. The microphysical processes moderate the impact of volcanic clouds on the earth's radiation budget and climate, suggesting that volcanic effects may be self limiting. It is noted that the injection of HCl into the stratosphere, which could lead to large ozone changes, is limited by a cold trap effect in which HCl and water vapor condense on ash particles in the rising volcanic plume and fall out as ice.

Pinto, Joseph P.↗

Moist convection on Neptune

A study of methane moist convection on Neptune examines the stability conditions which initiate moist convection of methane clouds. Temperature lapse rates that are unstable to moist convection are subadiabatic by a factor of two or more, while adiabatic and superadiabatic lapse rates are stable. In the observed Neptune temperature structure, vertical velocities greater than 40 m/s are required to lift moist air above the stable region and initiate moist convection. Alternatively, moist convection could be initiated by air that is slightly drier than its surroundings. Moist convective clouds achieve altitudes up to 100 mb, thereby exceeding the temperature minimum and depositing methane in the Neptune stratosphere. At least 2000 such clouds penetrate the Neptune stratosphere/hour.

Stoker, Carol R.↗

Relation between increasing methane and the presence of ice clouds at the mesopause

The possiblity is investigated that a substantial change has occurred in middle-atmospheric water vapor as a result of the increase in atmospheric methane over the past century and a half. It is shown from modeling of mesospheric ice-particle formation that noctilucent cloud brightness should be a sensitive indicator of the water content at the high-latitude summertime mesopause. From an examination of the historical record of noctilucent cloud occurrence, it is found that such clouds are absent from the record before 1885, a finding which is consistent with the hypothesis proposed in this paper.

Thomas, Gary E.↗

Methane rain on Titan

The atmosphere of Titan is characterized by means of model computations based on Voyager IRIS IR spectra and published data from laboratory determinations of absorption coefficients and cloud refractive indices. The results are presented in tables and graphs, and it is pointed out that the presence of Ar is not required in the model. Particular attention is given to the role of CH4, which is found to form patchy clouds (with particle radii of 50 microns or greater and visible/IR optical depths of 2-5) at altitudes up to about 30 km. The mechanisms by which such rain-sized particles could form are discussed, and it is suggested that the observed 500-600/cm spectrum is affected much less by the CH4 clouds than by H2 or variations in the temperature of the high-altitude haze.

Toon, Owen B.↗

A case study of mobilization and transport of Saharan dust

The mobilization and transport of the Saharan dust over the West Africa and the tropical Atlantic Ocean during the days of August 23-28, 1974, were investigated using the data set developed by GFDL, together with numerical models of the atmosphere and aerosol. It was found that the mobilization of dust during this period was related to the passage of a shallow easterly wave; mobilization was effected by dry convective mixing of low-level jets associated with the easterly wave. Model simulations show that the aerosol at any one point can be a complicated mixture of particles lifted at different times and different places; bimodal size distributions developed when dust was mobilized within a dust plume that was generated on a previous day.

Westphal, Douglas L.↗

On the size and composition of particles in polar stratospheric clouds

Attenuation measurements of the solar radiation between 1.5 and 15 micron wavelengths were performed with the airborne (DC-8) JPL MARK 4 interferometer during the 1987 Antarctic Expedition. The opacities not only provide information about the abundance of stratospheric gases but also about the optical depths of polar stratospheric clouds (PSCs) at wavelengths of negligible gas absorption (windows). The optical depth of PSCs can be determined for each window once the background attenuation, due to air-molecules and aerosol has been filtered out with a simple extinction law. The ratio of optical thicknesses at different wavelengths reveals information about particle size and particle composition. Among the almost 700 measured spectra only a few PSC cases exist. PSC events are identified by sudden reductions in the spectrally integrated intensity value and are also verified with backscattering data from an upward directed lidar instrument, that was mounted on the DC-8. For the selected case on September 21st at 14.40 GMT, lidar data indicate an optically thin cloud at 18k and later an additional optically thick cloud at 15 km altitude. All results still suffer from: (1) often arbitrary definitions of a clear case, that often already may have contained PSC particles and (2) noise problems that restrict the calculations of optical depths to values larger than 0.001. Once these problems are handled, this instrument may become a valuable tool towards a better understanding of the role PSCs play in the Antarctic stratosphere.

Kinne, Stefan↗

Physical processes in polar stratospheric ice clouds

A one dimensional model of cloud microphysics was used to simulate the formation and evolution of polar stratospheric ice clouds. Some of the processes which are included in the model are outlined. It is found that the clouds must undergo preferential nucleation upon the existing aerosols just as do tropospheric cirrus clouds. Therefore, there is an energy barrier between stratospheric nitric acid particles and ice particles implying that nitric acid does not form a continuous set of solutions between the trihydrate and ice. The Kelvin barrier is not significant in controlling the rate of formation of ice particles. It was found that the cloud properties are sensitive to the rate at which the air parcels cool. In wave clouds, with cooling rates of hundreds of degrees per day, most of the existing aerosols nucleate and become ice particles. Such clouds have particles with sizes on the order of a few microns, optical depths on order of unity and are probably not efficient at removing materials from the stratosphere. In clouds which form with cooling rates of a few degrees per day or less, only a small fraction of the aerosols become cloud particles. In such clouds the particle radius is larger than 10 microns, the optical depths are low and water vapor is efficiently removed. Seasonal simulations show that the lowest water vapor mixing ratio is determined by the lowest temperature reached, and that the time when clouds disappear is controlled by the time when temperatures begin to rise above the minimum values.

Toon, Owen B.↗

How climate evolved on the terrestrial planets

It is argued that the difference in the climates of Venus, earth, and Mars is due largely to differences in their ability to cycle CO2 between the crust and atmosphere. It is suggested that the earth has always had a moderate climate primarily because its cycling mechanism increases the amount of CO2 in the atmosphere when the surface of the planet cools and reduces the amount when the ground temperature rises. Mars is now frozen because it has lost the ability to cycle the gas back into its atmosphere, and Venus is a hothouse because it has no way of removing CO2 from its atmosphere.

Kasting, James F.↗

Atmospheric effects of a Canadian forest fire smoke plume

In 1982, a northern British Columbia forest fire created a massive smoke plume that could be detected for several days in satellite imagery. The radiative and dynamical impacts of this large forest fire smoke plume are investigated using interactive prognostic models of atmospheric circulation, aerosol microphysics and transport, and radiative heat transfer.

Westphal, Douglas L.↗