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Thompson, Christopher

Publications and source records attributed to Thompson, Christopher.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Standard Analytical Methods for Pyrolysis Bio-Oils

There has been significant recent interest in the production of renewable fuels and chemicals from biomass and waste feedstocks. Pyrolysis pathways produce a liquid bio-oil product, which must be processed further, or upgraded, to yield fuel or chemical products. Bio-oils are very complex and often unstable samples, and research and development on upgrading processes needs reliable analytical information. In particular, chemical characterization techniques are needed to quantify both functional groups and individual compounds present in bio-oils. Reliable analytics are also needed to enable the bioenergy industry, as industrial facilities often have different analytical needs and capabilities than research facilities. In this presentation, we will discuss the development of a suite of standard analytical methods for pyrolysis bio-oils. Analytical methods to be discussed include: Determination of Carbon, Hydrogen, Nitrogen, and Oxygen in bio-oils; Accelerated Aging of Fast Pyrolysis Bio-oil using Carbonyl Titration; Determination of Water Content in Bio-oils by Volumetric Karl Fischer Titration; Determination of Carbon Functional Groups; Elemental Analysis of Bio-oils by Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) - Na, K, Mg, Ca, S, P, and Fe; Determination of Phenolic Groups in Bio-oils using Revised Folin-Ciocalteu Methods: Single Cuvette and Plate Reader; Corrosivity of Bio-oils: Screening Test using Metal Leaching; Determination of Biogenic Content by 14C Measurement using Liquid Scintillation Counter. These new analytical methods are publicly available as Laboratory Analytical Procedures (https://www.nrel.gov/bioenergy/bio-oil-analysis.html), along with previously developed standard methods: GC-MS, Acid Titration, Carbonyl Titration, and 31P NMR. Additionally, the development of diffusion ordered NMR for characterization of bio-oil molecular weight will be discussed. Collectively, this suite of analytical methods represents the most comprehensive set of standard methods available for pyrolysis bio-oils. These standard methods are commonly used by the bioenergy community, and provide reliable information that enables research, scaleup, and industrial processing of biomass to produce renewable fuels and chemicals.

analytical↗
NASA NTRS2001

Temporal and Spectral Characteristics of Short Busts from the Soft Gamma Repeaters 1806-20 And 1900+14

We study the temporal and coarse spectral properties of 268 bursts from SGR 1806-20 and 679 bursts from SGR 1900+14, all observed with the Rossi X-Ray Timing Explorer/Proportional Counter Array. Hardness ratios and temporal parameters, such as T(sub 90) durations and tau(sub 90) emission times are determined for these bursts. We find a lognormal distribution of burst durations, ranging over more than two orders of magnitude: T(sub 90) equals approximately 10(exp -2) to > 1 s, with a peak at approximately 0.1 s. The burst light curves tend to be asymmetrical, with more than half of all events showing rise times t(sub r) < 0.3 T(sub 90). We find that there exists a correlation between the duration and fluence of bursts from both sources. We also find a significant anticorrelation between hardness ratio and fluence for SGR 1806-20 bursts and a marginal anticorrelation for SGR 1900+14 events. Finally, we discuss possible physical implications of these results within the framework of the magnetar model.

Goegues, Ersin↗
NASA NTRS2001

Evidence for a Sudden Magnetic Field Reconfiguration in Soft Gamma Repeater 1900+14

We report the detection of large flux changes in the persistent X-ray flux of soft gamma repeater (SGR) 1900 + 14 during its burst active episode in 1998. Most notably, we find a factor of approx. 700 increase in the nonburst X-ray flux following the August 27 flare, which decayed in time as a power law. Our measurements indicate that the pulse fraction remains constant throughout this decay. This suggests a global flux enhancement as a consequence of the August 27 flare rather than localized heating. While the persistent flux has since recovered to the preoutburst level, the pulse profile has not. The pulse shape changed to a near sinusoidal profile within the tail of the August 27 flare (in gamma-rays), and this effect has persisted for more than 1.5 years (in X-rays). The results presented here suggest that the magnetic field of the neutron star in SGR 1900 + 14 was significantly altered (perhaps globally) during the giant flare of August 27.

Woods, Peter M.↗
NASA NTRS2001

Temporal Characteristics of SGR 1806-20 and SGR 1900+14 Bursts

We study the temporal properties of 268 bursts from SGR 1806$-$20 and 679 bursts from SGR 1900+14 all observed with the Rossi X-Ray Timing Explorer/Proportional Counter Array. Temporal parameters, such as T$_{90}$ durations and $\tau$$_{90}$ emission times are implemented. We find a lognormal distribution of burst durations, ranging over more than two orders of magnitude: T$_{90}$ $\sims$ 10$ {-2}$ to $\gtrsim$ 1 s, with a peak $\sim$ 0.1 s. The burst light curves tend to be asymmetrical, with more than half of all events showing rise times t$_{r}$ $<$ 0.2 T$_{90}$. We find that there exists a correlation between the duration and fluence of bursts from both sources. We also find a significant anti-correlation between hardness ratio and fluence of SGR bursts. Finally we discuss possible physical implications of these results within the framework of the magnetar theory.

Gogus, Ersin↗
NASA NTRS2000

Statistical Properties of SGR 1806-20 Bursts

We present statistics of SGR 1806-20 bursts, combining 290 events detected with the Rossi X-Ray Timing Explorer/Proportional Counter Array, 111 events detected with the Burst and Transient Source Experiment, and 134 events detected with the International Cometary, Explorer. We find that the fluence distribution of bursts observed with each instrument are well described by power laws with indices 1.43, 1.76, and 1.67, respectively. The distribution of time intervals between successive bursts from SGR 1806-20 is described by a lognormal function with a peak at 103 s. There is no correlation between the burst intensity and either the waiting times until the next burst or the time elapsed since the previous burst. In all these statistical properties, SGR 1806-20 bursts resemble a self-organized critical system, similar to earthquakes and solar flares. Our results thus support the hypothesis that the energy source for soft gamma repeater bursts is crustquakes due to the evolving, strong magnetic field of the neutron star, rather than any accretion or nuclear power.

Gogus, Ersin↗
NASA NTRS2000

Timing Noise in SGR 1806-20

We have phase connected a sequence of Rossi X-ray Timing Explorer Proportional Counter Array observations of SGR 1806-20 covering 178 days. We find a simple secular spin-down model does not adequately fit the data. The period derivative varies gradually during the observations between 8.1 and 11.7 x 10(exp -11) s/s (approx. 40% larger than the long term trend), while the average burst rate as seen with the Burst and Transient Source Experiment drops throughout the time interval. The phase residuals show no evidence for periodicity, but more closely resemble timing noise as seen ill radio pulsars. The magnitude of the timing noise., however, is large relative to the noise level typically found in radio pulsars (Delta(sub 8) = 4.8; frequency derivative average power approx. = 8 X 10(exp -20) Hz/sq s). Combined with the noise levels measured for some AXPs. we find all magnetar candidates have A8 values larger than those expected from a simple extrapolation of the correlation found in radio pulsars. We find the timing noise ill SGR 1806-20 is greater than or equal to the levels found in some accreting systems (e.g., Vela X-1, 4U 1538-52 and 4U 1626-67). Alternatively, an orbital model with a period P(sub orb) = 733 days provides a statistically acceptable fit to the data. If the phase residuals are created by Doppler shifts from a gravitationally bound companion. then the allowed parameter space for the mass function (small) and orbital separation (large) rule out the possibility of accretion from the companion sufficient to power the persistent emission from the SGR.

Woods, Peter M.↗
NASA NTRS2000

Evidence for a Sudden Magnetic Field Reconfiguration in SGR 1900+14

We report on the detection of large flux changes in the persistent X-ray flux of SGR 1900+14 during its burst active episode in 1998. Most notably, we find a factor of approximately 700 increase in the non-burst X-ray flux following the August 27th flare that decayed in time as a power-law. Throughout the decay of this flux enhancement, our measurements indicate that the pulse fraction remains constant. This indicates a global flux enhancement as a consequence of the August 27th flare rather than localized heating. While the persistent flux has since recovered to the pre-outburst level, the pulse profile has not. The pulse shape changed to a near sinusoidal profile within the tail of the August 27th flare (in gamma-rays) and this effect has persisted for more than 1.5 years (in X-rays). The results presented here suggest the magnetic field of the neutron star in SGR 1900+14 was significantly altered (perhaps globally) during the giant flare of August 27.

Woods, Peter M.↗
NASA NTRS1999

Hard Burst Emission from the Soft Gamma Repeater SGR 1900+14

We present evidence for burst emission from SGR 1900 + 14 with a power-law high-energy spectrum extending beyond 500 keV. Unlike previous detections of high-energy photons during bursts from soft gamma repeaters (SGRs), these emissions are not associated with extraordinarily bright flares. Not only is the emission hard, but the spectra are better fitted by D. Band's gamma-ray burst (GRB) function rather than by the traditional optically thin thermal bremsstrahlung model. We find that the spectral evolution within these hard events obeys a hardness/intensity anticorrelation. Temporally, these events are distinct from typical SGR burst emissions in that they are longer (approximately 1 s) and have relatively smooth profiles. Despite a difference in peak luminosity of approximately > 10(exp 11) between these bursts from SGR 1900 + 14 and cosmological GRBs, there are striking temporal and spectral similarities between the two kinds of bursts, aside from spectral evolution. We outline an interpretation of these events in the context of the magnetar model.

Woods, Peter M.↗
NASA NTRS1999

Variable Spin-Down in the Soft Gamma Repeater SGR 1900+14 and Correlations with Burst Activity

We have analyzed Rossi X-ray Timing Explorer Proportional Counter Array observations of the pulsed emission from SGR 1900+ 14 during 1996 September, 1998 June-October, and early 1999. Using these measurements and results reported elsewhere, we construct a period history of this source for 2.5 yr. We find significant deviations from a steady spin-down trend during quiescence and the burst active interval. Burst and Transient Source Experiment observations of the burst emission are presented and correlations between the burst activity and spin-down rate of SGR 1900+14 are discussed. We find an 80 day interval during the summer of 1998 when the average spin-down rate is larger than the rate elsewhere by a factor approximately 2.3. This enhanced spin-down may be the result of a discontinuous spin-down event or "braking glitch" at the time of the giant flare on 1998 August 27. Furthermore, we find a large discrepancy between the pulsar period and average spin-down rate in X-rays as compared to radio observations for 1998 December and 1999 January.

Woods, Peter M.↗
NASA NTRS1999

Discovery of a Magnetar Associated with the Soft Gamma Repeater SGR 1900 + 14

The soft-gamma repeater (SGR) 1900 + 14 became active again on June 1998 after a long period of quiescence; it remained at a low state of activity until August 1998, when it emitted a series of extraordinarily intense outbursts. We have observed the source with RXTE twice, during the onset of each active episode. We confirm the pulsations at the 5.16 s period reported earlier from SCR 1900 + 14 . Here we report the detection of a secular spindown of the pulse period at an average rate of 1.1 x 10(exp -10) s/s. In view of the strong similarities between SGRs, we attribute the spindown of SGR 1900 + 14 to magnetic dipole radiation, possibly accelerated by a quiescent flux, as in the case of SGR 1806 - 20. This allows an estimate of the pulsar dipolar magnetic field, which is 2 - 8 x 10(exp 14) G. Our results confirm that SGRs are magnetars.

Kouveliotou, Chryssa↗
NASA NTRS1999

BeppoSAX Observations of the SGR 1900+14 in Quiescence and During an Active Period

We present results from two Beppo SAX Narrow Field Instrument (NFI) observations of SGR-1900+14 made during a quiescent and an active period of the source. We detect pulsations in the 1997 May 12-13 observation (quiescence) at 5.157190(7) sec and the 1998 September 15-16 observation (active period) at 5.16026](12) sec. Using results reported by Hurley et al. (1999a), we establish a long-term spin down rate during quiescence of 5.82(2)-approx. times 10(exp -11) s/s which implies a dipole magnetic field of sim 5.5 approx. times 10(exp 14) G. We confirm deviations from a constant spin down rate during the active period. We also find spectral similarities between SGR-1900+14 in quiescence and anomalous X-ray pulsars (AXPs).

Woods, Peter↗
NASA NTRS1999

Statistical Properties of SGR 1900+14 Bursts

We study the statistics of soft gamma repeater (SGR) bursts, using a data base of 187 events detected with BATSE and 837 events detected with RXTE PCA, all from SGR 1900+14 during its 1998-1999 active phase. we find that the fluence or energy distribution of bursts is consistent with a power law of index 1.66, over 4 orders of magnitude. This scale-free distribution resembles the Gutenberg-Richter Law for earthquakes, and gives evidence for self-organized criticality in SGRS. The distribution of time intervals between successive bursts from SGR 1900+14 is consistent with a log-normal distribution. There is no correlation between burst intensity and the waiting times till the next burst, but there is some evidence for a correlation between burst intensity and the time elapsed since the previous burst. We also find a correlation between the duration and the energy of the bursts, but with significant scatter. In all these statistical properties, SGR bursts resemble earthquakes and solar flares more closely than they resemble any known accretion-powered or nuclear-powered phenomena. Thus our analysis lends support to the hypothesis that the energy source for SGR bursts is internal to the neutron star, and plausibly magnetic.

Gogus, Ersin↗
NASA NTRS1999

Hard Burst Emission from the Soft Gamma Repeater SGR 1900+14

We present evidence for burst emission from SGR 1900+14 with a power-law high energy spectrum extending beyond 500 kev. Unlike previous detections of high energy photons during bursts from SGRS, these emissions are not associated with high-luminosity burst intervals. Not only is the emission hard, but the spectra are better fit by Band's GRB function rather than by the traditional optically-thin thermal bremsstrahlung model. We find that the spectral evolution within these hard events obeys a hardness/intensity anti-correlation. Temporally, these events are distinct from typical SGR burst emissions in that they are longer (about 1 s) and have relatively smooth profiles. Despite a difference in peak luminosity of > 1E+ll between these bursts from SGR 1900+14 and cosmological GRBS, there are striking temporal and spectral similarities between the two kinds of bursts, aside from spectral evolution. We outline an interpretation of these events in the context of the magnetar model.

Duncan, Robert D.↗
NASA NTRS1999

On the Variable Spin-Down of SGR 1900+14

We consider the physical implications of the rapid spindown of Soft Gamma Repeater 1900+14 reported in a companion paper by Woods et al. During an 80 day interval between June 1998 and the large outburst on August 27, 1998, the mean spin-down rate increased by a factor 2.3 resulting in a positive period offset of delta P/P = 1 X 10(exp -4)/ A radiation hydrodynamical outflow associated with the August 27 event could impart the required torque, but only if the dipole magnetic field is stronger than about 10(exp 14) G and the outflow lasts longer than the observed X-ray flare. A positive period increment is also a natural consequence of a gradual plastic deformation of the neutron star crust by an intense magnetic field. Finally, we discuss the relative stability of the long term spin-down rate of SGR 1900+14, and compare the relative spindown rates of the SGRs and the Anomalous X-ray Pulsars.

Thompson, Christopher↗