Engineering Papers⌕ Search

Engineering topics

Sun, C.

Publications and source records attributed to Sun, C..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Preliminary Study of JPSS-1/NOAA-20 VIIRS Day-Night Band Straylight Characterization and Correction Methods

The JPSS-1 (now named NOAA-20) VIIRS instrument has successfully operated since its launch in November 18, 2017. A panchromatic channel onboard NOAA-20 VIIRS is called the day-night band (DNB). With its large dynamic range and high sensitivity, the DNB detectors can make observations during both daytime and nighttime. However, the DNB night image quality is affected by the straylight contamination. In this study, we focused on Earth view data in the midto-high latitude of the northern and southern hemispheres when spacecraft is crossing the day/night terminators at the beginning of NOAA-20 mission. Based on on-orbit data analysis from previous VIIRS sensor onboard S-NPP mission, straylight contamination mainly depends on the Earth-Sun-spacecraft geometry, and it is also detector and scan-angle dependent. Inter-comparison investigation of straylight behavior in both SNPP and NOAA-20 instruments will be conducted to better understand straylight characteristics. The preliminary study has been performed in this paper to mitigate straylight contamination for NOAA-20VIIRS DNB night images. The effectiveness of the straylight correction algorithm, directly adapted from the S-NPP DNB, is assessed for night images in the day/night terminators. Further work has been identified to improve current straylight correction methodology and DNB-based environmental data products.NOAA-20.

Day-Night Band↗
NASA NTRS2018

An Early Assessment of JPSS-1/NOAA-20 VIIRS Day-Night Band On-Orbit Calibration and Performance

The JPSS-1 (now named NOAA-20) VIIRS instrument has been successfully operating on orbit since November 28th, 2017. The Day-Night Band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 m that is capable of observing the Earth scene in visible/near-Infrared spectral range at spatial resolution of 750 m. The DNB operates at low, mid, or high radiometric gain stages, and it uses an onboard solar diffuser (SD) panel for low gain stage calibration. The SD observations also provide a mean to compute gain ratios between low-to-mid and mid-to-high gain stages. With their large dynamic range and high sensitivity, the DNB detectors can make observations during both daytime and nighttime. This paper provides an early assessment of the DNB on-orbit performance and behavior in the first 90-day post launch test (PLT) period and beyond. The calibration methodology used by the VIIRS Characterization Support Team (VCST) in support of the NASA earth science community will be presented. The trending of OBC dark-offsets, SD gains and gain ratios, and signal-to-noise ratio (SNR) at minimum radiance have been analyzed, especially during key events such as the Nadir and Cryo-cooler doors opening. Furthermore, we performed inter-comparison studies between SNPP and JPSS-1 instruments and evaluated DNB radiometric calibration and characterization, including the SD degradation, detector gains and gain ratios, as well as the calibration comparison between the IDPS LUTs and our VCST delivery results.

Chen, H.↗
DOE OSTI2017

The Role of Anisotropy on the Self-Organization of Gas Bubble Superlattice

Self-organization of nanoscale void/gas bubble superlattices has been widely observed in irradiation experiments however yet to be well understood. The recent discovery of incoherent face-centered-cubic (fcc) Xe bubble lattice in body-centered-cubic (bcc) UMo challenges the widely accepted coherency between superlattices and matrices. A complete mechanistic understanding of bubble lattice self-organization may have a large impact to materials science and nuclear energy advancement, and is the objective of this project. The knowledge obtained through a coherent integration of experimental and computational approach will advance the current understanding of self-organization mechanisms of nanostructures under irradiation. To realize this goal, two appealing self-organization mechanisms previously proposed in open literatures have been identified: anisotropic elastic interaction between voids and kinetic anisotropy such as one-dimensional (1D) self-interstitial atoms (SIA) diffusion. For the first year, the focus is on the effect 1D diffusion using bcc Mo and W, with the former being elastically anisotropic while the latter isotropic. Efforts have been made to investigate the fundamental interaction between inert gas and metal matrices, the mechanism for void/bubble superlattice formation and their stabilities under irradiation and annealing, and the experimental conditions for bubble superlattice formation and evolution, and to establish advanced characterization techniques for bubble superlattice.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Effect of tube processing methods on microstructure, mechanical properties and irradiation response of 14YWT nanostructured ferritic alloys

In this research, innovative thermal spray deposition (Process I) and conventional hot extrusion processing (Process II) methods have been used to produce thin walled tubing (~0.5 mm wall thickness) out of 14YWT, a nanostructured ferritic alloy. The effects of processing methods on the microstructure, mechanical properties and irradiation response have been investigated by using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and, micro- and nano-hardness techniques. It has been found that these two processes have a significant effect on the microstructure and mechanical properties of the as-fabricated 14YWT tubes. Even though both processing methods yield the formation of various size Y-Ti-O particles, the conventional hot extrusion method results in a microstructure with smaller, homogenously distributed nano-oxides (NOs, Y-Ti-O particles < 5 nm) with higher density. Therefore, Process II tubes exhibit twice the hardness of Process I tubes. It has also been found that these two tremendously different initial microstructures strongly affect irradiation response in these tubes under extremely high dose ion irradiations up to 1100 peak dpa at 450 °C. The finer, denser and homogenously distributed NOs in the Process II tube result in a reduction in swelling by two orders of magnitude. On the other hand, inhomogeneity of the initial microstructure in the Process I tube leads to large variations in both swelling and irradiation induced hardening. Moreover, hardening mechanisms before and after irradiation were measured and compared with detailed calculations. In conclusion, this study clearly indicates the crucial effect of initial microstructure on radiation response of 14YWT alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Influence of injected interstitials on the void swelling in two structural variants of 304L stainless steel induced by self-ion irradiation at 500 °C

The two variants of AISI 304L stainless steel (SS) with different grain size distributions were ion irradiated at 500 °C to a peak dose of ~60 dpa. In the coarse-grained annealed variant, a peak swelling of ~12% was observed closer to the specimen surface rather than at the depth of peak displacement damage. The forward shift in depth between peak swelling and peak dose is proposed to be a consequence of suppression of void nucleation by injected interstitials. The swelling behavior in the front portion of the ion range mirrors that of neutron-induced swelling in this steel, exhibiting significant curvature with increasing dose as the swelling rate approaches the terminal swelling rate of 1%/dpa. Furthermore, an ultrafine grain variant of this steel produced by severely plastic deformation exhibits a similar suppression of void nucleation in the injected interstitial region, but also shows a significantly extended transient regime, not reaching the terminal swelling rate by 60 dpa.

304 stainless steel↗
NASA NTRS2016

On-Orbit Calibration and Performance of S-NPP VIIRS DNB

The S-NPP VIIRS instrument has successfully operated since its launch in October 2011. The VIIRS Day-Night Band (DNB) is a panchromatic channel covering wavelengths from 0.5 to 0.9 m that is capable of observing Earth scenes during both day and nighttime orbits at a spatial resolution of 750 m. To cover the large dynamic range, the DNB operates at low, mid, or high gain stages, and it uses an onboard solar diffuser (SD) for its low gain stage calibration. The SD observations also provide a means to compute gain ratios of low-to-mid and mid-to-high gain stages. This paper describes the DNB on-orbit calibration methodologies used by the VIIRS Characterization Support Team (VCST) in supporting the NASA earth science community with consistent VIIRS sensor data records (SDRs) made available by the Land Science Investigator-led Processing Systems (SIPS). It provides an assessment and update of DNB on-orbit performance, including the SD degradation in the DNB spectral range, detector gain and gain ratio trending, stray light contamination and its correction. Also presented in this paper are performance validations based on earth scenes and lunar observations.

Chen, H.↗
DOE OSTI2016

Temperature dependence of the radiation tolerance of nanocrystalline pyrochlores A 2 Ti 2 O 7 (A = Gd, Ho and Lu)

A potentially enhanced radiation resistance of nanocrystalline materials, as a consequence of the high density of interfaces and surfaces, has attracted much attention both to understand the fundamental role of these defect sinks and to develop them for high-radiation environments. Here, irradiation response of nanocrystalline A 2 Ti 2 O 7 (A = Gd, Ho and Lu) pyrochlore powders with grain sizes of 20–30 nm was investigated by 1-MeV Kr 2+ ion bombardment. In situ transmission electron microscopy (TEM) revealed that the critical amorphization fluence for each nanocrystalline compound at room temperature was greater than that for their coarse-grained counterparts, indicating an enhanced amorphization resistance. The effect of temperature on the irradiation response of one of these compounds, nanocrystalline Lu 2 Ti 2 O 7 , was further examined by performing ion irradiation at an elevated temperature range of 480–600 K. The critical amorphization temperature (T c ) was found to be noticeably higher in nanocrystalline Lu 2 Ti 2 O 7 (610 K) than its coarse-grained counterpart (480 K), revealing that nanocrystalline Lu 2 Ti 2 O 7 is less resistant to amorphization compared to its coarse-grained phase under high temperatures. We interpret these results with the aid of atomistic simulations. Molecular statics calculations find that cation antisite defects are less energetically costly to form near surfaces than in the bulk, suggesting that the nanocrystalline form of these materials is generally less susceptible to amorphization than coarse-grained counterparts at low temperatures where defect kinetics are negligible. In contrast, at high temperatures, the annealing efficiency of antisite defects by cation interstitials is significantly reduced due to the sink properties of the surfaces in the nanocrystalline pyrochlore, which contributes to the observed higher amorphization temperature in the nano-grained phase than in coarse-grained counterpart. Altogether, these results provide new insight into the behavior of nanocrystalline materials under irradiation.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Microstructure chemistry and mechanical properties of Ni-based superalloy Rene N4 under irradiation at room temperature

Nickel superalloys with cubic L12 structured γ' (Ni 3 (Al, Ti)) precipitates exhibit high strength at high temperatures and excellent corrosion resistance when exposed to water. Unlike prior studies on irradiation damage of other Ni-based superalloys, our study on Rene N4 involves much larger γ' precipitates, ~450 nm in size, a size regime where the irradiation-induced disordering and dissolution kinetics and the corresponding mechanical property evolution are unknown. Under heavy ion irradiation at room temperature, the submicron-sized γ' precipitates were fully disordered at ~0.3 dpa and only later partially dissolved after 75 dpa irradiation. Nanoindentation experiments indicate that the mechanical properties of the alloy change significantly, with a dramatic decrease in hardness, with irradiation dose. Three contributions to the change in hardness were examined: defect clusters, disordering and dissolution. Moreover, the generation of defect clusters in the matrix and precipitates slightly increased the indentation hardness, while disordering of the submicron-sized γ' precipitates resulted in a dramatic decrease in the total hardness, which decreased further during the early stages of the intermixing between γ' precipitates and matrix (<18 dpa). As a result, controlling the long-range-ordering and chemical intermixing can be used to tailor the mechanical properties of Ni-based superalloys under irradiation.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Thermally Induced Interdiffusion and Precipitation in a Ni/Ni 3 Al System

Ordered Ni 3 Al intermetallic precipitates constitute the main hardening sources of Ni-based superalloys. Here, we report the interdiffusion and precipitation behavior in a Ni/Ni3Al model system. The deposition of Ni3Al on a pure Ni layer at 500°C generated L12-structured γ' (Ni3Al) precipitates, preferentially at the interface. After annealing at 800°C for 1 h, interdiffusion between Ni and Ni3Al layers occurred, and the γ' precipitates that grew near the parent Ni/Ni 3 Al interface are ~2.8 times larger in size than those formed in the matrix. In conclusion, Monte Carlo simulations indicate that vacancies preferentially diffuse along the Ni/Ni 3 Al interface, increasing the probability of precipitation.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Structural and magnetic properties of nickel antimony ferrospinels

Spinel-type compounds of Fe–Ni–Sb–O system were synthesized as polycrystalline powders. The crystal and magnetic properties were investigated using X-ray and neutron powder diffraction, Mössbauer and X-ray absorption spectroscopy and magnetization measurements. The samples crystallize in the cubic system, space group Fd – 3 m. The distribution of cations between octahedral and tetrahedral sites was refined from the diffraction data sets using constraints imposed by the magnetic, Mössbauer and EDS results and the ionic radii. The cation distribution and the temperature dependence of the lattice parameter (a) and the oxygen positional parameter (u) were obtained. A chemical formula close to Fe0.8Ni1.8Sb0.4O4 was determined, with Sb5+ cations occupying octahedral sites, and Fe3+ and Ni2+ occupying both tetrahedral and octahedral sites. Fe3+ mainly (85/15 ratio) occupy tetrahedral sites, and conversely Ni2+ mainly reside on octahedral ones. The magnetic unit cell is the same as the crystallographic one, having identical symmetry relations. The results indicate that the compounds have a collinear ferrimagnetic structure with antiferromagnetic coupling between the tetrahedral (A) and octahedral (B) sites. Uniquely, the temperature dependence of the net magnetization of this rare earth free ferrimagnet exhibits a compensation point.

Crystal structure↗
DOE OSTI2015

X-rays only when you want them: Optimized pump–probe experiments using pseudo-single-bunch operation

Laser pump–X-ray probe experiments require control over the X-ray pulse pattern and timing. Here, the first use of pseudo-single-bunch mode at the Advanced Light Source in picosecond time-resolved X-ray absorption experiments on solutions and solids is reported. In this mode the X-ray repetition rate is fully adjustable from single shot to 500 kHz, allowing it to be matched to typical laser excitation pulse rates. Suppressing undesired X-ray pulses considerably reduces detector noise and improves signal to noise in time-resolved experiments. In addition, dose-induced sample damage is considerably reduced, easing experimental setup and allowing the investigation of less robust samples. Single-shot X-ray exposures of a streak camera detector using a conventional non-gated charge-coupled device (CCD) camera are also demonstrated.

43 PARTICLE ACCELERATORS↗
DOE OSTI2015

Superior radiation-resistant nanoengineered austenitic 304L stainless steel for applications in extreme radiation environments

Nuclear energy provides more than 10% of electrical power internationally, and the increasing engagement of nuclear energy is essential to meet the rapid worldwide increase in energy demand. A paramount challenge in the development of advanced nuclear reactors is the discovery of advanced structural materials that can endure extreme environments, such as severe neutron irradiation damage at high temperatures. It has been known for decades that high dose radiation can introduce significant void swelling accompanied by precipitation in austenitic stainless steel (SS). Here we report, however, that through nanoengineering, ultra-fine grained (UFG) 304L SS with an average grain size of ~100 nm, can withstand Fe ion irradiation at 500°C to 80 displacements-per-atom (dpa) with moderate grain coarsening. Compared to coarse grained (CG) counterparts, swelling resistance of UFG SS is improved by nearly an order of magnitude and swelling rate is reduced by a factor of 5. M₂₃C₆ precipitates, abundant in irradiated CG SS, are largely absent in UFG SS. This study provides a nanoengineering approach to design and discover radiation tolerant metallic materials for applications in extreme radiation environments.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Electrochemical cells for medium- and large-scale energy storage

This is one of the chapters in the book titled “Advances in batteries for large- and medium-scale energy storage: Applications in power systems and electric vehicles” that will be published by the Woodhead Publishing Limited. The chapter discusses the basic electrochemical fundamentals of electrochemical energy storage devices with a focus on the rechargeable batteries. Several practical secondary battery systems are also discussed as examples

Wang, Wei↗