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Toon, G. C.

Publications and source records attributed to Toon, G. C..

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

The Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment: Deployment on the ATLAS Space Shuttle Missions

The ATMOS Fourier transform spectrometer was flown for a fourth time on the Space Shuttle as part of the ATLAS-3 instrument payload in November 1994. More than 190 sunrise and sunset occultation events provided measurements of more than 30 atmospheric trace gases at latitudes 3 - 49 deg N and 65 - 72 deg S, including observations both inside and outside the Antarctic polar vortex. The instrument configuration, data retrieval methodology, and mission background are described to place in context analyses of ATMOS data presented in this issue.

Gunson, M. R.↗
NASA NTRS1996

Balloon observations of organic and inorganic chlorine in the stratosphere: the role of HClO4 production on sulfate aerosols

Simultaneous observations of stratospheric organic and inorganic chlorine were made in September 1993 out of Fort Sumner, New Mexico, using JPL balloon-borne MkIV interferometer. Between 15 and 20 km, a significant fraction (20-60%) of the inorganic chlorine could not be accounted for by the sum of measured HCl, ClONO2, and HOCl. Laboratory measurements of the reaction of ClO radicals on sulfuric acid solutions have indicated that, along with HCl, small amounts of perchloric acid, HClO4, were formed. Very little is known about the fate of HClO4 in the stratosphere and we use a photochemical box model to determine the impact of this new species on the partitioning of inorganic chlorine in the stratosphere. Assuming that HClO4 is photochemically stable, it is shown that in the enhanced aerosol loading conditions resulting from Mt. Pinatubo's eruption, HClO4 could represent a significant reservoir of chlorine in the lower stratosphere, sequestering up to 0.2 ppbv (or 50%) of the total inorganic chlorine at 16 km. The occurrence of this new species could bring to closure the inorganic chlorine budget deficiency made apparent by recent ER-2 aircraft in situ measurements of HCl.

unmanned↗
NASA NTRS1995

Balloon-borne observations of mid-latitude hydrofluoric acid

Measurements of stratospheric hydrofluoric acid (HF) have been made by the JPL MkIV interferometer during high-altitude balloon flights. Infrared solar absorption spectra were acquired near 35 deg N at altitudes between local tropopause and 38 km. Volume mixing ratio profiles of HF derived from 4 flights (1990-93), in conjunction with simultaneously observed N2O profiles, indicate an average rate of HF increase of (5.5 +/- 0.3)% per year, in agreement with time-dependent, two-dimensional model simulations (6% per year) and ATMOS measurements.

Sen, B.↗
NASA NTRS1994

Hydrochloric acid and the chlorine budget of the lower statosphere

Concentrations of HCl measurements in the lower stratosphere in 1993 by the ALIAS instrument on the ER-2 aircraft reveal that only 40% of inorganic chlorine (Cl(y), inferred from in situ measurements of organic chlorinated sources gases) is present as HCl, significantly lower than model predictions. Although the sum of measured HCl, ClO and ClONO2, the latter inferred from measurements of ClO and NO2 equals Cl(y) to within the incertainty of measurement, it is systematically less than Cl(y) by 30-50%. This discrepancy suggests that concentrations of ClONO2 may exceed those of HC; near 20 km altitude, consistent with a slower photolysis rate for ClONO2 than calculated using recommended cross sections. Comparison of profiles of HCl measured during 1992 and 1193 at mid-latitudes by balloon (BLISS and MARKIV), space shuttle (ATMOS), and satellite (HALOE) instruments with the aircraft data reveal an apparent pressure dependence to the HCl to Cl(y) ratio, consistent with a factor of 3-10 reduction in the photolysis rate for ClONO2 at ER-2 altitudes. However, the diurnal variation of ClO is well-simulated by models using the recommended photolysis rate, and simulations measurements of ClONO2 and HCl at mid-latitudes by ATMOS and MARKIV report HCl (HCL+ ClONO2) ratios greater than or equal to 50%. Premliminary measurements by ALIAS in the southern hemisphere report HCl/Cl(y) values of about 75%.

Webster, C. R.↗
NASA NTRS1994

Comparison of column abundances from three infrared spectrometers during AASE 2

Three Fourier transform infrared (FTIR) spectromenters were based on board the NASA DC-8 during the second Airborne Arctic Stratospheric Expedition (AASE II) in 1992. Two FTIRs used solar absorption and one used thermal emission. We compare over 2000 measurements from these 3 FTIRs, on 12 DC-8 flights, for closely coincident air masses and times, both inside and outside the polar vortex. In the majority of cases the offset biases are quite small, in the range 1-4%, and comparable to the absolute precisions expected. In most cases the rms scatter is in the range 4-11%; this scatter is unlikely to be geophysical, but rather is probably instrumental or analytical in origin.

Traub, W. A.↗
NASA NTRS1994

Latitude variations of stratospheric trace gases

We present vertical column abundances of H2O, N2O, HNO3, NO2, O3, HF, HCl, and ClNO3, determined from solar absorption spectra measured by the JPL MkIV interferometer from the NASA DC-8 aircraft. These observations, taken in 1987 and 1992, covered latitudes ranging from 85 deg S to 85 deg N. Although most gases display latitude symmetry, large asymmetries in H2O, HNO3, and O3 are apparent, which can be ascribed to processes enhanced by the colder Antarctic winter temperatures.

Toon, G. C.↗
NASA NTRS1993

Airborne observations of the composition of the 1992 tropical stratosphere by FTIR solar absorption spectrometry

Vertical column measurements of the gaseous composition of the tropical stratosphere were made from the NASA DC-8 aircraft early in 1992. As anticipated, the burdens of the stratospheric source gases (e.g., O3, HF, HCl, ClNO3, HNO3) were reduced from their mid-latitude values due to increased uplift and photolysis. The tracers revealed considerably more uplift near the equator than the sub-tropics. For example, the HF burdens at +/- 20 deg latitude were nearly double those at 5 deg N. This, together with results obtained from other long-lived gases (e.g. N2O, CH4, CF2Cl2) indicates that volume mixing ratios found at 22 km altitude at mid-latitudes occurred at 26 km in the sub-tropics and at 30 km in the equatorial zone. This zone of uplift was symmetrical about the equator even though the sun was overhead at 20 deg S.

Toon, G. C.↗
NASA NTRS1993

Post-Pinatubo optical depth spectra vs. latitude and vortex structure: Airborne tracking sunphotometer measurements in AASE 2

In January and March 1992, DC-8-measured stratospheric particle optical depth spectra, tau(sub P)(lambda), peaked broadly at midvisible or longer wavelenghts. At mid-to-high northern latitudes outside the vortex, tau(sub p)(526 nm) above about 11 km was as large as 0.22 in both January and March, reflecting continued Pinatubo volcanic influence. In both months, in-vortex tau(sub p)(lambda) above 11 km was smaller than outside-vortex values by a factor of two or more, and in January a strong anticorrelation was observed between tau(sub p)(lambda) and HF column content (an indicator of vortex penetration). In late January at 18-20S, near the edge of the southern subtropical jet, tau(sub p)(526 nm) above 12 km was only about 0.07-0.09, with a flatter spectral shape than northern mid- to high-latitude measurements in both January and March. Occasional high-latitude vertical profiles indicate 6-11-km slab optical depths, Delta tau(sub p)(526 nm), of 0.05 to 0.1, which should be added to the above-11-km values to yield values above 6 km.

Russell, P. B.↗
NASA NTRS1993

Post-Pinatubo Optical Depth Spectra VS. Latitude and Vortex Structure: Airborne Tracking Sunphotometer Measurements in AASE 2

In January and March 1992, DC-8-measured stratospheric particle optical depth spectra, (tau)(sub p)(lambda), peaked broadly at midvisible or longer wavelengths. At mid-to-high northern latitudes outside the vortex, tau(sub p)(526 microns) above about 11 km was as large as 0.22 in both January and March, reflecting continued Pinatubo volcanic influence. In both months, in-vortex tau(sub p) above 11 km was smaller than outside-vortex values by a factor of two or more, and in January a strong anticorrelation was observed between tau(sub p)(lambda) and HF column content (an indicator of vortex penetration). In late January at 18-20S, near the edge of the southern subtropical jet, tau(sub p)(526 microns) above 12 km was only about 0.07- 0.09, with a flatter spectral shape than northern mid-to high-latitude measurements in both January and March. Occasional high-latitude vertical profiles indicate 6-1 km slab optical depths, delta(tau)(sub p)(526 micron), of 0.05 to 0.1, which should be added to the above-11-km values to yield values above 6 km.

Russell, P. B.↗
NASA NTRS1993

Post-Pinatubo Optical Depth Spectra vs Latitude and Vortex Structure: Airborne Tracking Sunphotometer Measurements in AASE 2

In January and March 1992, DC-8-measured stratospheric particle optical depth spectra, tau(sub p)(lambda), peaked broadly at midvisible or longer wavelengths. At mid-to-high northern latitudes outside the vortex, tau(sub p)(526 nm) nm) above about 11 km was as large as 0.22 in both January and March, reflecting continued Pinatubo volcanic influence. In both months, in-vortex tau(sub p)(lambda) above 11 km was smaller than outside-vortex values by a factor of two or more, and in January a strong anticorrelation was observed between tau(sub p)(lambda) and HF column content (an indicator of vortex penetration). In late January at 18-20S, near the edge of the southern subtropical jet, tau(sub p)(526 nm) above 12 km was only about 0.07-0.09, with a flatter spectral shape than northern mid- to high-latitude measurements in both January and March. Occasional high-latitude vertical profiles indicate 6-11-km slab optical depths, Delta tau(sub p)(526 nm), of 0.05 to 0.1, which should be added to the above-11-km values to yield values above 6 km.

Russell, P. B.↗
NASA NTRS1993

Airborne observations of the 1992 Arctic winter stratosphere by FTIR solar absorption spectroscopy

The JPL MkIV interferometer, a Fourier Transform Infra-Red (FTIR) spectrometer designed specifically for atmospheric remote sensing, made measurements of the composition of the Arctic stratosphere in January, February and March 1992. These measurements were made from the NASA DC-8 aircraft as part of the AASE2 campaign. The data reveal that despite 5 to 6 km of subsidence inside the vortex, which more than doubled the vertically integrated column amounts (burdens) of HF and HNO3 with respect to outside the vortex, considerable losses of NO2, HCl and ClNO3 were evident by mid-January. Temporary freeze-out of HNO3 was observed only on one occasion, Jan. 19, and was accompanied by substantial reductions in HCl and ClNO3. During February and March, ClNO3 and NO2 amounts increased dramatically. HCl also recovered but at a much slower rate, so that by March ClNO3 was the major reservoir of inorganic chlorine, at times exceeding HCl by a factor 2.

Toon, G. C.↗