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Strahan, S. E.

Publications and source records attributed to Strahan, S. E..

At least 37 records · Page 2

Effects of Pinatubo aerosol on stratospheric ozone at mid-latitudes

Mid-latitude ozone data from ER-2 aircraft measurements in 1989, 1991, and 1992 were examined to determine how sulfate aerosols from the eruption of Mt. Pinatubo had affected ozone at about 18 km. N2O was used as a tracer to help distinguish between chemical and dynamical aerosol effects. At 20-45 deg N in February 1992, ozone was about 10-20% lower than February 1989 and 1991, with respect to N2O. Data from Aug. 1991 - Mar. 1992 showed changes in ozone with respect to N2O, but the magnitude of those changes was not correlated with the magnitude of the changes in aerosol surface area density.

Weaver, A.↗

New observations of the NOy/N2O correlation in the lower stratosphere

During the Airborne Arctic Stratospheric Expedition 2 (AASE 2), September 1991 through March 1992, in situ measurements of reactive nitrogen (NO(y) and N20 were made in the Northern Hemisphere lower stratosphere. We present an analysis of this new data and compare it with results from similar data taken during AASE in the winter of 1989. In the Northern Hemisphere there is consistent linear correlation of N2O and NO(y) which shows no interannual variation. Cases of departure from a linear correlation are examined and classified as being due to denitrification (NO(y) loss) or sampling air from a region where the photochemical lifetime of NO(y) is decreased. The latter case was observed for the first time in the winter of 1992.

Loewenstein, M.↗

Effects of Pinatubo Aerosol on Stratospheric Zone at Mid-Lattiudes

Mid-latitude ozone data from ER-2 aircraft measurements in 1989, 1991 and 1992 were examined to determine how sulfate aerosols from the eruption of Mt. Pinatubo had affected ozone at about 18 km. N2O was used as a tracer to help distinguish between chemical and dynamical aerosol effects. At 20-45 deg N in February 1992, ozone was about 10-20% lower than February 1989 and 1991, with respect to N2O. Data from Aug.1991 - Mar. 1992 showed changes in ozone with respect to N2O, but the magnitude of those changes was not correlated with the magnitude of the changes in aerosol surface area density.

Weaver, A.↗

New Observations of the NO(y)/N2O Correlation in the lower Stratosphere

During the Airborne Arctic Stratospheric Expedition II (AASE II), September 1991 through March 1992, in situ measurements of reactive nitrogen (NO(y)) and N2O were made in the Northern Hemisphere lower stratosphere. We present an analysis of this new data and compare it with results from similar data taken during AASE in the winter of 1989. In the Northern Hemisphere there is a consistent linear correlation of N2O and NO(y) which shows no interannual variation. Cases of departure from a linear correlation are examined and classified as being due to denitrification (NO(y) loss) or sampling air from a region where the photochemical lifetime of NO(y) is decreased. The latter case was observed for the first time in the winter of 1992.

Lowenstein, M.↗

Chemical loss of ozone in the Arctic polar vortex in the winter of 1991- 1992

In situ measurements of chlorine monoxide, bromine monoxide, and ozone are extrapolated globally, with the use of meteorological tracers, to infer the loss rates for ozone in the Arctic lower stratosphere during the Airborne Arctic Stratospheric Expedition II (AASE II) in the winter of 1991-1992. The analysis indicates removal of 15 to 20 percent of ambient ozone because of elevated concentrations of chlorine monoxide and bromine monoxide. Observations during AASE II define rates of removal of chlorine monoxide attributable to reaction with nitrogen dioxide (produced by photolysis of nitric acid) and to production of hydrochloric acid. Ozone loss ceased in March as concentrations of chlorine monoxide declined. Ozone losses could approach 50 percent if regeneration of nitrogen dioxide were inhibited by irreversible removal of nitrogen oxides (denitrification), as presently observed in the Antarctic, or without denitrification if inorganic chlorine concentrations were to double.

Salawitch, R. J.↗

Chemical Loss of Ozone in the Arctic Polar Vortex in the Winter of 1991-1992

In situ measurements of chlorine monoxide, bromine monoxide, and ozone are extrapolated globally, with the use of meteorological tracers, to infer the loss rates for ozone in the Arctic lower stratosphere during the Airborne Arctic Stratospheric Expedition II (AASE II) in the winter of 1991-1992. The analysis indicates removal of 15 to 20 percent of ambient ozone because of elevated concentrations of chlorine monoxide and bromine monoxide. Observations during AASE II define rates of removal of chlorine monoxide attributable to reaction with nitrogen dioxide (produced by photolysis of nitric acid) and to production of hydrochloric acid. Ozone loss ceased in March as concentrations of chlorine monoxide declined. Ozone losses could approach 50 percent if regeneration of nitrogen dioxide were inhibited by irreversible removal of nitrogen oxides (denitrification), as presently observed in the Antarctic, or without denitrification if inorganic chlorine concentrations were to double.

Salawitch, R. J.↗

Correlation Of N2O And O3 In The Atmosphere

Report describes study of correlation between concentrations of nitrous oxide and ozone in atmosphere of Antarctic region during late austral winter. Strong anticorrelation provides signature of air in lower stratosphere; alteration of correlation at specific sites indicate loss of ozone or mixing of perturbed and unperturbed air. Positive correlation interpreted as evidence of chemical depletion of ozone or horizontal mixing of normal air from lower stratosphere with ozone-depleted air from vortex.

Strahan, S. E.↗

N2O As A Tracer Of Antarctic Atmospheric Flows

Report discusses use of natural N2O as tracer gas in effort to determine large-scale lower stratospheric air flows during 1987 Airborne Antarctic Ozone Experiment. Data essential to understanding motions of air into and out of southern polar vortex and "ozone hole". N2O chosen as tracer because it has purely tropospheric sources, has troposheric lifetime greater than 20 years, and has long chemical lifetime in lower stratosphere.

Loewenstein, M.↗

Nitrous Oxide In The Antarctic Stratosphere

Paper reports on measurements of nitrous oxide (N2O) in upper atmosphere of Southern Hemisphere, made by tunable-laser absorption spectrometer on airplane. Measurements fill gap in information about distribution of N2O over Antarctic while ozone hole forming.

Podolske, J. R.↗

A diagnostic for denitrification in the winter polar stratospheres

The pairwise correlation of NO(y) and N2O data from the Southern and Northern Hemispheres is presented. Both data sets show a linear correlation region, defined as a reference state, and regions of denitrification where the correlation breaks down. Using two-dimensional photochemical model simulations of the atmosphere, a similar linear correlation is found between NO(y) and N2O, thereby establishing a theoretical framework for the reference state. This general approach, which can be extended to other pairs of molecules, should prove to be powerful in further comparisons of aircraft data with numerical models.

Fahey, D. W.↗

A comparison of ER-2 measurements of stratospheric water vapor between the 1987 Antarctic and 1989 Arctic Airborne missions

Vertical profiles of water vapor inside the Antarctic vortex have been compared with those taken outside it over Punta Arenas (53 deg S, 71 deg W). A similar exercise was performed with Arctic vortex profiles and those taken over Stavanger (59 deg N, 6 deg E). Residual water, defined as the stratospheric water vapor mixing ratio with the contribution from methane oxidation subtracted, is also shown as profiles inside and outside the vortex for both missions. The Arctic and Antarctic profiles of water vapor and residual water are compared. Locally dehydrated air was evident both inside and outside the Antarctic vortex, but such dehydration was not evident in and around the Arctic vortex. Arctic profiles of residual water are consistent with nontropical entry for some air.

Kelly, K. K.↗

N2O as a dynamical tracer in the Arctic vortex

This paper reports N2O measurements obtained by the Airborne Tunable Laser Absorption Spectrometer from 14 flights of the NASA ER-2 aircraft during the 1989 Airborne Arctic Stratospheric Expedition field campaign. In the altitude range expected for ozone loss, N2O has a long photochemical lifetime, making it an excellent tracer of lower stratospheric air motions. As in the southern hemisphere, the zonal wind speed maximum and large gradients of potential vorticity and N2O identify the vortex edge. The N2O profiles inside the vortex indicate net descent relative to outside the vortex and to the summer polar lower stratosphere. The descent of the N2O profile during the Arctic night relative to the summer profile is comparable to the downward shift in the vertical profile observed in the 1987 Antarctic winter vortex. Winter profiles at the poles are very similar above the 435 K potential temperature surface, but divergent below.

Loewenstein, M.↗

ATLAS instrument characterization - Accuracy of the AASE and AAOE nitrous oxide data sets

The Airborne Tunabel Laser Absorption Spectrometer ATLAS was used to measure nitrous oxide in the 1987 Airborne Antarctic Ozone Experiment (AAOE) and in the 1989 Airborne Arctic Stratospheric Expedition (AASE). After the AASE, a detailed study of the ATLAS characteristics was undertaken to quantify the error inherent in the in situ measurement of atmospheric N2O. Using the latest calibration of the ATLAS (June 1989) and incorporating the recognized errors arising in the flight environment of ATLAS, it was established that, for both the AASE and the AAOE, most of the acquired N2O data sets are accurate to + or - 10 percent (2 sigma).

Loewenstein, M.↗

Correlation of N2O and ozone in the southern polar vortex during the Airborne Antarctic Ozone Experiment

The correlation of N2O and ozone in the Antarctic stratosphere during the late austral winter was investigated using measurements of N2O mixing ratios obtained by an airborne laser spectrometer and in situ measurements of ozone for latitudes between 53 and 72 deg S. In addition, airborne N2O and O3 measurements taken between 13 and 20 km in the mid-latitudes (37 deg N and 53 deg S) were correlated. It was found that, while the mid-latitude ozone-N2O corelation was negative, poleward of 53 deg S, the N2O and O3 mixing ratios often showed a strong positive correlation, which approximately coincided with the edge of the polar vortex as defined by the wind-speed maximum. Inside the vortex, in lower wind speed regions, the N2O-O3 correlation became negative again, with the lowest ozone mixing ratios usually found near the boundary with the positively correlated region.

Strahan, S. E.↗

Stratospheric nitrous oxide distribution in the Southern Hemisphere

Nitrous oxide measurements were made in the Southern Hemisphere as part of the Airborne Antarctic Ozone Experiment in late winter and early spring 1987, covering the altitude range 14-21 km. This paper reports on N2O measurements made by the airborne tunable laser absorption spectrometer, which was flown onboard the NASA ER-2 aircraft. Average vertical N2O profiles at latitudes 72 deg S, 54 deg S, and 42 deg S are presented and compared, when possible, with equivalent summer profiles. Latitudinal gradients of N2O on isentropic surfaces are presented and discussed in terms of their implications about the inhibition of horizontal mixing near the polar vortex. Finally, a large-scale distribution of N2O for the region 72 deg S to 42 deg S latitude is presented.

Podolske, J. R.↗

Evidence for diabatic cooling and poleward transport within and around the 1987 Antarctic ozone hole

Atmospheric dynamics at altitudes of 17.5-19 km were analyzed using measurements of N2O, total water, total odd-nitrogen species, and potential vorticity (derived from pressures, temperatures, and wind speeds) obtained aboard the ER-2 aircraft flown in the period between August 23 and September 22 during the Airborne Antarctic Ozone Experiment. Results indicated a consistent gradual poleward movement of air, extending from about 10 deg in latitude outside the boundary of the ozone hole to about 5 deg inside. Evidence is presented of ongoing diabatic cooling throughout this zone, both inside and outside the chemically perturbed region.

Profitt, M. H.↗

Dehydration in the lower Antarctic stratosphere during late winter and early spring, 1987

The history of minimum temperatures at 50 and 70 mb is examined from NMC, UK Met O and ECMWF analyses. MSU channel 24 data are similarly inspected. South Pole sonde data are used to calculate saturation humidity mixing ratio as a function of altitude and time throughout 1987. Saturation with respect to ice could be maintained for water mixing ratios of 3.5 ppmv for a period of about 80 days from mid-June to mid-September. Dehydration to mixing ratios of 1 ppmv or less was possible sporadically. Data from the ER-2 flights between 53 S and 72 S are used in conjunction with particle size measurements and air parcel trajectories to demonstrate the dehydration occurring over Antarctica. Water mixing ratios at the latitude of Punta Arens (53 S), in conjunction with tracer measurements and trajectory analysis, show that at potential temperatures from about 325 to 400 K, the dryness (less than 3 ppmv) had its origin over Antarctica rather than in the tropics. Water mixing ratios within the Antarctic vortex varied from 1.5 to 3.8 ppmv, with a strong isentropic gradient being evident in the region of high potential vorticity gradients.

Kelly, K. K.↗

Nitrous oxide as a dynamical tracer in the 1987 Airborne Antarctic Ozone Experiment

In situ N2O measurements were made using an airborne tunable laser absorption spectrometer (ATLAS) on 12 flights into the Antarctic vortex, as well as on five transit flights outside the vortex region in August and September 1987, as part of the Airborne Antartic Ozone Experiment. Vertical profiles of N2O were obtained within the vortex on most of these flights and were obtained outside the vortex on several occasions. Flights into the vortex region show N2O decreasing southward between 53 and 72 S latitude on constant potential temperature surfaces in the lower stratosphere. The data lead to two important conclusions about the vortex region: (1) the lower stratosphere in August/September 1987 was occupied by 'old' air, which had subsided several kilometers during polar winter; (2) the N2O profile in the vortex was in an approximately steady state in August/September 1987, which indicates that the spring upwelling, suggested by several theories, did not occur.

Loewenstein, M.↗