Engineering Papers⌕ Search

Engineering topics

Thomas, Kathie L.

Publications and source records attributed to Thomas, Kathie L..

Electron energy-loss spectroscopy of carbon in interplanetary dust particles

The nature of the carbon-bearing phases in IDP's provides information regarding the chemical and physical processes involved in the formation and evolution of the early solar system. Several carbon-bearing materials have been observed in IDP's, but details of their nature, abundance, and distribution are still poorly known. A knowledge of the abundance and nature of carbon in IDP's is useful in constraining the sources of IDP's and for comparisons with other chondritic materials. Estimates of carbon abundance in anhydrous and hydrated IDP's indicate that most of these particles have significantly higher carbon than the carbonaceous chondrites. Mineralogical analyses show that carbonates are only a minor component of most hydrated IDP's, and so the high carbon abundances in this group of IDP's indicates that other carbon-bearing phases are present in significant concentrations. Using the technique of electron energy-loss spectroscopy (EELS), we have identified two forms of carbon in a hydrated IDP, oxidized carbon (carbonates), and amorphous elemental carbon.

Keller, Lindsay P.↗

Carbon in primitive interplanetary dust particles

Currently, one of the best sources of information regarding the nature and formation of carbonaceous materials in the early solar system comes from studies of primitive interplanetary dust particles (IDP's). Carbon is a significant component of most IDP's, and the nature of the C-rich phases bears on the chemical and physical processes that have affected C from its nucleosynthesis to its incorporation into primitive solar system bodies. We review the data regarding C in IDP's since approximately 1987. Brownlee summarized the state of C in IDP's in a workshop help at ARC in 1987; other recent reviews have summarized the formation mechanisms that have been proposed for carbonaceous materials in primitive solar system materials. We discuss the abundance of C in IDP's, the nature and distribution of C, and topics and strategies for future work.

Keller, Lindsay P.↗

Quantitative analyses of carbon in anhydrous and hydrated interplanetary dust particles

Carbon is an important and significant component of most anhydrous and hydrated IDP's. We have analyzed approx. 40 anhydrous and hydrated chondritic IDP's for major and minor elements, including C and O. Quantitative analyses of light elements in small particles are difficult and require careful procedures in order to obtain reliable results. In our work, we have completed extensive analytical checks to verify the accuracy and precision of C abundances in IDP's. In our present work, additional methods are used to verify C abundances in IDP's including analysis of IDP thin sections embedded in S, and direct observation of carbonaceous material in thin sections. Our work shows conclusively that C is strongly enriched in IDP's relative to CI abundances.

Thomas, Kathie L.↗

Carbon abundance and silicate mineralogy of anhydrous interplanetary dust particles

We have studied nineteen anhydrous chondritic interplanetary dust particles (IDPs) using analytical electron microscopy. We have determined a method for quantitative light element EDX analysis of small particles and have applied these techniques to a group of IDPs. Our results show that some IDPs have significantly higher bulk carbon abundances than do carbonaceous chondrites. We have also identified a relationship between carbon abundance and silicate mineralogy in our set of anhydrous IDPs. In general, these particles are dominated by pyroxene, olivine, or a subequal mixture of olivine and pyroxene. The pyroxene-dominated IDPs have a higher carbon abundance than those dominated by olivines. Members of the mixed mineralogy IDPs can be grouped with either the pyroxene- or olivine-dominated particles based on their carbon abundance. The high carbon, pyroxene-dominated particles have primitive mineralogies and bulk compositions which show strong similarities to cometary dust particles. We believe that the lower carbon, olivine-dominated IDPs are probably derived from asteroids. Based on carbon abundances, the mixed-mineralogy group represents particles derived from either comets or asteroids. We believe that the high carbon, pyroxene-rich anhydrous IDPs are the best candidates for cometary dust.

Thomas, Kathie L.↗

An interplanetary dust particle with links to CI chondrites

W7013F5 is a chondritic, hydrated interplanetary dust particle whose composition and mineralogy is nearly identical to that found in the CI chondrites. Transmission electron microscope observations show that the phyllosilicates in W7013F5 consist largely of a coherent undergrowth of Mg-Fe serpentine and Fe-bearing saponite on the unitcell scale. This distinctive intergrowth of phyllosilicates has only been observed previously in the CI chondrites. Other secondary minerals in W7013F5 include Mg-Fe carbonates, magnetite, and pentlandite. The mineral assemblage in W7013F5 is generally not as oxidized as that in the CI chondrites. The presence of kamacite in W7013F5 indicates that the particle is extraterrestrial, and a thin amorphous rim surrounding the particle provides evidence that it is not a piece of a meteorite that fragmented during transit through the atmosphere. The apparent lack of hydrated IDPs with CI mineralogy and chemistry may indicate that CI-type dust-producing asteroids are uncommon in the asteroid belt.

Keller, Lindsay P.↗

Transmission electron microscopy of an interplanetary dust particle with links to CI chondrites

The majority of hydrated interplanetary dust particles (IDPs) have compositions that resemble CI and CM chondrites, however, their mineralogies are most similar to the fine grained material in certain altered type-3 carbonaceous and ordinary chondrites. During the transmission electron microscope studies of hydrated IDPs, a unique particle was discovered whose mineralogy is very similar to that reported from CI chondrites. W7013F5 is the first IDP whose mineralogy and chemistry approximates that of CI chondrites. The similarity in mineralogy and mineral chemistry suggests that W7013F5 was altered under conditions similar to those that existed on the CI parent bodies.

Keller, Lindsay P.↗