Isotopic Effect on Electrochemical CO2 Reduction Activity and Selectivity in H2O- and D2O-based Electrolytes over Palladium
Explore the source record for details and available documents.
99 GENERAL AND MISCELLANEOUS↗
Engineering topics
Tackett, Brian M.
Publications and source records attributed to Tackett, Brian M..
Prussian blue analogues as platform materials for understanding and developing oxygen evolution reaction electrocatalysts
Transition metal based materials containing Fe have drawn great attention as oxygen evolution reaction (OER) catalysts. The nature of the electrocatalytic active species remains under debate due to the ambiguous physicochemical properties of the catalyst materials, such as the oxidation states and crystal structures. Here, in order to address this issue, transition metal Prussian blue analogues (TM-PBA, Na(TM)(Fe)(CN) 6 , TM = V, Fe, Co, and Ni) with an isomorphous structure are investigated for OER catalysis. Our combined experimental measurements and density functional theory (DFT) calculations reveal that TM-PBAs exhibit volcano-like OER activity with Ni-PBA located near the top of the volcano. Such a volcano-like activity profile can be attributed to the distinctive binding energy difference between *O and *OH on different TM-PBAs surfaces. This research demonstrates that TM-PBAs can be used as platform materials for understanding structure-property-activity relationships in OER catalysts.
25 ENERGY STORAGE↗
Exploring electrocatalytic stability and activity of unmodified and platinum-modified tungsten and niobium nitrides
Not Available
Denny, Steven R.↗